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    • 5. 发明授权
    • Process for producing a monoglyceride-containing composition
    • 制备含单酸甘油酯的组合物的方法
    • US07767838B2
    • 2010-08-03
    • US10558156
    • 2004-06-03
    • Hiroki SawadaJiro HashimotoHaruya MinoToshitsugu Maeda
    • Hiroki SawadaJiro HashimotoHaruya MinoToshitsugu Maeda
    • C11C3/00
    • C11C3/06C11C3/02C11C3/10
    • The invention provides a process for producing a monoglyceride-containing composition by reacting glycerin with at least one kind of acyl-containing compound selected from fatty acid and glycerin ester, the reaction being conducted with a catalyst containing at least one metal selected from iron, cobalt and manganese in an amount of 0.1 to 60 ppm in terms of metal (weight ratio to the total weight of glycerin and the acyl-containing compound), as well as a process for producing a monoglyceride-containing composition by reacting glycerin with at least one kind of acyl-containing compound selected from fatty acid and glycerin ester, including a step of maintaining the amount of water at 500 to 5000 ppm in the reaction system after the degree of conversion in the reaction of glycerin with fatty acid reaches 90% or more based on the fatty acid, or during the ester exchange reaction of glycerin with glycerin ester.
    • 本发明提供了一种通过甘油与至少一种选自脂肪酸和甘油酯的含酰基化合物反应制备含单酸甘油酯的组合物的方法,该反应用含有至少一种选自铁,钴 和金属量为0.1〜60ppm的锰(与甘油和含酰基的化合物的总重量的重量比),以及通过使甘油与至少一种甘油反应生成含甘油单体的组合物的方法 包括选自脂肪酸和甘油酯的含酰基化合物的种类,包括在甘油与脂肪酸的反应中的转化度达到90%以上之后,在反应体系中保持500〜5000ppm的水量的步骤 基于脂肪酸,或甘油与甘油酯的酯交换反应。
    • 8. 发明申请
    • Process for producing a monoglyceride-containing composition
    • 制备含单酸甘油酯的组合物的方法
    • US20070129560A1
    • 2007-06-07
    • US10558156
    • 2004-06-03
    • Hiroki SawadaJiro HashimotoHaruya MinoToshitsugu Maeda
    • Hiroki SawadaJiro HashimotoHaruya MinoToshitsugu Maeda
    • C07C51/43
    • C11C3/06C11C3/02C11C3/10
    • The invention provides a process for producing a monoglyceride-containing composition by reacting glycerin with at least one kind of acyl-containing compound selected from fatty acid and glycerin ester, the reaction being conducted with a catalyst containing at least one metal selected from iron, cobalt and manganese in an amount of 0.1 to 60 ppm in terms of metal (weight ratio to the total weight of glycerin and the acyl-containing compound), as well as a process for producing a monoglyceride-containing composition by reacting glycerin with at least one kind of acyl-containing compound selected from fatty acid and glycerin ester, including a step of maintaining the amount of water at 500 to 5000 ppm in the reaction system after the degree of conversion in the reaction of glycerin with fatty acid reaches 90% or more based on the fatty acid, or during the ester exchange reaction of glycerin with glycerin ester.
    • 本发明提供了一种通过甘油与至少一种选自脂肪酸和甘油酯的含酰基化合物反应制备含单酸甘油酯的组合物的方法,该反应用含有至少一种选自铁,钴 和金属量为0.1〜60ppm的锰(与甘油和含酰基的化合物的总重量的重量比),以及通过使甘油与至少一种甘油反应生成含甘油单体的组合物的方法 包括选自脂肪酸和甘油酯的含酰基化合物的种类,包括在甘油与脂肪酸的反应中的转化度达到90%以上之后,在反应体系中保持500〜5000ppm的水量的步骤 基于脂肪酸,或甘油与甘油酯的酯交换反应。
    • 9. 发明授权
    • Cutting oil composition
    • 切割油组成
    • US06383991B1
    • 2002-05-07
    • US09647592
    • 2000-11-27
    • Jiro HashimotoToshiya HagiharaKazuhiko Nishimoto
    • Jiro HashimotoToshiya HagiharaKazuhiko Nishimoto
    • C10M10508
    • C10M107/34C10M125/26C10M169/04C10M2201/087C10M2201/10C10M2201/102C10M2201/105C10M2209/1033C10M2209/1045C10M2209/1055C10M2209/1065C10M2209/107C10M2209/1075C10M2209/1085C10M2209/1095C10M2215/042C10M2215/224C10N2240/401
    • The present invention relates to a cutting oil comprising (a) a polyether compound represented by the formula (I): R1O(EO)m(AO)nR2  (I) wherein each of R1 and R2, which may be identical or different, is hydrogen atom or a hydrocarbon group having 1 to 24 carbon atoms, at least one of which is a hydrocarbon group; EO is oxyethylene group; AO is an oxyalkylene group having 3 or 4 carbon atoms; and each of m and n is 1 to 50, wherein a sum of m and n is from 4 to 100; a cutting oil composition comprising the above cutting oil and an abrasive; a cutting method using the above cutting oil composition; and a process of cleaning a wafer, comprising the steps of cleaning a wafer obtainable by cutting an ingot with a wire saw using the above cutting oil composition; heating the resulting waste water to a temperature equal to or higher than a cloud point of a polyether compound represented by the formula (I) contained in the waste water, to allow separation into an oil phase and an aqueous phase; and removing the oil phase comprising the polyether compound from the waste water. According to the present invention, there can be obtained excellent dispersibility of the abrasive, and excellent re-dispersibility, cutting performance and workability when sedimented, and the object to be cut obtained after cutting can be easily cleaned.
    • 本发明涉及一种切削油,其包含(a)由式(I)表示的聚醚化合物:其中可以相同或不同的R 1和R 2各自为氢原子或具有1至24个碳原子的烃基 ,其中至少一个是烃基; EO是氧乙烯基; AO是具有3或4个碳原子的氧化烯基团; m和n分别为1〜50,m和n的和为4〜100; 包含上述切削油和磨料的切削油组合物; 使用上述切削油组合物的切削方法; 以及清洁晶片的方法,包括以下步骤:使用上述切削油组合物清洁通过用线锯切割锭块可获得的晶片; 将得到的废水加热至与废水中所含的式(I)所示的聚醚化合物的浊点相同或更高的温度,使其分离成油相和水相。 并从废水中除去包含聚醚化合物的油相。 根据本发明,可以获得磨料的优异的分散性,并且当沉降时优异的再分散性,切割性能和可加工性,并且可以容易地清洁切割后获得的待切割物体。