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1. 发明授权

US5534490A (Hg,Cu)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub.y oxide superconductor and method of preparing the same 失效
标题翻译：（Hg，Cu）Ba2Ca2Cu3Oy氧化物超导体及其制备方法
公开(公告)号：US5534490A
公开(公告)日：1996-07-09
申请号：US264660
申请日：1994-06-23
申请人： Makoto Itoh , Ayako Yamamoto , Kazuyuki Isawa , Seiji Adachi , Hisao Yamauchi , Shoji Tanaka
发明人： Makoto Itoh , Ayako Yamamoto , Kazuyuki Isawa , Seiji Adachi , Hisao Yamauchi , Shoji Tanaka
IPC分类号： C01G1/00 , C01G13/00 , C04B35/00 , C04B35/45 , H01B12/00 , H01B13/00 , H01L39/12 , H01L39/24 , C04B35/50
CPC分类号： H01L39/2419 , H01L39/126 , Y10S505/725 , Y10S505/739 , Y10S505/742 , Y10S505/779
摘要： Provided is an Hg-Ba-Ca-Cu-O oxide superconductor having a high superconductivity transition temperature Tc and a method which can prepare the same in excellent reproducibility. This oxide superconductor consists essentially of Hg, Ba, Ca, Cu and O, and is expressed in a chemical formula (Hg.sub.1-X Cu.sub.X)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub.Y, wherein X=0.05 to 0.7 and Y=8 to 8.75. A method of preparing the oxide superconductor comprises a step of mixing raw materials of Hg, Ba, Ca and Cu with each other so that (Hg+Ba):Ca:Cu=b:1:C and Hg:Ba=(1-a):a, wherein 0.625.ltoreq.a.ltoreq.0.714, 1.ltoreq.b.ltoreq.3 and 1.667.ltoreq.c.ltoreq.3.444, in mole ratio, and compression-molding the mixture, and a step of heat treating a compact obtained by the compression molding. This oxide superconductor has a superconductivity transition temperature Tc of 134 K., which is the highest at present.
摘要翻译：提供具有高超导转变温度Tc的Hg-Ba-Ca-Cu-O氧化物超导体和可以以优异的再现性制备它的方法。该氧化物超导体主要由Hg，Ba，Ca，Cu和O组成，并以化学式（Hg1-XCuX）Ba2Ca2Cu3OY表示，其中X = 0.05〜0.7，Y = 8〜8.75。制备氧化物超导体的方法包括将Hg，Ba，Ca和Cu的原料彼此混合以使（Hg + Ba）：Ca：Cu = b：1：C和Hg：Ba =（1- a）：a，其中以摩尔比0.625

2. 发明授权

US5444039A (Hg,Pb)-Ba-Ca-Cu-O superconductor and method of manufacturing the same 失效
标题翻译：（Hg，Pb）-Ba-Ca-Cu-O超导体及其制造方法
公开(公告)号：US5444039A
公开(公告)日：1995-08-22
申请号：US304494
申请日：1994-09-12
申请人： Kazuyuki Isawa , Ayako Yamamoto , Makoto Itoh , Seiji Adachi , Hisao Yamauchi
发明人： Kazuyuki Isawa , Ayako Yamamoto , Makoto Itoh , Seiji Adachi , Hisao Yamauchi
IPC分类号： C01G1/00 , C01G13/00 , C01G21/00 , C04B35/45 , H01B13/00 , H01L39/12 , C01F11/02 , C01G3/02
CPC分类号： H01L39/126 , Y10S505/739 , Y10S505/776 , Y10S505/785
摘要： The oxide superconductor according to the present invention is represented by (Hg.sub.1-x Pb.sub.x)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub..delta. (0.08.ltoreq.x.ltoreq.0.41, 7.625.ltoreq..delta..ltoreq.9.15), and has a crystal structure in which a lamination unit of (Hg, Pb)O.sub.z -BaO-CuO.sub.2 -Ca-CuO.sub.2 -Ca-CuO.sub.2 -BaO is laminated in a c-axial direction of the crystal structure (0.625.ltoreq.z.ltoreq.2.15). Further, the method of manufacturing an oxide superconductor, according to the present invention, includes the steps of: mixing material powders of HgO, PbO, BaO, CaO and CuO at a mole ratio of (Hg.sub.1-x Pb.sub.x):Ba:Ca:Cu=a:2:b:c (1.ltoreq.a.ltoreq.2.5, 2.ltoreq.b.ltoreq.3, 2.5.ltoreq.c.ltoreq.4) and compression-molding the mixture powder into a compact; and subjecting the compact to a thermal treatment at 600.degree.-750.degree. C.
摘要翻译：根据本发明的氧化物超导体由（Hg1-xPbx）Ba2Ca2Cu3Oδ（0.08≤x≤0.441,7.625≤δ= 9.15）表示，并且具有晶体结构，其中层压单元（Hg，Pb）Oz-BaO-CuO2-Ca-CuO2-Ca-CuO2-BaO在晶体结构的c轴方向上层压（0.625≤z= 2.15）。此外，根据本发明的氧化物超导体的制造方法包括以下步骤：以（Hg1-xPbx）：Ba:Ca:Cu的摩尔比混合HgO，PbO，BaO，CaO和CuO的材料粉末 = a：2：b：c（1）将混合粉末压缩成型成型体; 并在600〜750℃下进行热处理。

3. 发明授权

US5652199A Method of manufacturing oxide superconductor 失效
标题翻译：制造氧化物超导体的方法
公开(公告)号：US5652199A
公开(公告)日：1997-07-29
申请号：US360407
申请日：1994-12-21
申请人： Kazuyuki Isawa , Ayako Yamamoto , Seiji Adachi , Makoto Itoh , Hisao Yamauchi
发明人： Kazuyuki Isawa , Ayako Yamamoto , Seiji Adachi , Makoto Itoh , Hisao Yamauchi
IPC分类号： C01G1/00 , C01G13/00 , C04B35/45 , H01B12/00 , H01B13/00 , H01L39/12 , H01L39/24 , C04B35/64
CPC分类号： C04B35/45 , H01L39/2419
摘要： A method of manufacturing an oxide superconductor, including the steps of mixing oxide materials of the metals contained in an oxide superconductor represented by HgBa.sub.2 Ca.sub.2 Cu.sub.3 O.sub.8+y to prepare a powder mixture of the composition noted above, molding the powder mixture to prepare a molded body of a desired shape, and applying a heat treatment to the molded body within a hermetic container at a temperature sufficient for bringing about a solid phase reaction of the oxide materials for at least 20 hours. Also provided is a method of manufacturing an oxide superconductor, including the steps of mixing at least one additive element selected from the group consisting of Pb, Bi, Tl, Au, Pt, Ag, Cd and In with oxide materials of the metals contained in a Hg-series 1223 type oxide superconductor to prepare a powder mixture, molding the powder mixture to prepare a molded body of a desired shape, and applying a heat treatment to the molded body within a hermetic container at a temperature sufficient for bringing about a solid phase reaction of the oxide materials for at least 10 hours.
摘要翻译：一种制造氧化物超导体的方法，包括以下步骤：将由HgBa2Ca2Cu3O8 + y表示的氧化物超导体中所含的金属的氧化物材料混合，制备上述组合物的粉末混合物，模制该粉末混合物以制备所需的形状，并且在足以使氧化物材料的固相反应至少20小时的温度下在密封容器内对成型体进行热处理。还提供了一种制造氧化物超导体的方法，包括以下步骤：将选自Pb，Bi，Tl，Au，Pt，Ag，Cd和In中的至少一种添加元素与包含在其中的金属的氧化物材料混合一种Hg系1223型氧化物超导体，以制备粉末混合物，模塑该粉末混合物以制备所需形状的成型体，并且在足以产生固体的温度下对密闭容器内的成型体进行热处理氧化物材料的相位反应至少10小时。

4. 发明授权

US5599775A (Hg Cu)Bg.sub.2 Ca.sub.2 Cu.sub.3 Oy oxide superconductor and method of preparing the same 失效
标题翻译：（Hg Cu）Bg2Ca2Cu3Oy氧化物超导体及其制备方法
公开(公告)号：US5599775A
公开(公告)日：1997-02-04
申请号：US591990
申请日：1996-01-26
申请人： Makoto Itoh , Ayako Yamamoto , Kazuyuki Isawa , Seiji Adachi , Hisao Yamauchi , Shoji Tanaka
发明人： Makoto Itoh , Ayako Yamamoto , Kazuyuki Isawa , Seiji Adachi , Hisao Yamauchi , Shoji Tanaka
IPC分类号： C01G1/00 , C01G13/00 , C04B35/00 , C04B35/45 , H01B12/00 , H01B13/00 , H01L39/12 , H01L39/24
CPC分类号： H01L39/2419 , H01L39/126 , Y10S505/725 , Y10S505/739 , Y10S505/742 , Y10S505/779
摘要： Provided is an Hg--Ba--Ca--Cu--O oxide superconductor having a high superconductivity transition temperature Tc and a method which can prepare the same in excellent reproducibility. This oxide superconductor consists essentially of Hg, Ba, Ca, Cu and O, and is expressed in a chemical formula (Hg.sub.1-X Cu.sub.X)Ba.sub.2 Ca.sub.2 Cu.sub.3 O.sub.y, wherein X=0.05 to 0.7 and Y=8 to 8.75. A method of preparing the oxide superconductor comprises a step of mixing raw materials of Hg, Ba, Ca and Cu with each other so that (Hg+Ba):Ca:Cu =b:1:C and Hg:Ba=(1-a):a, wherein 0.625.ltoreq.a.ltoreq.0.714, 1.ltoreq.b.ltoreq.3 and 1.667.ltoreq.c.ltoreq.3.444, in mole ratio, and compression-molding the mixture, and a step of heat treating a compact obtained by the compression molding. This oxide superconductor has a superconductivity transition temperature Tc of 134 K, which is the highest at present.
摘要翻译：提供具有高超导转变温度Tc的Hg-Ba-Ca-Cu-O氧化物超导体和可以以优异的再现性制备它的方法。该氧化物超导体主要由Hg，Ba，Ca，Cu和O组成，并以化学式（Hg1-XCuX）Ba2Ca2Cu3Oy表示，其中X = 0.05〜0.7，Y = 8〜8.75。制备氧化物超导体的方法包括将Hg，Ba，Ca和Cu的原料彼此混合以使（Hg + Ba）：Ca：Cu = b：1：C和Hg：Ba =（1- a）：a，其中以摩尔比0.625

5. 发明授权

US5716907A Rock-salt/infinite layer chlorine-containing oxide superconductor and manufacturing method of the same 失效
标题翻译：岩盐/无限层含氯氧化物超导体及其制造方法相同
公开(公告)号：US5716907A
公开(公告)日：1998-02-10
申请号：US618827
申请日：1996-03-20
申请人： Tadashi Tatsuki , Seiji Adachi , Makoto Itoh , Toshiyuki Tamura , Changqin Jin , Xiao-Jing Wu , Hisao Yamauchi
发明人： Tadashi Tatsuki , Seiji Adachi , Makoto Itoh , Toshiyuki Tamura , Changqin Jin , Xiao-Jing Wu , Hisao Yamauchi
IPC分类号： C01G1/00 , C01G3/00 , C04B35/45 , C04B35/645 , H01B12/00 , H01B13/00 , H01L39/24 , C04B35/01
CPC分类号： C04B35/45 , C04B35/645 , H01L39/2419 , Y10S505/776 , Y10S505/779
摘要： The present invention is an oxide superconductor containing alkaline earth metal M (where M is at least one element of Ba, Sr, and Ca) and having a crystalline structure in which a portion based on two rock-salt structures including the alkaline earth metal M, oxygen, and chlorine, and a 2n-1 piece of infinite layer structure portion are alternately layered on each other, said 2n-1 piece of infinite layer structure portion having an atom layer including copper atoms and oxygen atoms in a ratio of 1 to 2 and of an atom layer including only M atoms layered on each other (where n is an integer of 1 or more and where copper atoms and oxygen atom are contained in a ratio of 1 to 2 if n is 1).
摘要翻译：本发明是含有碱土金属M（其中M是Ba，Sr和Ca的至少一种元素）的氧化物超导体，具有结晶结构，其中基于包括碱土金属M的两种岩盐结构的部分，氧和氯，并且2n-1个无限层结构部分彼此交替层叠，所述2n-1个无限层结构部分具有包含铜原子和氧原子的原子层，比例为1〜 2和仅包含彼此层叠的M原子的原子层（n为1以上的整数，如果n为1，则以1〜2的比例含有铜原子和氧原子）。

6. 发明授权

US5776862A Oxide superconductor and process of producing the same 失效
标题翻译：氧化物超导体及其制造方法
公开(公告)号：US5776862A
公开(公告)日：1998-07-07
申请号：US684985
申请日：1996-07-22
申请人： Ryo Usami , Kazuyuki Isawa , Hiroshi Kubota , Roman Puzniak , Hisao Yamauchi , Shoji Tanaka
发明人： Ryo Usami , Kazuyuki Isawa , Hiroshi Kubota , Roman Puzniak , Hisao Yamauchi , Shoji Tanaka
IPC分类号： C04B35/45 , C01G1/00 , C01G13/00 , H01B12/00 , H01B13/00 , H01L39/12 , H01L39/24
CPC分类号： H01L39/2419 , H01L39/126 , Y10S505/742 , Y10S505/782
摘要： The hole density of an oxide superconductor having holes as carriers is higher than the hole density to bring the highest value of the superconductivity critical temperature Tc thereof, and it can be made higher than the optimal density to bring the highest Tc value by treating the oxide superconductor with heat in an oxidizing gas atmosphere, or by replacing positive ions constituting the oxide superconductor except for copper with ions of a low valence number. Accordingly, it is possible to substantially reduce the rate of decrease of the critical current density owing to an applied magnetic field when the magnetic field is applied parallel to the crystal c axis, and to allow a current conductor produced by using the oxide superconductor to have high critical current density.
摘要翻译：具有空穴作为载体的氧化物超导体的空穴密度高于空穴密度以达到其超导临界温度Tc的最高值，并且可以使其高于通过处理氧化物以获得最高Tc值的最佳密度在氧化气体气氛中具有热的超导体，或者通过用低价数离子替代构成除铜以外的氧化物超导体的正离子。因此，当平行于晶体c轴施加磁场时，由于所施加的磁场，可以显着降低临界电流密度的降低率，并且允许通过使用氧化物超导体产生的电流导体具有高临界电流密度。

7. 发明授权

US5840659A Method of preparing oxide superconductive material 失效
标题翻译：制备氧化物超导材料的方法
公开(公告)号：US5840659A
公开(公告)日：1998-11-24
申请号：US818368
申请日：1997-03-14
申请人： Tetsuyuki Kaneko , Kazuyuki Hamada , Hisao Yamauchi , Seiji Adachi , Shoji Tanaka
发明人： Tetsuyuki Kaneko , Kazuyuki Hamada , Hisao Yamauchi , Seiji Adachi , Shoji Tanaka
IPC分类号： C01G1/00 , C01G15/00 , C04B35/00 , C04B35/45 , H01B12/00 , H01B13/00 , H01L39/12 , H01L39/24 , A23G1/00 , A23G3/30 , A23L1/10 , A23L1/522
CPC分类号： C04B35/4512 , H01L39/126
摘要： In order to provide a Tl--Ba--Ca--Cu--O superconductive material which can obtain a stable superconducting state and a method of preparing the same, the oxide superconductive material is expressed in the following composition formula: Tl.sub.x Ba.sub.2 Ca.sub.y Cu.sub.3 O.sub.z where x, y and z are in relations satisfying 1.5.ltoreq.x.ltoreq.2.0, 2.0.ltoreq.y.ltoreq.2.5, x+y=4.0 and 9.0.ltoreq.z.ltoreq.11.0, and comprises tetragonal system superconducting phases having lattice constants of a=0.385 to 0.386 nm and c longer than 3.575 nm, to exhibit zero resistance under a temperature of at least 125 K, while the method comprises a step of mixing powder raw materials in blending ratios for satisfying the above composition formula, a step of sintering the as-formed mixed powder in an oxygen jet or in the atmosphere to obtain a sintered body, and a step of annealing the sintered body in a closed atmosphere at 700.degree. to 800.degree. C. for at least 10 hours.
摘要翻译：为了提供可以获得稳定的超导状态的Tl-Ba-Ca-Cu-O超导材料及其制备方法，氧化物超导材料以下列组成式表示：其中x，y和z分别为在满足1.5

8. 发明授权

US5705457A Oxide superconductor and method for manufacturing the same 失效
标题翻译：氧化物超导体及其制造方法
公开(公告)号：US5705457A
公开(公告)日：1998-01-06
申请号：US525912
申请日：1995-09-08
申请人： Toshiyuki Tamura , Seiji Adachi , Xiao-Jing Wu , Hisao Yamauchi
发明人： Toshiyuki Tamura , Seiji Adachi , Xiao-Jing Wu , Hisao Yamauchi
IPC分类号： C01G1/00 , C01G21/00 , C04B35/45 , C04B35/645 , H01B13/00 , H01L39/24 , H01L39/12
CPC分类号： C04B35/45 , C04B35/645 , Y10S505/742 , Y10S505/776
摘要： The present invention provides an oxide superconductor which is expressed in the composition formula (Pb.sub.1-x-y M.sub.x (A1).sub.y)(A2).sub.2 (A3).sub.n-1 (Cu).sub.n (O).sub.2n+3+z (wherein 0.ltoreq.0.6, 0.ltoreq.y.ltoreq.0.6, x+y.ltoreq.0.6, n denotes integers of 1 or more, -0.6.ltoreq.z.ltoreq.0.5, M denotes Cu or Cd, and A1, A2 and A3 denote at least one element of Ba, Sr, and Ca, respectively) and which has a crystal structure stacking rock salt structure based portions and infinite layer structure portions, wherein the rock salt structure based portion has a structure that an atoms layer having 0.5-1.5 oxygen atoms, in case the total atoms number of Pb, M and A1 is one, and an atoms layer having one or less oxygen atoms per one A2 atom, are stacked and the infinite layer structure portion has a structure that an atoms layer having 2 oxygen atoms per one Cu atom and an atoms layer of A3 atoms only, are stacked. Further, the present invention provides a method for manufacturing the above oxide superconductor by heat-treating a raw material of oxide superconductor at a temperature of 800.degree.-1200.degree. C. under superhigh pressure of 2-8 GPa.
摘要翻译：本发明提供以组成式（Pb1-x-yMx（A1）y）（A2）2（A3）n-1（Cu）n（O）2n + 3 + z（其中0）表示的氧化物超导体 n = 0.6，0≤y≤0.6，x + y <0.6，n表示1以上的整数，-0.6≤Z≤0.5，M表示Cu或Cd，A1表示，A2和A3分别表示Ba，Sr和Ca中的至少一种元素），其具有层叠基于盐岩结构的部分和无限层结构部分的晶体结构，其中岩盐结构基部分具有以下结构：原子在氧原子数为0.5-1.5的情况下，在Pb，M和Al的总原子数为1的情况下，每个A2原子具有一个或多个氧原子的原子层被堆叠，并且无限层结构部分具有以下结构：每个Cu原子具有2个氧原子并且仅具有A3原子的原子层的原子层被堆叠。此外，本发明提供一种通过在800〜1200℃的温度下在2-8GPa的超高压下热处理氧化物超导体的原料来制造上述氧化物超导体的方法。

9. 发明授权

US5670457A Oxide superconductor and method of producing same 失效
标题翻译：氧化物超导体及其制造方法
公开(公告)号：US5670457A
公开(公告)日：1997-09-23
申请号：US356640
申请日：1994-12-15
申请人： Seiji Adachi , Changqin Jin , Xiao-Jing Wu , Hisao Yamauchi , Shoji Tanaka
发明人： Seiji Adachi , Changqin Jin , Xiao-Jing Wu , Hisao Yamauchi , Shoji Tanaka
IPC分类号： C01G1/00 , C01G3/00 , H01B12/00 , H01B13/00 , H01L39/12 , C04B35/01 , C04B35/03
CPC分类号： H01L39/126 , Y10S505/776 , Y10S505/778
摘要： An oxide superconductor composed of Cu, O and at least one of Ba, Sr and Ca and including alternately arranged at least one oxygen-deficient perovskite structure section and at least one infinite layer structure section, wherein the perovskite structure section consists of two first atomic layers and a second atomic layer sandwiched between the first layers, and wherein the infinite layer structure section consists of alternately arranged, third and fourth atomic layers. Each of the first layers consists of O and an element M.sup.1 selected from Ba, Sr and Ca and has an atomic ratio O/M.sup.1 of 1 or less, while the second layer consists of O and Cu and has an atomic ratio O/Cu of 2 or less. Each of the third layers consists of O and Cu and has an atomic ratio O/Cu of 2, while each of the fourth layers consists of an element M.sup.2 selected from Ba, Sr and Ca. A superconductor having a superconducting critical temperature of over 100 K. may be produced by heat treatment at 800.degree.-1,200.degree.C. under a super-high pressure of 20,000-80,000 atm.
摘要翻译：由Cu，O和Ba，Sr和Ca中的至少一种构成的氧化物超导体，包括交替排列至少一个缺氧钙钛矿结构部分和至少一个无限层结构部分，其中钙钛矿结构部分由两个第一原子层和夹在第一层之间的第二原子层，并且其中无限层结构部分由交替排列的第三和第四原子层组成。每个第一层由O和选自Ba，Sr和Ca的元素M1组成，并且具有1或更小的原子比O / M1，而第二层由O和Cu组成，并且原子比O / Cu为 2以下。每个第三层由O和Cu组成，并且原子比O / Cu为2，而每个第四层由选自Ba，Sr和Ca的元素M2组成。具有超导临界温度超过100K的超导体可以通过在20000-80,000大气压的超高压下在800-1200℃下进行热处理来制备。

10. 发明授权

US5446017A Superconductive copper-containing oxide materials of the formula A.sub.p B.sub.q Cu.sub.2 O.sub.4.+-.r 失效
标题翻译：超导的含铜氧化物材料，具有下式：ApBqCu2O4 +/- r
公开(公告)号：US5446017A
公开(公告)日：1995-08-29
申请号：US45077
申请日：1993-04-12
申请人： Takeshi Sakurai , Nobuyuki Sugii , Seiji Adachi , Michiharu Ichikawa , Yuji Yaegashi , Hisao Yamauchi , Masahiko Shimada , Hirotsugu Takizawa
发明人： Takeshi Sakurai , Nobuyuki Sugii , Seiji Adachi , Michiharu Ichikawa , Yuji Yaegashi , Hisao Yamauchi , Masahiko Shimada , Hirotsugu Takizawa
IPC分类号： C01G1/00 , C01G3/00 , C04B35/00 , C04B35/45 , H01B12/06 , H01B13/00 , H01L39/12 , H01L39/24 , H01B12/00
CPC分类号： H01L39/126 , Y10S505/775 , Y10S505/776
摘要： A superconductive oxide material having an infinite layer structure and having the following formula:A.sub.p B.sub.q Cu.sub.2 O.sub.4.+-.rwherein A and B are different and each represent an element selected from lanthanoid elements and elements belonging to Groups IA, IIA and IIIA of the Periodic Table, p is between 0.9 and 1.1, q is between 0.9 and 1.1 and r is between 0 and 0.6. The oxide material has a crystal structure belonging to a tetragonal system of P4/mmm and 1-123 having the following lattice parameters:3.8.ANG..ltoreq.a.ltoreq.4.0.ANG.7.6.ANG..ltoreq.c.ltoreq.8.0.ANG.or to an orthorhombic system of Pmmm and I-47 having the following lattice parmeters:3.8.ANG..ltoreq.a.ltoreq.3.95.ANG.3.82.ANG..ltoreq.b.ltoreq.4.0.ANG.7.6.ANG..ltoreq.c.ltoreq.8.0.ANG..
摘要翻译：具有无限层结构并具有下式的超导氧化物材料：ApBqCu2O4 +/- r其中A和B不同，并且各自表示选自镧系元素和元素周期表中IA，IIA和IIIA族的元素，p 在0.9和1.1之间，q在0.9和1.1之间，r在0和0.6之间。氧化物材料具有属于P4 / mmm和1-123的四方晶系的晶体结构，具有以下晶格参数：3.8 ANGSTROM

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