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1. 发明授权

US07754819B2 Thermoplastic elastomer 失效
标题翻译：热塑性弹性体
公开(公告)号：US07754819B2
公开(公告)日：2010-07-13
申请号：US11262753
申请日：2005-11-01
申请人： Keisuke Chino , Manabu Kato , Tetsuji Kawazura
发明人： Keisuke Chino , Manabu Kato , Tetsuji Kawazura
IPC分类号： C08F8/32
CPC分类号： C08F8/14 , C08F2800/10 , C08F2810/20 , C08F8/46 , C08F210/16 , C08F8/32
摘要： A thermoplastic elastomer having a side chain having a moiety crosslinkable by hydrogen bond containing a carbonyl-containing group and a nitrogen-containing heterocycle, and another side chain having a covalently crosslinkable moiety, the thermoplastic elastomer being able to be crosslinked at the covalently crosslinkable moiety by at least one bond selected from the group consisting of amide, ester, lactone, urethane, ether, thiourethane, and thioether. The thermoplastic elastomer exhibits excellent mechanical strength without detracting from its excellent recycleability.
摘要翻译：一种具有侧链的热塑性弹性体，所述侧链具有通过含有含羰基的基团和含氮杂环的氢键可交联的部分，另一侧链具有共价交联部分，所述热塑性弹性体能够在共价交联部分通过选自酰胺，酯，内酯，氨基甲酸酯，醚，硫代氨基甲酸酯和硫醚中的至少一种键。热塑性弹性体显示出优异的机械强度，而不会降低其优异的可循环性。

2. 发明申请

US20060094829A1 Thermoplastic elastomer 失效
标题翻译：热塑性弹性体
公开(公告)号：US20060094829A1
公开(公告)日：2006-05-04
申请号：US11262753
申请日：2005-11-01
申请人： Keisuke Chino , Manabu Kato , Tetsuji Kawazura
发明人： Keisuke Chino , Manabu Kato , Tetsuji Kawazura
IPC分类号： C08F265/02
CPC分类号： C08F8/14 , C08F2800/10 , C08F2810/20 , C08F8/46 , C08F210/16 , C08F8/32
摘要： Disclosed is a thermoplastic elastomer having a side chain having a moiety crosslinkable by hydrogen bond containing a carbonyl-containing group and a nitrogen-containing heterocycle, and another side chain having a covalently crosslinkable moiety, the thermoplastic elastomer being able to be crosslinked at the covalently crosslinkable moiety by at least one bond selected from the group consisting of amide, ester, lactone, urethane, ether, thiourethane, and thioether. The thermoplastic elastomer of the present invention exhibits excellent mechanical strength without detracting from the excellent recyclability.
摘要翻译：公开了一种热塑性弹性体，其具有侧链，其具有可通过含有含羰基的基团和含氮杂环的氢键交联的部分，以及具有共价交联部分的另一侧链，所述热塑性弹性体能够共价交联通过选自酰胺，酯，内酯，氨基甲酸酯，醚，硫代氨基甲酸酯和硫醚中的至少一个键的可交联部分。本发明的热塑性弹性体显示出优异的机械强度，而不会降低优异的可再循环性。

3. 发明申请

US20060135703A1 Modified polymer having organic group derived from compound having mono-nitroxide free radical 审中-公开
标题翻译：具有衍生自具有单硝基氧自由基的化合物的有机基团的改性聚合物
公开(公告)号：US20060135703A1
公开(公告)日：2006-06-22
申请号：US11316986
申请日：2005-12-27
申请人： Hidekazu Onoi , Tetsuji Kawazura , Keisuke Chino
发明人： Hidekazu Onoi , Tetsuji Kawazura , Keisuke Chino
IPC分类号： C08F8/30
CPC分类号： C08C19/00 , C08C19/22 , C08F8/30 , C08F8/50 , C08F110/06
摘要： A process for producing a modified polymer having, in the molecule thereof, an organic group(s) introduced thereinto and derived from a compound(s) having a free radical comprising reacting a polymer such as an elastomer with a compound having the free radical stable at an ordinary temperature in the presence of oxygen, after or while a carbon radical(s) is generated in the polymer, whereby the modified polymer having an improved bondability and processability is formed.
摘要翻译：一种制备改性聚合物的方法，其在分子中具有引入其中并衍生自具有自由基的化合物的有机基团，包括使诸如弹性体的聚合物与具有自由基稳定性的化合物反应在常温下在氧的存在下，在聚合物中产生碳自由基之后或同时形成具有改善的粘合性和加工性的改性聚合物。

4. 发明授权

US06653409B2 Radical-modified polymer and polymer composition containing the same 失效
公开(公告)号：US06653409B2
公开(公告)日：2003-11-25
申请号：US10080590
申请日：2002-02-25
申请人： Makoto Ashiura , Keisuke Chino , Tetsuji Kawazura
发明人： Makoto Ashiura , Keisuke Chino , Tetsuji Kawazura
IPC分类号： C08F830
CPC分类号： B60C1/00 , C08C19/44 , C08F257/02 , C08F291/00 , C08F293/005 , C08F295/00 , C08L51/003 , C08L53/02
摘要： A radical-modified polymer having a free radical compound stable in the presence of oxygen at an ordinary temperature at the end of the molecule thereof or in the molecular chain thereof and a polymer composition containing the same.

5. 发明授权

US06642291B2 Viscoelasticity improving agent for rubber and rubber composition containing the same 失效
公开(公告)号：US06642291B2
公开(公告)日：2003-11-04
申请号：US09859488
申请日：2001-05-18
申请人： Keisuke Chino , Naoshi Miyashita , Makoto Ashiura , Tetsuji Kawazura
发明人： Keisuke Chino , Naoshi Miyashita , Makoto Ashiura , Tetsuji Kawazura
IPC分类号： C08G6348
CPC分类号： C08K5/32 , B60C1/00 , C08K5/3435 , C08L21/00
摘要： A viscoelasticity improving agent for rubber obtained by reacting an alkyllithium compound with a free radical compound having an isocyanate group in the molecule thereof and existing stably at room temperature in the presence of oxygen and a rubber composition.

6. 发明授权

US06809157B2 Thermoplastic polymer and thermoplastic elastomer composition 失效
标题翻译：热塑性聚合物和热塑性弹性体组合物
公开(公告)号：US06809157B2
公开(公告)日：2004-10-26
申请号：US09883239
申请日：2001-06-19
申请人： Keisuke Chino , Makoto Ashiura , Tetsuji Kawazura , Masahiro Ikawa
发明人： Keisuke Chino , Makoto Ashiura , Tetsuji Kawazura , Masahiro Ikawa
IPC分类号： C08F832
CPC分类号： C08F8/30 , C08F210/00
摘要： A thermoplastic polymer having a carbonyl-containing group and a nitrogen-containing 5-membered heterocycle-containing group in side chains, and a composition thereof. The thermoplastic polymer and composition thereof have excellent recycle property in that physical properties do not deteriorate even though formation of crosslinking and dissociation of crosslinking are repeatedly conducted with altering temperature. The thermoplastic polymer and composition thereof are that its crosslinked structure is considerably stable at room temperature, and therefore have considerably high tensile strength. In particular, in the case of bonding to a main chain at 3-position or 4-position of a nitrogen-containing 5-membered heterocycle, intermolecular hydrogen bond is caused, so that a cured product has high mechanical properties.
摘要翻译：具有含羰基的热塑性聚合物和侧链中含有含氮5元杂环的基团及其组合物。热塑性聚合物及其组合物具有优异的循环性能，即使交联的交联和交联的解离反应在改变温度下进行物理性能也不会劣化。热塑性聚合物及其组合物是其交联结构在室温下相当稳定，因此具有相当高的拉伸强度。特别地，在与含氮5元杂环的3-位或4-位的主链键合的情况下，引起分子间氢键，使得固化物具有高的机械性能。

7. 发明申请

US20050124764A1 Process for producing modified polymer 失效
标题翻译：生产改性聚合物的方法
公开(公告)号：US20050124764A1
公开(公告)日：2005-06-09
申请号：US10501228
申请日：2003-12-01
申请人： Hidekazu Onoi , Tetsuji Kawazura , Keisuke Chino
发明人： Hidekazu Onoi , Tetsuji Kawazura , Keisuke Chino
IPC分类号： C08C19/00 , C08C19/22 , C08F8/00 , C08F8/30 , C08F8/50 , C08F2/00
CPC分类号： C08C19/00 , C08C19/22 , C08F8/30 , C08F8/50 , C08F110/06
摘要： A process for producing a modified polymer having, in the molecule thereof, an organic group(s) introduced thereinto and derived from a compound(s) having a free radical comprising reacting a polymer such as an elastomer with a compound having the free radical stable at an ordinary temperature in the presence of oxygen, after or while a carbon radical(s) is generated in the polymer, whereby the modified polymer having an improved bondability and processability is formed.
摘要翻译：一种制备改性聚合物的方法，其在分子中具有引入其中并衍生自具有自由基的化合物的有机基团，包括使诸如弹性体的聚合物与具有自由基稳定性的化合物反应在常温下在氧的存在下，在聚合物中产生碳自由基之后或同时形成具有改善的粘合性和加工性的改性聚合物。

8. 发明授权

US07019086B2 Process for producing modified polymer 失效
标题翻译：生产改性聚合物的方法
公开(公告)号：US07019086B2
公开(公告)日：2006-03-28
申请号：US10501228
申请日：2003-12-01
申请人： Hidekazu Onoi , Tetsuji Kawazura , Keisuke Chino
发明人： Hidekazu Onoi , Tetsuji Kawazura , Keisuke Chino
IPC分类号： C08C19/22
CPC分类号： C08C19/00 , C08C19/22 , C08F8/30 , C08F8/50 , C08F110/06
摘要： A process for producing a modified polymer having, in the molecule thereof, an organic group(s) introduced thereinto and derived from a compound(s) having a free radical comprising reacting a polymer such as an elastomer with a compound having the free radical stable at an ordinary temperature in the presence of oxygen, after or while a carbon radical(s) is generated in the polymer, whereby the modified polymer having an improved bondability and processability is formed.
摘要翻译：一种制备改性聚合物的方法，其在分子中具有引入其中并衍生自具有自由基的化合物的有机基团，包括使诸如弹性体的聚合物与具有自由基稳定性的化合物反应在常温下在氧的存在下，在聚合物中产生碳自由基之后或同时形成具有改善的粘合性和加工性的改性聚合物。

9. 发明申请

US20130053517A1 METHOD FOR PRODUCING MODIFIED POLYMER 有权
标题翻译：生产改性聚合物的方法
公开(公告)号：US20130053517A1
公开(公告)日：2013-02-28
申请号：US13696085
申请日：2011-04-13
申请人： Tetsuji Kawazura , Michiko Kawabata
发明人： Tetsuji Kawazura , Michiko Kawabata
IPC分类号： C08F8/32
CPC分类号： C08F293/005 , C08F2438/02
摘要： A modified polymer is produced by reacting (A) a polymer with (B) a compound having a nitroxide free radical in the molecule stable at room temperature and in the presence of oxygen, (C) an organic peroxide, and (D) a radically polymerizable monomer having a functional group in the presence of (E) an amine compound comprising a monoamine compound represented by the general formula: NR1R2R3 (R1: C1-C20 alkyl group or aryl group; R2 and R3: H, C1-C20 alkyl group, or aryl group) or a polyamine compound represented by the general formula: (R4)2N(R5N)nR6N(R4)2 (R4: H or C1-C6 alkyl group; R5 and R6: C1-C6 alkylene group; n: 0 to 20). This method can not only reduce the reaction temperature but also improve the modification rate.
摘要翻译：通过使（A）聚合物与（B）在分子中具有氮氧自由基的化合物在室温下和在氧气存在下稳定，（C）有机过氧化物和（D）从根本上反应而制备改性聚合物在（E）包含由以下通式表示的单胺化合物的胺化合物存在下具有官能团的可聚合单体：（R 1：C 1 -C 20烷基或芳基; R 2和R 3：H，C 1 -C 20烷基（R4）2N（R5N）nR6N（R4）2（R4：H或C1-C6烷基; R5和R6：C1-C6亚烷基; n = 0）表示的多胺化合物， 0〜20）。该方法不仅可以降低反应温度，而且可以提高改性率。

10. 发明申请

US20090182069A1 RUBBER COMPOSITION CONTAINING MODIFIED CONJUGATED DIENE-BASED POLYMER BONDED TO FULLERENE 失效
标题翻译：含有改性共轭二烯基聚合物的橡胶组合物结合到富勒烯
公开(公告)号：US20090182069A1
公开(公告)日：2009-07-16
申请号：US12406188
申请日：2009-03-18
申请人： Makoto Ashiura , Tetsuji Kawazura , Fumito Yatsuyanagi
发明人： Makoto Ashiura , Tetsuji Kawazura , Fumito Yatsuyanagi
IPC分类号： C08K3/04 , C08K3/36
CPC分类号： B82Y30/00 , B60C1/00 , C08L19/006
摘要： A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan δ balance.
摘要翻译：通过在分子中配合含有0.5〜100重量％的具有与其结合的富勒烯的改性共轭二烯系聚合物，重均分子量为50,000以上，优异的加工性的橡胶组合物，优异的平衡性模量和热积累，优异的冷流动性和优异的tanδ平衡。

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