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1. 发明授权

US06834508B2 Hydrogen storage and supply system 失效
标题翻译：储氢系统
公开(公告)号：US06834508B2
公开(公告)日：2004-12-28
申请号：US10285731
申请日：2002-10-31
申请人： Keith Bradley , Jeff Wyatt , Seung-Hoon Jhi , Young-Kyun Kwon , Jean Christophe Gabriel , George Gruner
发明人： Keith Bradley , Jeff Wyatt , Seung-Hoon Jhi , Young-Kyun Kwon , Jean Christophe Gabriel , George Gruner
IPC分类号： F17C1100
CPC分类号： F17C11/005 , G06Q50/06 , Y02E60/321 , Y02P90/45
摘要： This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.
摘要翻译：本发明提供了一种用于操作低温氢存储系统的装置和方法，所述低温储氢系统包含构造成吸附氢气的多孔介质。氢存储和供给系统包括氢源装置和低温存储装置。描述允许从氢源装置对冷冻摄影装置进行能量效率充填的方法和装置。冷藏式氢存储装置充满冷的加压氢气。在填充过程中，通过氢吸附到主介质上的过程，在冷冻存储装置中产生热量。提供了用于去除所产生的热量和温氢的方法和装置。还提供了用于在氢源装置内捕获和再循环逸出的氢的装置和方法。

2. 发明授权

US07036324B2 Hydrogen storage and supply system 失效
标题翻译：储氢系统
公开(公告)号：US07036324B2
公开(公告)日：2006-05-02
申请号：US11007383
申请日：2004-12-07
申请人： Keith Bradley , Jeff Wyatt , Seung-Hoon Jhi , Young-Kyun Kwon , Jean Christophe Gabriel , George Gruner
发明人： Keith Bradley , Jeff Wyatt , Seung-Hoon Jhi , Young-Kyun Kwon , Jean Christophe Gabriel , George Gruner
IPC分类号： F17C11/00 , F17C13/02 , B65B1/04 , B65B1/20
CPC分类号： F17C11/005 , G06Q50/06 , Y02E60/321 , Y02P90/45
摘要： This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.
摘要翻译：本发明提供了一种用于操作低温氢存储系统的装置和方法，所述低温储氢系统包含构造成吸附氢气的多孔介质。氢存储和供给系统包括氢源装置和低温存储装置。描述允许从氢源装置对冷冻摄影装置进行能量效率充填的方法和装置。冷藏式氢存储装置充满冷的加压氢气。在填充过程中，通过氢吸附到主介质上的过程，在冷冻存储装置中产生热量。提供了用于去除所产生的热量和温氢的方法和装置。还提供了用于在氢源装置内捕获和再循环逸出的氢的装置和方法。

3. 发明申请

US20050183424A1 Hydrogen storage and supply system 失效
标题翻译：储氢系统
公开(公告)号：US20050183424A1
公开(公告)日：2005-08-25
申请号：US11007383
申请日：2004-12-07
申请人： Keith Bradley , Jeff Wyatt , Seung-Hoon Jhi , Young-Kyun Kwon , Jean-Christophe Gabriel , George Gruner
发明人： Keith Bradley , Jeff Wyatt , Seung-Hoon Jhi , Young-Kyun Kwon , Jean-Christophe Gabriel , George Gruner
IPC分类号： B65B1/04 , B65B1/30 , B65B3/04 , B65B3/26 , B67C3/02 , B67D99/00 , F17C11/00 , F17C13/02 , G06F17/00 , B67D5/00
CPC分类号： F17C11/005 , G06Q50/06 , Y02E60/321 , Y02P90/45
摘要： This invention provides for an apparatus and a method for operation of a cryogenic hydrogen storage system that contains a porous medium configured to adsorb hydrogen. The hydrogen storage and supply system includes a hydrogen source apparatus and a cryosorptive storage apparatus. Methods and devices that allow for an energy efficient filling of the cryosorptive apparatus from the hydrogen source apparatus are described. The cryosorptive hydrogen storage apparatus is filled with cold, pressurized hydrogen. During the course of filling, heat is generated in the cryosorptive storage device by the process of hydrogen adsorption on to the host medium. Methods and devices are provided for the removal the generated heat and the warm hydrogen. Further provided are devices and methods for the capture and recycle of escaped hydrogen within the hydrogen source apparatus.
摘要翻译：本发明提供了一种用于操作低温氢存储系统的装置和方法，该低温储氢系统包含构造成吸附氢气的多孔介质。氢存储和供给系统包括氢源装置和低温存储装置。描述允许从氢源装置对冷冻摄影装置进行能量效率充填的方法和装置。冷藏式氢存储装置充满冷的加压氢气。在填充过程中，通过氢吸附到主介质上的过程，在冷冻存储装置中产生热量。提供了用于去除所产生的热量和温氢的方法和装置。还提供了用于在氢源装置内捕获和再循环逸出的氢的装置和方法。

4. 发明申请

US20070092437A1 Increasing hydrogen adsorption of nanostructured storage materials by modifying sp2 covalent bonds 审中-公开
标题翻译：通过改变sp2共价键来增加纳米结构储存材料的氢吸附
公开(公告)号：US20070092437A1
公开(公告)日：2007-04-26
申请号：US10020344
申请日：2001-12-11
申请人： Young-Kyun Kwon , Seung-Hoon Jhi , Keith Bradley , Philip Collins , Jean-Christophe Gabriel , George Gruner
发明人： Young-Kyun Kwon , Seung-Hoon Jhi , Keith Bradley , Philip Collins , Jean-Christophe Gabriel , George Gruner
IPC分类号： C01B3/00
CPC分类号： C01B3/0021 , B82Y30/00 , C01B3/001 , Y02E60/325
摘要： According to the invention, nanostructured storage materials are provided for storing hydrogen. The nanostructured storage materials can include a network of light elements, such as Be, B, C, N, O, F, Mg, P, S, and Cl, coupled with sp2 bonds. The hydrogen adsorption to the nanostructured storage material is improved by modifying the sp2 bonds. The sp2 bonds can be modified by forming the nanostructured storage material from the above light elements, possibly with a shape other than a planar layer, and by introducing defects. A chemical vapor deposition technique can be used for the synthesis, where doping gases are included into the flow. Methods for forming the nanostructured storage material with defects include removing light elements from the nanostructured storage material by irradiation with electrons, neutrons, ions, gamma rays, X-rays, and microwaves.
摘要翻译：根据本发明，提供用于储存氢的纳米结构储存材料。纳米结构的储存材料可以包括与Sp 2键结合的诸如Be，B，C，N，O，F，Mg，P，S和Cl的光元件网络。对纳米结构储存材料的氢吸附通过改变sp 2 O 2键来改善。可以通过从上述光元件形成纳米结构的储存材料，可能具有不同于平面层的形状，并且通过引入缺陷来修饰sp 2 O 2键。化学气相沉积技术可以用于合成，其中掺杂气体被包括在流中。用于形成具有缺陷的纳米结构存储材料的方法包括通过用电子，中子，离子，γ射线，X射线和微波照射从纳米结构的储存材料中去除光元件。

5. 发明申请

US20060165577A1 Boron oxide and related compounds for hydrogen storage 失效
公开(公告)号：US20060165577A1
公开(公告)日：2006-07-27
申请号：US11271446
申请日：2005-11-09
申请人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe Gabriel
发明人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe Gabriel
IPC分类号： C01B17/66 , C01B35/10
CPC分类号： B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/306 , B01D2253/308 , B01D2256/16 , B01D2259/4525 , C01B3/001 , Y02E60/324
摘要： A hydrogen storage medium is provided, where the medium is comprised of boron oxide and closely related compounds such as orthoboric acid, metaboric acid, hydrated boric acid, and disodium borohydrate. The medium is substantially an amorphous glassy network, albeit with local regions of order, pores, and networks that provide surface area. Hydrogen is adsorbed by the medium with a heat of adsorption of about 9 kJ/mol to about 13 kJ/mol, a value which is higher than that of the heat of adsorption of hydrogen on carbon. The value for the heat of adsorption of hydrogen on the inventive storage medium is provided by computation, and corroborated by experimental observation. The higher heat of adsorption of the medium provides for operation at temperatures higher temperatures higher than those provided by carbon. Further provided are methods by which the storage medium can be prepared in such a form so as to permit high capacity hydrogen storage, as well as an apparatus, with the inventive medium disposed therein, for storing hydrogen.

6. 发明授权

US07479240B2 Boron oxide and related compounds for hydrogen storage 失效
标题翻译：用于储氢的氧化硼和相关化合物
公开(公告)号：US07479240B2
公开(公告)日：2009-01-20
申请号：US11271446
申请日：2005-11-09
申请人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
发明人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
IPC分类号： C09K3/00
CPC分类号： B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/306 , B01D2253/308 , B01D2256/16 , B01D2259/4525 , C01B3/001 , Y02E60/324
摘要： A hydrogen storage medium is provided, where the medium is comprised of boron oxide and closely related compounds such as orthoboric acid, metaboric acid, hydrated boric acid, and disodium borohydrate. The medium is substantially an amorphous glassy network, albeit with local regions of order, pores, and networks that provide surface area. Hydrogen is adsorbed by the medium with a heat of adsorption of about 9 kJ/mol to about 13 kJ/mol, a value which is higher than that of the heat of adsorption of hydrogen on carbon. The value for the heat of adsorption of hydrogen on the inventive storage medium is provided by computation, and corroborated by experimental observation. The higher heat of adsorption of the medium provides for operation at temperatures higher temperatures higher than those provided by carbon. Further provided are methods by which the storage medium can be prepared in such a form so as to permit high capacity hydrogen storage, as well as an apparatus, with the inventive medium disposed therein, for storing hydrogen.
摘要翻译：提供了一种储氢介质，其中介质由氧化硼和紧密相关的化合物如原硼酸，偏硼酸，水合硼酸和硼酸二钠组成。该介质基本上是非晶玻璃质网络，尽管有局部的顺序区域，孔隙和提供表面积的网络。氢气吸附在约9kJ / mol至约13kJ / mol的吸附热下，该值高于碳对碳的吸附热。通过计算提供了本发明储存介质上氢的吸附热值，并通过实验观察证实。介质吸收较高的热量在比碳提供的温度更高的温度下运行。还提供了存储介质可以以允许高容量氢存储的形式制备的方法，以及其中设置有本发明介质的装置，用于储存氢。

7. 发明授权

US06991773B2 Boron-oxide and related compounds for hydrogen storage 失效
标题翻译：用于氢存储的硼氧化物和相关化合物
公开(公告)号：US06991773B2
公开(公告)日：2006-01-31
申请号：US10267792
申请日：2002-10-08
申请人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
发明人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
IPC分类号： C01B3/04 , C09K3/00
CPC分类号： B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/306 , B01D2253/308 , B01D2256/16 , B01D2259/4525 , C01B3/001 , Y02E60/324
摘要： A hydrogen storage medium is provided, where the medium is comprised of boron oxide and closely related compounds such as orthoboric acid, metaboric acid, hydrated boric acid, and disodium borohydrate. The medium is substantially an amorphous glassy network, albeit with local regions of order, pores, and networks that provide surface area. Hydrogen is adsorbed by the medium with a heat of adsorption of about 9 kJ/mol to about 13 kJ/mol, a value which is higher than that of the heat of adsorption of hydrogen on carbon. The value for the heat of adsorption of hydrogen on the inventive storage medium is provided by computation, and corroborated by experimental observation. The higher heat of adsorption of the medium provides for operation at temperatures higher temperatures higher than those provided by carbon. Further provided are methods by which the storage medium can be prepared in such a form so as to permit high capacity hydrogen storage, as well as an apparatus, with the inventive medium disposed therein, for storing hydrogen.
摘要翻译：提供了一种储氢介质，其中介质由氧化硼和紧密相关的化合物如原硼酸，偏硼酸，水合硼酸和硼酸二钠组成。该介质基本上是非晶玻璃质网络，尽管有局部的顺序区域，孔隙和提供表面积的网络。氢气吸附在约9kJ / mol至约13kJ / mol的吸附热下，该值高于碳对碳的吸附热。通过计算提供了本发明储存介质上氢的吸附热值，并通过实验观察证实。介质吸收较高的热量在比碳提供的温度更高的温度下运行。还提供了存储介质可以以允许高容量氢存储的形式制备的方法，以及其中设置有本发明介质的装置，用于储存氢。

8. 发明授权

US06672077B1 Hydrogen storage in nanostructure with physisorption 有权
标题翻译：具有物理吸附的纳米结构中的氢储存
公开(公告)号：US06672077B1
公开(公告)日：2004-01-06
申请号：US10020392
申请日：2001-12-11
申请人： Keith Bradley , Philip G. Collins , Jean-Christophe P. Gabriel , Young-Kyun Kwon , Seung-Hoon Jhi , George Grüner
发明人： Keith Bradley , Philip G. Collins , Jean-Christophe P. Gabriel , Young-Kyun Kwon , Seung-Hoon Jhi , George Grüner
IPC分类号： F17C1100
CPC分类号： C01B3/001 , F17C11/005 , Y02E60/321 , Y02E60/324 , Y10S977/948
摘要： A hydrogen containing nanostructure is provided, where the hydrogen is adsorbed to the nanostructure by physisorption. The nanostructure includes light elements, selected from the second and third rows of the periodic table. The nanostructure is formed as a layered network of light elements coupled with covalent sp2 bonds. The chemical composition of the nanostructure can be such that the desorption temperature of hydrogen is greater than the liquefaction temperature of nitrogen, 77 K. Further, a hydrogen storage system is provided, including a container and a nanostructured storage material within the container, wherein the nanostructured storage material includes light elements, and the nanostructured storage material is capable of adsorbing hydrogen by physisorption. The hydrogen storage system can include a liquid nitrogen based cooling system, capable of cooling the nanostructured storage material below the desorption temperature of hydrogen. Some embodiments contain a heater to control the temperature of the nanostructured storage material.
摘要翻译：提供含氢的纳米结构，其中通过物理吸附将氢吸附到纳米结构。纳米结构包括选自周期表的第二行和第三行的光元件。纳米结构形成为与共价sp 2结合的光元件的分层网络。纳米结构的化学组成可以使得氢的解吸温度大于氮的液化温度（77K）。此外，提供了一种储氢系统，其包括容器内的容器和纳米结构的储存材料，其中纳米结构储存材料包括轻元素，纳米结构储存材料能够通过物理吸附吸附氢。氢存储系统可以包括液氮冷却系统，其能够将纳米结构的储存材料冷却至低于氢的解吸温度。一些实施例包含用于控制纳米结构存储材料的温度的加热器。

9. 发明授权

US07181811B1 Micro-fastening system and method of manufacture 失效
标题翻译：微型紧固系统及其制造方法
公开(公告)号：US07181811B1
公开(公告)日：2007-02-27
申请号：US09601540
申请日：1999-02-11
申请人： David Tomanek , Richard Enbody , Young-Kyun Kwon
发明人： David Tomanek , Richard Enbody , Young-Kyun Kwon
IPC分类号： A44B18/00
CPC分类号： A44B18/0003 , Y10S977/724 , Y10S977/882 , Y10T24/27 , Y10T24/2775 , Y10T24/2792 , Y10T156/1089 , Y10T428/24008 , Y10T428/24017 , Y10T428/24174 , Y10T428/24182
摘要： This application relates to a micro-fastening system and, more particularly, to a mechanical micro-fastening system employing a plurality of mating nanoscale fastening elements (16, 18) and a method of manufacturing a micro-fastening system. The mating nanoscale fastening elements (16, 18) are formed by functionalizing nanotubes having an ordered array of hexagons with pentagons and heptagons at particular heterojunctions.
摘要翻译：本申请涉及一种微型紧固系统，更具体地，涉及一种采用多个配合的纳米级紧固件（16,18）的机械微型紧固系统和一种制造微型紧固系统的方法。配合的纳米级紧固元件（16,18）通过在具有特殊异质结的五边形和七边形上具有六边形有序排列的纳米管来形成。

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