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1. 发明授权

US5096878A Method for production of bi-containing superconducting ceramics laminates 失效
标题翻译：用于生产含二氧化钛超级陶瓷层压板的方法
公开(公告)号：US5096878A
公开(公告)日：1992-03-17
申请号：US647216
申请日：1991-01-28
申请人： Kazutomo Hoshino , Shigeru Yamazaki , Hidefusa Takahara , Masao Fukutomi
发明人： Kazutomo Hoshino , Shigeru Yamazaki , Hidefusa Takahara , Masao Fukutomi
IPC分类号： B32B18/00 , C04B35/45 , H01L39/24
CPC分类号： B32B18/00 , C04B35/4521 , C04B37/021 , H01L39/2461 , C04B2235/6565 , C04B2235/6567 , C04B2237/34 , C04B2237/408 , C04B2237/704 , C04B2237/706 , Y10S505/741 , Y10S505/742
摘要： A method for making superconductive ceramics laminates comprises forming a thick film of a composite oxide comprising bismuth, strontium, calcium, copper and oxygen on a flat plane of a substrate, and orienting and crystallizing the thus formed film by heat treatment to cause the c-axis of composite oxide crystals to be substantially perpendicular to said flat plane of said substrate. An intermediate layer formed of a noble metal, MgO, SrTiO.sub.3, yttria-stabilized zirconia or an oxide of a superconductive ceramics-constituting element may be interposed between the film and the substrate.

2. 发明授权

US5663528A Oxide superconductive wire and process for manufacturing the same 失效
标题翻译：氧化物超导线及其制造方法
公开(公告)号：US5663528A
公开(公告)日：1997-09-02
申请号：US170959
申请日：1993-12-21
申请人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
发明人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
IPC分类号： C01G29/00 , C01G1/00 , H01B12/04 , H01B13/00 , H01L39/14 , H01L39/24 , B32B9/00
CPC分类号： H01L39/248 , H01L39/143 , Y10S505/884
摘要： A clad superconductive wire or tape of an oxide superconductive material and a silver-copper alloy base containing 0.05-90 atomic % copper or a silver alloy. The silver-copper alloy base contains one or more elements selected from the group of Zr, Hf, Al, V, Nb and Ta in amounts of from 0.01-3 atomic %, or contains Au in amounts of 0.01-10 atomic %. The silver alloy contains one or more elements selected from the group of Ti, Zr, Hf, V, Nb, Ta, Mg, Ca, Sr and Ba in amounts of from 0.01 to 3 atomic %, or one or more elements selected from the group of Au, Al, Ga, In and Sn in amounts of 0.05 to 5 atomic %. The base material is filled with a Bi-containing oxide of Bi.sub.1 Pb.sub.u Sr.sub.x Ca.sub.y Cu.sub.z O.sub.w wherein u=0-0.3, X=0.8-1.2, y=0.2-1.2, and z=0.8-2.0, and processed to obtain a superconductive wire or tape having enhanced mechanical strength, superconductivity and plastic workability.
摘要翻译：包覆超导线或氧化物超导材料的带和含有0.05-90原子％铜或银合金的银 - 铜合金基体。银 - 铜合金基体含有选自Zr，Hf，Al，V，Nb和Ta中的一种或多种元素，其量为0.01-3原子％，或含有0.01-10原子％的Au。银合金含有选自Ti，Zr，Hf，V，Nb，Ta，Mg，Ca，Sr和Ba中的一种或多种元素，其含量为0.01至3原子％，或选自以下的一种或多种元素： Au，Al，Ga，In和Sn的含量为0.05〜5原子％。用Bi1PbuSrxCayCuzOw的Bi的氧化物填充基材，其中u = 0-0.3，X = 0.8-1.2，y = 0.2-1.2和z = 0.8-2.0，并加工得到具有增强的超导线或带机械强度，超导性和塑性加工性。

3. 发明授权

US07132388B1 High-temperature oxide superconductor 失效
标题翻译：高温氧化物超导体
公开(公告)号：US07132388B1
公开(公告)日：2006-11-07
申请号：US07293465
申请日：1989-01-04
申请人： Hiroshi Maeda , Yoshiaki Tanaka , Masao Fukutomi , Toshihisa Asano
发明人： Hiroshi Maeda , Yoshiaki Tanaka , Masao Fukutomi , Toshihisa Asano
IPC分类号： C04B101/00 , H01L12/00
CPC分类号： C04B35/4521 , H01L39/126 , Y10S505/782
摘要： The present invention provides a high-temperature oxide superconductors, which comprises an oxide expressed as (Bi1-xAx)—B—C—Cu oxide (where, A is Sb and/or AS; B and C are elements different from each other, each being one or more elements selected from the group consisting of Be, Mg, Ca, Sr and Ba; and x is characterized by 0≦x≦1). According to the present invention, it is possible to manufacture a high-temperature oxide superconductor having a transition temperature of over 100 K and not containg a rare-earth element at all, and to manufacture an excellent superconductor in reliability and stability easilier than doing conventional superconductors such as Y—Ba type ones.
摘要翻译：本发明提供了一种高温氧化物超导体，其包含以（Bi 1-x N A x S） - BC-Cu氧化物（其中A为Sb 和/或AS; B和C是彼此不同的元素，各自为选自Be，Mg，Ca，Sr和Ba的一种或多种元素; x的特征在于0≤x≤1）。根据本发明，可以制造转变温度超过100K的高温氧化物超导体，根本不包含稀土元素，并且制造优良的超导体，其可靠性和稳定性比常规方法更容易超导体如Y-Ba型。

4. 发明授权

US5145829A Method for manufacturing oxide high-temperature superconductor 失效
标题翻译：氧化物高温超导体的制造方法
公开(公告)号：US5145829A
公开(公告)日：1992-09-08
申请号：US396620
申请日：1989-08-22
申请人： Toshihisa Asano , Yoshiaki Tanaka , Masao Fukutomi , Hiroshi Maeda
发明人： Toshihisa Asano , Yoshiaki Tanaka , Masao Fukutomi , Hiroshi Maeda
IPC分类号： C04B35/00 , C01G1/00 , C04B35/45 , H01B12/00 , H01B13/00 , H01L39/24
CPC分类号： H01L39/2419 , C04B35/4525 , Y10S505/739 , Y10S505/74
摘要： A compacted and highly oriented microstructure of the bulk-shaped Bi-Sr-Ca-Cu-O system oxide superconductor is obtained by the intermediate pressing method of the present invention. The growth rate of the high critical temperature phase in the bulk of Pb-doped Bi-Sr-Ca-Cu-O system oxide superconductor is also much improved and the sintering duration for obtaining a single phase having a high critical temperature is shorteneed by this method. Additionally, a higher critcal current density of Bi-Sr-Ca-Cu-O system oxide superconductor is obtained by the working under pressure process after cooling between a first and a second sintering step. Furthermore, the magnetic field dependence of the critical current density of Bi-Sr-Ca-Cu-O system oxide superconductor is also improved by the method of the present invention. The thus intermediate pressing process between the first and second sintering step of the present invention may be applied so easily as to facilitate the manufacture of tapes, wires, discs or the like of the Bi-Sr-Ca-Cu-O system oxide superconductor.
摘要翻译：通过本发明的中间压制方法获得块状Bi-Sr-Ca-Cu-O系氧化物超导体的压实且高度取向的微观结构。 Pb掺杂的Bi-Sr-Ca-Cu-O体系氧化物超导体的大部分高临界温度相的生长速度也大大提高，并且获得具有高临界温度的单相的烧结持续时间通过这种短路方法。另外，Bi-Sr-Ca-Cu-O系氧化物超导体的Critcal电流密度通过在第一和第二烧结步骤冷却之后的加压工艺得到。此外，通过本发明的方法也提高了Bi-Sr-Ca-Cu-O系氧化物超导体的临界电流密度的磁场依赖性。本发明的第一和第二烧结步骤之间的这样的中间压制方法可以容易地应用，以便于Bi-Sr-Ca-Cu-O系氧化物超导体的带，线，盘等的制造。

5. 发明授权

US06271473B1 Oxide superconductive wire and process for manufacturing the same 失效
标题翻译：氧化物超导线及其制造方法
公开(公告)号：US06271473B1
公开(公告)日：2001-08-07
申请号：US08856698
申请日：1997-05-15
申请人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
发明人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
IPC分类号： H01B1204
CPC分类号： H01L39/248 , H01L39/143 , Y10S505/884
摘要： A clad superconductive wire or tape of an oxide superconductive material and a silver-copper alloy base containing 0.05-90 atomic % a copper or a silver alloy. The silver-copper alloy base contains one or more elements selected from the group of Zr, Hf, Al, V, Nb and Ta in amounts of from 0.01-3 atomic %, or contains Au in amount of 0.01-10 atomic %. The silver alloy contains one or more elements selected from the group of Ti, Zr, Hf, V, Nb, Ta, Mg, Ca, Sr and Ba in amounts of from 0.01 to 3 atomic %, or one or more elements selected from the group of Au, Al, Ga, In and Sn in amounts of 0.05 to atomic %. The base material is filled with a Bi-containing oxide of Bi1PbuSrxCayCuzOw wherein u=0-0.3, X=0.8-1.2, y=0.2-1.2, and z=0.8-2.0, and processed to obtain a superconductive wire or tape having enhanced mechanical strength, superconductivity and plastic workability.
摘要翻译：包覆超导线或氧化物超导材料的带和含有0.05-90原子％铜或银合金的银 - 铜合金基体。银 - 铜合金基体含有选自Zr，Hf，Al，V，Nb和Ta中的一种或多种元素，其量为0.01-3原子％，或含有0.01-10原子％的Au。银合金含有选自Ti，Zr，Hf，V，Nb，Ta，Mg，Ca，Sr和Ba中的一种或多种元素，其含量为0.01至3原子％，或选自以下的一种或多种元素： Au，Al，Ga，In和Sn的量为0.05〜原子％。用Bi1PbuSrxCayCuzOw的Bi的氧化物填充基材，其中u = 0-0.3，X = 0.8-1.2，y = 0.2-1.2和z = 0.8-2.0，并加工得到具有增强的超导线或带机械强度，超导性和塑性加工性。

6. 发明授权

US06246007B1 Oxide superconductive wire and process for manufacturing the same 失效
标题翻译：氧化物超导线及其制造方法
公开(公告)号：US06246007B1
公开(公告)日：2001-06-12
申请号：US08856699
申请日：1997-05-15
申请人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
发明人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
IPC分类号： H01L3924
CPC分类号： H01L39/248 , H01L39/143 , Y10S505/884
摘要： A clad superconductive wire or tape of an oxide superconductive material and a silver-copper alloy base containing 0.05-90 atomic % copper or a silver alloy. The silver-copper alloy base contains one or more elements selected from the group of Zr, Hf, Al, V, Nb and Ta in amounts of from 0.01-3 atomic %, or contains Au in amount of 0.01-10 atomic %. The silver alloy contains one or more elements selected from the group of Ti, Zr, Hf, V, Nb, Ta, Mg, Ca, Sr and Ba in amounts of from 0.01 to 3 atomic %, or one or more elements selected from the group of Au, Al, Ga, In and Sn in amounts of 0.05 to atomic %. The base material is filled with a Bi-containing oxide of Bi1PbuSrxCayCuzOw wherein u=0-0.3, X=0.8-1.2, y=0.2-1.2, and z=0.8-2.0, and processed to obtain a superconductive wire or tape having enhanced mechanical strength, superconductivity and plastic workability.
摘要翻译：包覆超导线或氧化物超导材料的带和含有0.05-90原子％铜或银合金的银 - 铜合金基体。银 - 铜合金基体含有选自Zr，Hf，Al，V，Nb和Ta中的一种或多种元素，其含量为0.01-3原子％，或含有0.01-10原子％的Au。银合金含有选自Ti，Zr，Hf，V，Nb，Ta，Mg，Ca，Sr和Ba中的一种或多种元素，其含量为0.01至3原子％，或选自以下的一种或多种元素： Au，Al，Ga，In和Sn的量为0.05〜原子％。用Bi1PbuSrxCayCuzOw的Bi的氧化物填充基材，其中u = 0-0.3，X = 0.8-1.2，y = 0.2-1.2和z = 0.8-2.0，并加工得到具有增强的超导线或带机械强度，超导性和塑性加工性。

7. 发明授权

US5827801A Oxide superconductive wire and process for manufacutring the same 失效
标题翻译：氧化物超导线及其制造方法
公开(公告)号：US5827801A
公开(公告)日：1998-10-27
申请号：US856702
申请日：1997-05-15
申请人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
发明人： Yoshiaki Tanaka , Tomoyuki Yanagiya , Fumiaki Matsumoto , Masao Fukutomi , Toshihisa Asano , Kazunori Komori , Hiroshi Maeda
IPC分类号： C01G29/00 , C01G1/00 , H01B12/04 , H01B13/00 , H01L39/14 , H01L39/24 , B32B9/00
CPC分类号： H01L39/248 , H01L39/143 , Y10S505/884
摘要： A clad superconductive wire or tape of an oxide superconductive material and a silver-copper alloy base containing 0.05-90 atomic % copper or a silver alloy. The silver-copper alloy base contains one or more elements selected from the group of Zr, Hf, Al, V, Nb and Ta in amounts of from 0.01-3 atomic %, or contains Au in amount of 0.01-10 atomic %. The silver alloy contains one or more elements selected from the group of Ti, Zr, Hf, V, Nb, Ta, Mg, Ca, Sr and Ba in amounts of from 0.01 to 3 atomic %, or one or more elements selected from the group of Au, Al, Ga, In and Sn in amounts of 0.05 to atomic %. The base material is filled with a Bi-containing oxide of Bi.sub.1 Pb.sub.u Sr.sub.x Ca.sub.y Cu.sub.z O.sub.w wherein u=0-0.3, x=0.8-1.2, y=0.2-1.2, and z=0.8-2.0, and processed to obtain a superconductive wire or tape having enhanced mechanical strength, superconductivity and plastic workability.
摘要翻译：包覆超导线或氧化物超导材料的带和含有0.05-90原子％铜或银合金的银 - 铜合金基体。银 - 铜合金基体含有选自Zr，Hf，Al，V，Nb和Ta中的一种或多种元素，其量为0.01-3原子％，或含有0.01-10原子％的Au。银合金含有选自Ti，Zr，Hf，V，Nb，Ta，Mg，Ca，Sr和Ba中的一种或多种元素，其含量为0.01至3原子％，或选自以下的一种或多种元素： Au，Al，Ga，In和Sn的量为0.05〜原子％。用Bi1PbuSrxCayCuzOw的Bi的氧化物填充基材，其中u = 0-0.3，x = 0.8-1.2，y = 0.2-1.2和z = 0.8-2.0，并处理以获得具有增强的超导线机械强度，超导性和塑性加工性。

8. 发明授权

US5567288A Crystal-oriented thin film manufacturing apparatus 失效
标题翻译：水晶取向薄膜制造装置
公开(公告)号：US5567288A
公开(公告)日：1996-10-22
申请号：US313339
申请日：1994-09-27
申请人： Masao Fukutomi , Shigeki Aoki , Kazunori Komori , Toshihisa Asano , Yoshiaki Tanaka , Hiroshi Maeda
发明人： Masao Fukutomi , Shigeki Aoki , Kazunori Komori , Toshihisa Asano , Yoshiaki Tanaka , Hiroshi Maeda
IPC分类号： C01G1/00 , C23C14/08 , C23C14/22 , C23C14/34 , C23C14/50 , C30B23/02 , C30B23/08 , C30B29/16
CPC分类号： C23C14/345 , C23C14/083 , C23C14/225 , C23C14/34 , C23C14/50 , C30B23/002
摘要： A substrate electrode having a plurality of substrate holders capable of causing a substrate to tilt by an arbitrary angle .theta. relative to the horizontal plane is provided. A plurality of auxiliary electrodes are arranged substantially vertically below the substrate electrode and between the substrate electrode and a target. The substrate electrode and the auxiliary electrodes are electrically insulated from the target. Bias voltage applied to the substrate electrode and the auxiliary electrodes causes the plasma boundary between the cathode dark space and the negative glow to form a cathodic plasma space having a parabolic section, thus forming a crystal-oriented thin film on the substrate surface.
摘要翻译：提供了具有能够使基板相对于水平面倾斜任意角度θ的多个基板保持器的基板电极。多个辅助电极基本上垂直地布置在衬底电极下方以及衬底电极和靶之间。基板电极和辅助电极与靶电绝缘。施加到基板电极和辅助电极的偏压导致阴极黑暗空间和负辉光之间的等离子体边界形成具有抛物面部分的阴极等离子体空间，从而在基板表面上形成晶体取向的薄膜。

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