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1. 发明授权

US06666748B2 Machining center and method of changing tools thereof 有权
公开(公告)号：US06666748B2
公开(公告)日：2003-12-23
申请号：US09946091
申请日：2001-09-04
申请人： Kazuyuki Hiramoto , Naoshi Takayama , Keigo Tada , Takashi Hoshi , Naozumi Tanikawa , Tsuyoshi Fukuhara , Kazutoyo Moriguchi
发明人： Kazuyuki Hiramoto , Naoshi Takayama , Keigo Tada , Takashi Hoshi , Naozumi Tanikawa , Tsuyoshi Fukuhara , Kazutoyo Moriguchi
IPC分类号： B24B500
CPC分类号： B24B7/10 , B23Q3/15773 , B24B17/10 , B24B53/013 , B24B53/053 , B24B57/02 , Y10T483/174
摘要： The invention provides a machining center for machining a workpiece by moving a grinding wheel and the workpiece relative to each other in the X, Y and Z directions. The machining center has a main spindle for removably mounting a grinding wheel, a spindle head for rotationally supporting the main spindle, a table for mounting the workpiece, a column for movably supporting the spindle head, and tool dressing means having a dresser spindle, provided over the spindle head to move in the vertical direction toward and away from the grinding wheel mounted to the main spindle, for mounting a dresser for truing or dressing the outer peripheral surface of the grinding wheel.

2. 发明授权

US07968751B2 Method of fluorination 失效
公开(公告)号：US07968751B2
公开(公告)日：2011-06-28
申请号：US12068481
申请日：2008-02-07
申请人： Shoji Hara , Tsuyoshi Fukuhara
发明人： Shoji Hara , Tsuyoshi Fukuhara
IPC分类号： C07C211/03 , C07C211/08
CPC分类号： C07D239/30 , C07B39/00 , C07B2200/09 , C07C17/093 , C07C17/16 , C07C17/18 , C07C29/64 , C07C51/60 , C07C67/307 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2601/20 , C07C2603/74 , C07H1/00 , C07H9/04 , C07H13/04 , C07H13/08 , C07H19/06 , C07C22/08 , C07C21/18 , C07C19/08 , C07C23/38 , C07C23/02 , C07C23/10 , C07C63/10 , C07C69/63 , C07C35/52 , C07C35/48
摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides. When a complex compound comprising HF and a base is reacted under irradiation with microwave, fluorination at a specific position which is difficult in accordance with conventional methods proceeds highly selectively, efficiently in a short time and safely.

3. 发明申请

US20080319228A1 Method of fluorination 失效
标题翻译：氟化方法
公开(公告)号：US20080319228A1
公开(公告)日：2008-12-25
申请号：US12068481
申请日：2008-02-07
申请人： Shoji Hara , Tsuyoshi Fukuhara
发明人： Shoji Hara , Tsuyoshi Fukuhara
IPC分类号： C07C211/15
CPC分类号： C07D239/30 , C07B39/00 , C07B2200/09 , C07C17/093 , C07C17/16 , C07C17/18 , C07C29/64 , C07C51/60 , C07C67/307 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2601/20 , C07C2603/74 , C07H1/00 , C07H9/04 , C07H13/04 , C07H13/08 , C07H19/06 , C07C22/08 , C07C21/18 , C07C19/08 , C07C23/38 , C07C23/02 , C07C23/10 , C07C63/10 , C07C69/63 , C07C35/52 , C07C35/48
摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides. When a complex compound comprising HF and a base is reacted under irradiation with microwave, fluorination at a specific position which is difficult in accordance with conventional methods proceeds highly selectively, efficiently in a short time and safely.
摘要翻译：一种氟化方法，包括使单糖，寡糖，多糖，这些糖与蛋白质和脂质结合形成的复合糖和多元醇的多元醇，醛，酮和酸的糖，以及这些化合物的衍生物和缩合物与氟化剂的代表性反应通过通式（I）热或照射微波或具有波长在微波区域周围的波长的电磁波。根据该方法，可以根据常规方法在150〜200℃的范围内的温度下安全地进行选择位置的氟化。包含微波照射或微波周围波长的电磁波的上述方法可以应用于除糖以外的基材。当包含HF和碱的络合物在微波照射下反应时，根据常规方法困难的特定位置的氟化在高速选择性地进行，在短时间内和安全地进行。

4. 发明申请

US20070191631A1 Process for producing optically active fluorochemical 失效
标题翻译：光学活性含氟化合物的制备方法
公开(公告)号：US20070191631A1
公开(公告)日：2007-08-16
申请号：US10591698
申请日：2005-03-02
申请人： Shoji Hara , Tsuyoshi Fukuhara
发明人： Shoji Hara , Tsuyoshi Fukuhara
IPC分类号： C07C69/63
CPC分类号： C07C29/124 , C07B39/00 , C07B53/00 , C07B2200/07 , C07C67/18 , C07D317/22 , C07D317/24 , C07C69/92 , C07C69/76 , C07C31/38
摘要： The present invention provides a process for producing an optically active fluoro compound represented by formula (3) through reaction between a specific fluoroamine and an optically active diol; and a process for producing an optically active fluoroalcohol through hydrolysis of the optically active fluoro compound. According to the process of the present invention, such optically active fluoro compounds and optically active fluoroalcohols can be produced at high optical purity and high yield in a simple manner. Such optically active fluoroalcohols are a useful source for producing drugs, pesticides, and other functional chemicals.
摘要翻译：本发明提供一种通过特定的氟代胺和光学活性的二醇之间的反应制备由式（3）表示的光学活性的氟化合物的方法; 以及通过光学活性氟化合物的水解生产光学活性氟代醇的方法。根据本发明的方法，可以简单的方式以高光学纯度和高产率制备这种光学活性氟化合物和光学活性氟代醇。这种光学活性氟代醇是生产药物，杀虫剂和其它功能性化学物质的有用来源。

5. 发明授权

US08093429B2 Fluoroamine having perfluoroalkyl group, process for producing the same, method of fluorination therewith, and method of recovering amide having perfluoroalkyl group 失效
标题翻译：具有全氟烷基的氟胺，其制造方法，其氟化方法以及回收具有全氟烷基的酰胺的方法
公开(公告)号：US08093429B2
公开(公告)日：2012-01-10
申请号：US12302362
申请日：2007-05-31
申请人： Toshio Hidaka , Takafumi Yoshimura , Shoji Hara , Tsuyoshi Fukuhara
发明人： Toshio Hidaka , Takafumi Yoshimura , Shoji Hara , Tsuyoshi Fukuhara
IPC分类号： C07C211/27
CPC分类号： C07C211/29 , C07C231/12 , Y02P20/582 , C07C233/65
摘要： Provided are a fluorous-tag-introduced fluoroamine of a general formula (I), its production method, a method of fluorination of a substrate having functional group containing oxygen with the fluoroamine serving as a fluorinating agent, and a method of recovering a fluorous-tag-introduced amide after the fluorination. The fluoroamine and its production method, as well as the fluorination method with the fluoroamine and the method of recovery of a fluorous-tag-introduced amide are ecological and advantageous in industrial use, as the load for separating and collecting the product after the fluorination with the fluoroamine serving as a fluorinating agent is small. (In the formula, R0 is an alkyl group or an aryl group having substituent(s) of Rf—(CH2)m—; Rf is a perfluoroalkyl group; m is from 0 to 2; R1 and R2 each are an alkyl group or an aryl group.)
摘要翻译：提供了通式（I）的氟标记导入的氟胺，其制备方法，含氟氧基官能团的底物氟化作为氟化剂的方法，以及回收氟 - 标签引入酰胺后氟化。氟胺及其制备方法以及氟胺的氟化方法和引入氟标签的酰胺的回收方法在工业上是生态和有利的，作为在氟化后分离和收集产物的负载作为氟化剂的氟胺是小的。（式中，R 0为具有Rf - （CH 2）m - 的取代基的烷基或芳基，Rf为全氟烷基，m为0〜2，R 1和R 2各自为烷基或芳基）

6. 发明授权

US07829741B2 Process for producing α, α-difluoroamine 失效
标题翻译：制备α，α-二氟胺的方法
公开(公告)号：US07829741B2
公开(公告)日：2010-11-09
申请号：US11718526
申请日：2005-10-20
申请人： Tsuyoshi Fukuhara , Shoji Hara , Toshio Hidaka
发明人： Tsuyoshi Fukuhara , Shoji Hara , Toshio Hidaka
IPC分类号： C07C209/68 , C07C209/74
CPC分类号： C07C209/74 , C07C213/08 , C07D233/02 , C07C211/29 , C07C217/58
摘要： A process for producing an α,α-difluoroamine which comprises using hydrogen fluoride and a Lewis base in specific amounts in the halogen-fluorine exchange reaction using an α,α-dihaloamine as the substrate. The process can be industrially applied, enables to obtain the object compound in a short time at a great yield and can be conducted easily with excellent productivity.
摘要翻译：一种制备α，α-二氟胺的方法，其包括使用α，α-二卤代胺作为底物，在卤素 - 氟交换反应中使用氟化氢和路易斯碱。该工艺可以在工业上应用，能够在短时间内以大的收率获得目标化合物，并且可以以优异的生产率容易地进行。

7. 发明申请

US20060014972A1 Method of fluorination 失效
标题翻译：氟化方法
公开(公告)号：US20060014972A1
公开(公告)日：2006-01-19
申请号：US10537437
申请日：2003-12-01
申请人： Shoji Hara , Tsuyoshi Fukuhara
发明人： Shoji Hara , Tsuyoshi Fukuhara
IPC分类号： C07J53/00 , C07G17/00
CPC分类号： C07D239/30 , C07B39/00 , C07B2200/09 , C07C17/093 , C07C17/16 , C07C17/18 , C07C29/64 , C07C51/60 , C07C67/307 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2601/20 , C07C2603/74 , C07H1/00 , C07H9/04 , C07H13/04 , C07H13/08 , C07H19/06 , C07C22/08 , C07C21/18 , C07C19/08 , C07C23/38 , C07C23/02 , C07C23/10 , C07C63/10 , C07C69/63 , C07C35/52 , C07C35/48
摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides. When a complex compound comprising HF and a base is reacted under irradiation with microwave, fluorination at a specific position which is difficult in accordance with conventional methods proceeds highly selectively, efficiently in a short time and safely.
摘要翻译：一种氟化方法，包括使单糖，寡糖，多糖，这些糖与蛋白质和脂质结合形成的复合糖和多元醇的多元醇，醛，酮和酸的糖，以及这些化合物的衍生物和缩合物与氟化剂的代表性反应通过通式（I）热或照射微波或具有波长在微波区域周围的波长的电磁波。根据该方法，可以根据常规方法在150〜200℃的范围内的温度下安全地进行选择位置的氟化。包含微波照射或微波周围波长的电磁波的上述方法可以应用于除糖以外的基材。当包含HF和碱的络合物在微波照射下反应时，根据常规方法困难的特定位置的氟化在高速选择性地进行，在短时间内和安全地进行。

8. 发明授权

US06784327B2 Process for the production of fluorinated organic compounds and fluorinating agents 有权
标题翻译：用于生产氟化有机化合物和氟化剂的方法
公开(公告)号：US06784327B2
公开(公告)日：2004-08-31
申请号：US10296942
申请日：2002-12-10
申请人： Norihiko Yoneda , Tsuyoshi Fukuhara , Kazuhiro Shimokawa , Kenji Adachi , Satoshi Oishi
发明人： Norihiko Yoneda , Tsuyoshi Fukuhara , Kazuhiro Shimokawa , Kenji Adachi , Satoshi Oishi
IPC分类号： C07C1710
CPC分类号： C07C67/307 , C07B39/00 , C07C17/093 , C07C17/16 , C07C17/18 , C07C29/64 , C07C37/62 , C07C41/22 , C07C45/30 , C07C51/60 , C07C201/12 , C07C209/74 , C07C245/04 , C07C245/06 , C07C319/20 , C07C2601/14 , C07C2603/18 , C07C211/52 , C07C323/03 , C07C323/22 , C07C323/52 , C07C323/60 , C07C323/65 , C07C33/46 , C07C205/11 , C07C69/75 , C07C53/42 , C07C39/27 , C07C49/697 , C07C49/687 , C07C69/716 , C07C43/225
摘要： A process for the production of a fluorinated organic compound, characterized by fluorinating an organic compound having a hydrogen atoms using IF5; and a novel fluorination process for fluorinating an organic compound having a hydrogen atoms by using a fluorinating agent containing IF5 and at least one member selected from the group consisting of acids, bases, salts and additives.
摘要翻译：一种制备氟化有机化合物的方法，其特征在于使用IF 5氟化具有氢原子的有机化合物; 以及通过使用含有IF 5的氟化剂和选自酸，碱，盐和添加剂中的至少一种的氟化有氢化物的有机化合物的新型氟化方法。

9. 发明授权

US4707536A Catalytic preparation of aromatic polyketone from phosgene and aromatic ether or sulfide 失效
标题翻译：从光气和芳香醚或硫化物催化制备芳香族聚酮
公开(公告)号：US4707536A
公开(公告)日：1987-11-17
申请号：US804615
申请日：1985-12-05
申请人： Norihiko Yoneda , Tsuyoshi Fukuhara , Seiichi Nozawa
发明人： Norihiko Yoneda , Tsuyoshi Fukuhara , Seiichi Nozawa
IPC分类号： C08G61/12 , C08G67/00 , C08G65/00 , C08G83/00
CPC分类号： C08G61/127 , C08G67/00
摘要： Disclosed herein is a process for producing aromatic polyketone, comprising reacting a compound represented by the formula (I): ##STR1## wherein each of R.sup.1 to R.sup.12 represents a hydrogen atom, a halogen atom, a hydrocarbon group or an alkoxy group; X.sup.1 and X.sup.2 respectively represent an oxygen atom or a sulfur atom and n is an integer of from 0 to 5,with phosgene (i) in the presence of a fluoroalkanesulfonic acid or (ii) in hydrogen fluoride in the presence of boron trifluoride at a temperature of from 65.degree. to 90.degree. C.
摘要翻译：本文公开了一种制备芳族聚酮的方法，包括使由式（I）表示的化合物：其中R 1至R 12各自表示氢原子，卤素原子，烃基或烷氧基 ; X1和X2分别表示氧原子或硫原子，n表示0〜5的整数，光气（i）在氟烷基磺酸的存在下，或（ii）在氟化氢中，在三氟化硼存在下，在温度从65℃到90℃

10. 发明申请

US20090281309A1 METHOD FOR PRODUCING 2-OXAZOLINE ANALOGUE OR 1,3-OXAZINE ANALOGUE 失效
标题翻译：生产2-氧杂环丙烷类似物或1,3-氧化物类似物的方法
公开(公告)号：US20090281309A1
公开(公告)日：2009-11-12
申请号：US12065347
申请日：2006-08-30
申请人： Shoji Hara , Tsuyoshi Fukuhara , Toshio Hidaka
发明人： Shoji Hara , Tsuyoshi Fukuhara , Toshio Hidaka
IPC分类号： C07D263/12 , C07D265/08
CPC分类号： C07D263/12 , C07D263/16 , C07D263/56 , C07D265/08 , C07D277/10
摘要： The present invention is a method for producing a 2-oxazoline analogue or a 1,3-oxazine analogue represented by the following general formula (3) by reacting a 1,2-aminoalcohol compound or a 1,2-aminothiol compound with an α,α-dihaloamine compound.(In the formula, n represents 0 or 1, and R represents an oxygen atom or a sulfur atom. R1, R2 and R3 each represents an atom or a group shown in Group 1 to Group 3, and R0 represents an atom or a group shown in Group 2 or Group 3. Two or more of R1, R2 and R3 may be bonded to each other to form a ring.Group 1: a hydrogen atom, a halogen atom, a nitro group, a cyano group, a formyl group, a carboxyl group, a sulfonyl group, a sulfinoyl group or a sulfenyl group;Group 2: an alkyl group, which may have an arbitrary substituent, an aryl group or an aralkyl group; andGroup 3: an alkyl-substituted, aryl-substituted or aralkyl-substituted oxy group, a carbonyl group, an oxycarbonyl group, a carbonyloxy group, a thio group, a sulfonyl group, a sulfinoyl group or a sulfenyl group)
摘要翻译：本发明是通过使1,2-氨基醇化合物或1,2-氨基硫醇化合物与α-羟基喹啉类化合物反应来制备由以下通式（3）表示的2-恶唑啉类似物或1,3-恶嗪类似物的方法，，α-二卤代胺化合物。（式中，n表示0或1，R表示氧原子或硫原子，R1，R2和R3各自表示1〜3族所示的原子或基团，R0表示原子或基团）第1组：氢原子，卤素原子，硝基，氰基，甲酰基等。另外，R 1，R 2，R 3可以相互结合形成环。，羧基，磺酰基，亚磺酰基或亚磺酰基;第2族：可以具有任意取代基的烷基，芳基或芳烷基;第3族：烷基取代的芳基 - 取代或芳烷基取代的氧基，羰基，氧羰基，羰氧基，硫基，磺酰基，亚磺酰基或亚磺酰基）

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