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1. 发明授权

US4076923A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4076923A
公开(公告)日：1978-02-28
申请号：US669299
申请日：1976-03-22
申请人： Kazuo Matsuura , Masaomi Matsuzaki , Fumiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Kazuo Matsuura , Masaomi Matsuzaki , Fumiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F10/00 , C08F10/10 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00 , C08F10/10
摘要： According to the present invention, there is provided a process for preparing polyolefins which comprises polymerizing or copolymerizing olefins using as catalyst a component consisting of a solid carrier and a titanium compound and/or a vanadium compound supported thereon, and an organometallic compound, said solid carrier consisting of a product obtained by mixing and heating an aluminum oxide and an ammonium sulfate.
摘要翻译：根据本发明，提供了一种制备聚烯烃的方法，其包括使用作为催化剂的烯烃聚合或共聚烯烃，所述组分由固体载体和/或其上负载的钒化合物和/或有机金属化合物组成，所述固体载体由通过混合和加热氧化铝和硫酸铵获得的产物组成。

2. 发明授权

US4027088A Process of preparing polyolefins 失效
标题翻译：制备聚烯烃的方法
公开(公告)号：US4027088A
公开(公告)日：1977-05-31
申请号：US595371
申请日：1975-07-11
申请人： Kazuo Matsuura , Masaomi Matsuzaki , Fumiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Kazuo Matsuura , Masaomi Matsuzaki , Fumiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F4/00 , C08F4/60 , C08F10/00 , C08F10/10 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00 , C08F10/10
摘要： A process of polymerizing or copolymerizing a class of olefins is carried out in the presence of a catalyst, which catalyst comprises one of more solid compounds selected as a carrier from the group consisting of an oxide, a double oxide and a hydroxide of halogen-free magnesium and/or calcium. The carrier is treated by direct contact with gaseous sulfur dioxide (SO.sub.2) under a gaseous atmosphere. A titanium and/or vanadium compound, viz. Ziegler catalyst component, is deposited on the treated carrier and activated by an organometal compound.
摘要翻译：聚合或共聚一类烯烃的方法是在催化剂的存在下进行的，该催化剂包括选自氧化物，双氧化物和无卤素氢氧化物的更多的固体化合物之一作为载体镁和/或钙。在气态气氛下，通过与气态二氧化硫（SO2）直接接触来处理载体。钛和/或钒化合物，即齐格勒催化剂组分沉积在经处理的载体上并被有机金属化合物活化。

3. 发明授权

US4088812A Process for preparing polyolefins 失效
标题翻译：聚烯烃的制备方法
公开(公告)号：US4088812A
公开(公告)日：1978-05-09
申请号：US752003
申请日：1976-12-20
申请人： Kazuo Matuura , Masaomi Matsuzaki , Humiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
发明人： Kazuo Matuura , Masaomi Matsuzaki , Humiaki Oshimi , Nobuyuki Kuroda , Mituji Miyoshi
IPC分类号： C08F4/02 , C08F4/62 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00
摘要： This invention discloses an improved catalyst for the polymerization or copolymerization of olefins, and a process for preparing polyolefins which comprises polymerizing or copolymerizing olefins using the said catalyst. According to the invention there is provided a process for preparing polyolefins by polymerizing or copolymerizing olefins using as a catalyst at least one compound selected from the group consisting of a titanium compound and a vanadium compound supported on a solid carrier, and an organometallic compound, said solid carrier comprising a product obtained by treatment with SO.sub.3 of at least one member selected from the group consisting of an oxide of Group II-IV metals of the Periodic Table and a double oxide of the said oxide and other oxide, which other oxide may be another oxide of Group II-IV metals of the Periodic Table or may be an oxide of other Group metals of the same Table.
摘要翻译：本发明公开了一种用于烯烃聚合或共聚的改进催化剂，以及一种制备聚烯烃的方法，该方法包括使用所述催化剂聚合或共聚烯烃。根据本发明，提供了一种通过使用至少一种选自负载在固体载体上的钛化合物和钒化合物和有机金属化合物的化合物作为催化剂聚合或共聚烯烃的方法，所述方法固体载体，其包含通过用SO 3处理由选自元素周期表中的II-IV族金属的氧化物和所述氧化物和其它氧化物的二氧化物中的至少一种获得的产物，其它氧化物可以是元素周期表第II-Ⅳ族金属的另一种氧化物，或者可以是同一表中其他族金属的氧化物。

4. 发明授权

US4154915A Process for producing polyolefins 失效
标题翻译：生产聚烯烃的方法
公开(公告)号：US4154915A
公开(公告)日：1979-05-15
申请号：US575788
申请日：1975-05-08
申请人： Kazuo Matsuura , Masaomi Matsuzaki , Toru Nakamura , Nobuyuki Kuroda , Mitsuji Miyoshi
发明人： Kazuo Matsuura , Masaomi Matsuzaki , Toru Nakamura , Nobuyuki Kuroda , Mitsuji Miyoshi
IPC分类号： C08F10/00 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00
摘要： An improved catalyst system is disclosed for use in the polymerization or copolymerization of olefins. The catalyst comprises a transition metal compound, an organometal compound and a composite carrier. This carrier is constituted by a SO.sub.3 treated alumina and a magnesium and/or a calcium compound. The polymerization or copolymerization of olefins such as ethylene, propylene and 1-butene is effected under conditions similar to those for reactions by means of Ziegler catalysts, but the resulting polyolefins have a wider molecular weight distribution, viz, a larger flow parameter as required for extrusion or blow molding.
摘要翻译：公开了用于烯烃聚合或共聚的改进的催化剂体系。催化剂包括过渡金属化合物，有机金属化合物和复合载体。该载体由SO 3处理的氧化铝和镁和/或钙化合物构成。烯烃如乙烯，丙烯和1-丁烯的聚合或共聚在与通过齐格勒催化剂进行反应的条件类似的条件下进行，但是得到的聚烯烃具有更宽的分子量分布，挤出或吹塑。

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