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    • 4. 发明授权
    • Color developer sheet
    • 彩色显影片
    • US4870048A
    • 1989-09-26
    • US179356
    • 1988-04-08
    • Katsumi MatsuokaShojiro SanoKeiso SaekiMasanobu TakashimaKen Iwakura
    • Katsumi MatsuokaShojiro SanoKeiso SaekiMasanobu TakashimaKen Iwakura
    • B41M5/333B41M5/155C07F15/04C07F15/06
    • B41M5/155Y10S428/914Y10T428/277
    • A color developer sheet which brings about color development by contact with a substantially colorless electron-donating color former, where said sheet contains an organometallic compound represented by the following general formula (I), (II) or (III) to enhance light resistance and stability of the color product obtained by the color development: ##STR1## wherein M represents a nickel atom, a copper atom, a cobalt atom, or a zinc atom; X.sub.1 and X.sub.2 each represents an oxygen atom, a sulfur atom, or --NR.sub.5 --, in which R.sub.5 represents a hydrogen atom, an alkyl group, an aryl group, or a hydroxyl group; X.sub.3 represents a hydroxyl group, or a mercapto group; Y represents an oxygen atom, a sulfur atom, or --CHR.sub.6, in which R.sub.6 represents a hydrogen atom, an alkyl group, or an aryl group; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, a halogen atom, a cyano group, or an alkyl, aryl, cycloalkyl or heterocyclyl group attached to the carbon atom directly or via a divalent linkage group, or at least either combination of R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 may be connected to each other to form a 5- or 6-membered ring together with the carbon atoms; and Z represents an organic ligand which forms a complex by binding to M via its hetero atom.
    • 一种通过与基本上无色的给电子成色剂接触而引起显色的彩色显影片,其中所述片含有由以下通式(I),(II)或(III)表示的有机金属化合物,以提高耐光性, (II)其中M表示镍原子,铜原子,钴原子或锌原子;(III)其中M表示镍原子, X 1和X 2各自表示氧原子,硫原子或-NR 5 - ,其中R 5表示氢原子,烷基,芳基或羟基; X3表示羟基或巯基; Y表示氧原子,硫原子或-CHR6,其中R6表示氢原子,烷基或芳基; R 1,R 2,R 3和R 4各自表示直接或经由二价连接基团连接到碳原子上的氢原子,卤原子,氰基或烷基,芳基,环烷基或杂环基,或至少 R 1和R 2和/或R 3和R 4可以彼此连接以与碳原子一起形成5-或6-元环; Z表示通过其杂原子与M结合形成络合物的有机配体。
    • 10. 发明授权
    • Optical image-recording material
    • 光学图像记录材料
    • US5051333A
    • 1991-09-24
    • US541865
    • 1990-06-21
    • Naoto YanagiharaKen IwakuraTosiaki EndoKeiso Saeki
    • Naoto YanagiharaKen IwakuraTosiaki EndoKeiso Saeki
    • G03C1/00G03F7/004
    • G03C1/002G03F7/002
    • An optical image-recording material comprising:(a) microcapsules, in which at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent are enclosed together, and (b) at least one reducing agent not enclosed in the microcapsules, or(c) microcapsules, in which at least one reducing agent is enclosed, and (d) both at least one leuco dye capable of forming a color by oxidation and at least one photo-oxidizing agent not enclosed in the microcapsules,wherein the microcapsules have capsule walls made from a material which lowers its permeability barrier to at least one component selected from the photo-oxidizing agent and the reducing agent when the capsule wall material is heated above its glass transition temperature, and the leuco dye is a xanthene compound having an N-substituted anilino group substituted by an electron attracting group.
    • 一种光学图像记录材料,包括:(a)微胶囊,其中至少一种能够通过氧化形成颜色的无色染料和至少一种光氧化剂被包封在一起,和(b)至少一种不包含的还原剂 在微胶囊中,或(c)其中封闭有至少一种还原剂的微胶囊,和(d)能够通过氧化形成颜色的至少一种无色染料和不包封在微胶囊中的至少一种光氧化剂 其中,所述微胶囊具有由将所述胶囊壁材料加热到高于其玻璃化转变温度时将其对所述光氧化剂和还原剂中的至少一种成分的透过性阻挡性降低的材料制成的胶囊壁,所述无色染料为 具有被吸电子基团取代的N-取代苯胺基的呫吨化合物。