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1. 发明授权

US4720516A Composite material with improved properties 失效
标题翻译：具有改善性能的复合材料
公开(公告)号：US4720516A
公开(公告)日：1988-01-19
申请号：US450378
申请日：1982-12-16
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori , Yasuaki Ii
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori , Yasuaki Ii
IPC分类号： C08L23/26 , C08G18/62 , C08K3/00 , C08K5/17 , C08K5/29 , C08K7/00 , C08K7/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L77/00 , C08L77/10 , C08L101/00 , C08K7/06 , C08K7/22
CPC分类号： C08G18/6204 , C08L51/06
摘要： A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.
摘要翻译：一种聚烯烃树脂组合物，其包含用不饱和羧酸改性的聚烯烃，选自聚环氧化物，多异氰酸酯和多胺中的至少一种，以及增强剂。

2. 发明授权

US4550130A Composite material with improved properties 失效
公开(公告)号：US4550130A
公开(公告)日：1985-10-29
申请号：US584400
申请日：1984-02-28
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori , Yasuaki Ii
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori , Yasuaki Ii
IPC分类号： C08G18/62 , C08L51/06 , C08K7/00 , C08K7/06 , C08K7/22
CPC分类号： C08G18/6204 , C08L51/06
摘要： A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.

3. 发明授权

US4368283A Reinforced resin composition 失效
标题翻译：增强树脂组合物
公开(公告)号：US4368283A
公开(公告)日：1983-01-11
申请号：US279016
申请日：1981-06-30
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
IPC分类号： C08L67/00 , C08K5/09 , C08K5/098 , C08K5/10 , C08K5/103 , C08K7/14 , C08L7/00 , C08L21/00 , C08L23/00 , C08L67/02 , C08L101/00 , C08K5/15
CPC分类号： C08L67/02 , C08K5/098 , C08K5/103 , C08K7/14
摘要： Reinforced resin compositions exhibiting excellent heat resistance and appearance, and containing by weight: (a) at least 30% of a polyethylene terephthalate-type resin, (b) 5 to 60% glass fiber, (c) 0.03 to 5% of one or more salts of organic carboxylic acids with metals of the Groups Ia and IIa of the Periodic Table, and (d) 0.1 to 20% of a sorbitan derivative are disclosed. Optionally liquid or solid paraffin or polyethylene wax is incorporated in an amount of 0.3 to 5% based on the total composition may be incorporated if a white article is desired.Molded articles prepared from these compositions, high in heat resistance and uniform appearance, even if the thickness of the molded article is small or uneven or the molding operation is carried out at a relatively low mold temperature, are also disclosed. Molding temperature dependence and thickness dependence on the heat distortion temperature of the molded article are remarkably improved as well.
摘要翻译：表现出优异的耐热性和外观的增强树脂组合物，其重量含量：（a）至少30％的聚对苯二甲酸乙二醇酯类树脂，（b）5至60％的玻璃纤维，（c）0.03至5％的一种或公开了更多的有机羧酸盐与周期表的Ia和IIa族的金属，和（d）0.1-20％的脱水山梨醇衍生物。任选地，如果需要白色制品，则可以加入基于总组合物的0.3至5％的液体或固体石蜡或聚乙烯蜡。即使模制品的厚度小或不均匀，或者在相对较低的模具温度下进行模塑操作，也公开了由这些组合物制备的模制品，耐热性和均匀的外观。模塑制品的热变形温度依赖性和厚度依赖性也显着提高。

4. 发明授权

US4504608A Flame retardant polyester resin compositions 失效
标题翻译：阻燃聚酯树脂组合物
公开(公告)号：US4504608A
公开(公告)日：1985-03-12
申请号：US461228
申请日：1983-01-26
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
IPC分类号： C08L67/00 , C08G59/00 , C08K3/00 , C08K3/22 , C08K5/3492 , C08K5/3495 , C08L63/00 , C08L67/02 , C08L63/02
CPC分类号： C08K5/34924
摘要： Flame retardant reinforced with polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-30 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant component (I) to (II) is in the range of 0.2
摘要翻译：公开了用聚酯树脂组合物增强的阻燃剂，由下列通式（I）和（II）表示的玻璃纤维和阻燃剂体系以及三氧化锑。阻燃剂体系是1-20重量份组分（I）和2-30重量份组分（II）的混合物，只要阻燃组分的重量比（I）/（II） I）至（II）在0.2 <（I）/（II）<4的范围内，阻燃剂（I）+（II）的总量在3-40重量份的范围内。存在2至30重量份的三氧化锑，并且还存在5至60重量％的玻璃纤维，这两个百分比基于总树脂组合物的重量来表示。树脂组合物除了是阻燃剂外还具有出色的机械，热性能和成型性。其中X是氢，氯或溴，m的平均值为0至11，n的平均值为0至7，卤素含量为10重量％以上。 R1和R2的值在附件说明书中给出。

5. 发明授权

US4562216A Flame retardant polyester resin compositions 失效
标题翻译：阻燃聚酯树脂组合物
公开(公告)号：US4562216A
公开(公告)日：1985-12-31
申请号：US568531
申请日：1984-01-05
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
IPC分类号： C08L67/00 , C08K5/06 , C08K5/1515 , C08L67/02
CPC分类号： C08K5/06 , C08K5/1515 , C08L67/02
摘要： Flame retardant reinforced with thermoplastic polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-40 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant components (I) to (II) is in the range of 0
摘要翻译：公开了用热塑性聚酯树脂组合物增强的阻燃剂，由下列通式（I）和（II）表示的玻璃纤维和阻燃剂体系以及三氧化锑。阻燃剂体系是1-20重量份组分（I）和2-40重量份组分（II）的混合物，只要阻燃组分的重量比（I）/（II） I）至（II）的范围在0 <（I）/（II）≤5的范围内，阻燃剂（I）+（II）的总量在3-40份的范围内，重量。存在2至3重量份的三氧化锑，并且还存在5至60重量％的玻璃纤维，这两个百分比基于总树脂组合物的重量来表示。树脂组合物除了具有阻燃性外，还具有突出的机械，热，成型和机加工性能。其中X是氢，氯或溴，其中1和m的平均值分别为0〜11，卤素含量为10％以上，重量。 R1和R2的值在附件说明书中给出。

6. 发明授权

US4351751A Glass fiber reinforced polyethylene terephthalate resin composition 失效
标题翻译：玻璃纤维增强聚对苯二甲酸乙二醇酯树脂组合物
公开(公告)号：US4351751A
公开(公告)日：1982-09-28
申请号：US217095
申请日：1980-12-16
申请人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
发明人： Kazuo Kishida , Isao Sasaki , Hiroshi Mori
IPC分类号： C08K5/098 , C08K7/14 , C08L67/02 , C08L91/08
CPC分类号： C08K5/098 , C08K7/14 , C08L67/02
摘要： Polyethylene terephthalate type resin-containing molding compositions reinforced with glass fibers also containing from 0.03 to 5 weight percent of an organic caboxylic acid metal salt such as sodium stearate and an ether compound such as polyoxyethylene monononylphenyl ether present in an amount of from 0.1 up to 20 weight percent in which the average number of recurring alkylene oxide units is from 5 to 200 are disclosed. Also a solid or liquid paraffin or polyethylene wax may be included in an amount of from 0.3 to 5 weight percent. Moldings made from the disclosed compositions have a uniform appearance and exhibit improved heat resistance.
摘要翻译：还含有0.03〜5重量％的有机羧酸金属盐如硬脂酸钠和乙醚化合物如聚氧乙烯单壬基苯基醚的玻璃纤维增强聚对苯二甲酸乙二醇酯型树脂成型组合物，其量为0.1至20 公开了其中平均循环氧化烯单元数为5至200的重量百分数。固体或液体石蜡或聚乙烯蜡的含量也可以为0.3〜5重量％。由所公开的组合物制成的模制品具有均匀的外观并且显示出改进的耐热性。

7. 发明授权

US4507423A Modified polyolefin composite material with improved properties 失效
标题翻译：改性聚烯烃复合材料具有改进的性能
公开(公告)号：US4507423A
公开(公告)日：1985-03-26
申请号：US450386
申请日：1982-12-16
申请人： Isao Sasaki , Yasuaki Ii , Hiroshi Mori
发明人： Isao Sasaki , Yasuaki Ii , Hiroshi Mori
IPC分类号： C08L23/26 , C08F4/00 , C08F4/28 , C08F255/00 , C08K3/00 , C08K7/06 , C08L7/00 , C08L21/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00 , C08K5/14 , C08L51/08
CPC分类号： C08K3/0033
摘要： A polyolefin resin composition comprising a modified polyolefin prepared by reacting a polyolefin with an unsaturated carboxylic acid in the presence of a catalyst including at least one member selected from the group consisting of ketal peroxides and dialkyl peroxides having a decomposition temperature necessary for attaining the half life of 10 hours of at least 80.degree. C., and a fibrous, powdery, or flaky reinforcement.
摘要翻译：一种聚烯烃树脂组合物，其包含通过使聚烯烃与不饱和羧酸在催化剂存在下反应制备的改性聚烯烃，所述催化剂包括选自由缩酮过氧化物和具有达到半衰期所需的分解温度的二烷基过氧化物组成的组中的至少一种至少80℃的10小时，以及纤维状，粉状或片状的增强物。

8. 发明授权

US4546145A Polymer composition 失效
标题翻译：聚合物组成
公开(公告)号：US4546145A
公开(公告)日：1985-10-08
申请号：US640252
申请日：1984-08-14
申请人： Kazuo Kishida , Isao Sasaki , Nobuhiro Mukai
发明人： Kazuo Kishida , Isao Sasaki , Nobuhiro Mukai
IPC分类号： C08F2/44 , C08K3/04 , C08K3/00 , C08K3/08 , C08K3/26
CPC分类号： C08F2/44
摘要： A polymer composition wherein an inorganic substance and an organic polymer are firmly consolidated, which is characterized by being produced by polymerizing a vinyl monomer susceptible to radical polymerization in a polymerization system containing a dispersed inorganic substance in the presence of at least one monomer selected from sulfonic acid monomers, sulfonate monomers, or carboxylic acid monomers represented by the general formula [I] ##STR1## wherein R.sub.1 is a hydrogen atom, alkyl group having 1 to 20 carbon atoms, phenyl group, derivative of phenyl group, or halogen atom, X is CONH, ##STR2## COO(CH.sub.2).sub.m or (CH.sub.2).sub.n (wherein R.sub.2 and R.sub.3 are each a hydrogen atom or alkyl group having 1 to 15 carbon atoms, R.sub.4 is an alkylene group having 1 to 15 carbon atoms, m is an integer of 1 to 20, and n is an integer of 0 to 20), and Y is a hydrogen atom, ammonium radical, or an alkali metal atom, or by the general formula [II] ##STR3## wherein R.sub.5 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.6 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, COOZ, halogen atom, phenyl group, or derivative of phenyl group, R.sub.7 is a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group, and Z is a hydrogen atom, ammonium radical, or alkali metal atom, or by the general formula [III] ##STR4## wherein R.sub.8 and R.sub.9 are each a hydrogen atom, alkyl group having 1 to 15 carbon atoms, halogen atom, phenyl group, or derivative of phenyl group.
摘要翻译：一种聚合物组合物，其中无机物质和有机聚合物被牢固地固化，其特征在于通过在含有分散的无机物质的聚合体系中聚合具有自由基聚合的乙烯基单体在至少一种选自以下的单体由通式[I]表示的酸单体，磺酸酯单体或羧酸单体其中R1是氢原子，具有1-20个碳原子的烷基，苯基，苯基衍生物或卤素原子，X为CONH，COO（CH 2）m或（CH 2）n（其中R 2和R 3各自为氢原子或具有1至15个碳原子的烷基，R 4为具有1至15个碳原子的亚烷基 m为1〜20的整数，n为0〜20的整数，Y为氢原子，铵基或碱金属原子，通式[II]表示。[II] ]其中R5是氢原子，具有1至1的烷基 5个碳原子，COOZ，卤素原子，苯基或苯基的衍生物，R6是氢原子，具有1至15个碳原子的烷基，COOZ，卤素原子，苯基或苯基的衍生物，R7是氢原子，碳原子数1〜15的烷基，卤素原子，苯基或苯基的衍生物，Z为氢原子，铵基或碱金属原子，或通式[III] [III]其中R8和R9各自为氢原子，具有1至15个碳原子的烷基，卤素原子，苯基或苯基的衍生物。

9. 发明授权

US4388345A Coating composition and process for preparing synthetic resin shaped articles by using same 失效
标题翻译：涂料组合物及其制备方法
公开(公告)号：US4388345A
公开(公告)日：1983-06-14
申请号：US343221
申请日：1982-01-27
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Misao Tamura
IPC分类号： C09D5/00 , C08J7/04 , C08J7/16 , C09D4/00 , B05D3/06
CPC分类号： C08J7/16 , C09D4/00 , C08J2331/00 , Y10T428/31507
摘要： A shaped article of synthetic resins, such as polydiethylene glycol bisallylcarbonate, is coated with the following coating composition and then irradiated with ultraviolet rays, whereby the coating composition deposited on the shaped article is cured to form a coating film having an excellent abrasion resistance, surface smoothness, adhesion to the substrate resin, flexibility, heat resistance, solvent resistance and durability. The coating composition comprised of (a) a mixture of, based on the weight of the mixture, (i) 25-99.95 wt. % of at least one polyfunctional monomer having at least three acryloyloxy or methacryloyloxy groups, (ii) 0-50 wt. % of at least one mono- or bi-functional monomer having one or two polymerizable unsaturated groups and (iii) 0.05-25 wt. % of at least one organic acid which has at least one halogen substituent (fluorine, chlorine or bromine) and which is liquid at normal temperature and pressure, and (b) 0.01-10 wt. parts, based on 100 wt. parts of said mixture, of a photosensitizer. The coating composition may contain 0.05-25 wt. % of at least one compound having an acrylamide or methacrylamide group and a hydroxyl group or groups.
摘要翻译：合成树脂如聚二甘醇双烯丙基碳酸酯的成形制品用以下涂料组合物涂覆，然后用紫外线照射，由此沉积在成型制品上的涂料组合物固化以形成具有优异耐磨性，表面平滑性，与基材树脂的粘合性，柔软性，耐热性，耐溶剂性和耐久性。涂料组合物包含（a）基于混合物重量的混合物，（i）25-99.95wt。至少一种具有至少三个丙烯酰氧基或甲基丙烯酰氧基的多官能单体的％，（ii）0-50wt。％的至少一种具有一个或两个可聚合不饱和基团的单官能或双官能单体和（iii）0.05-25wt。至少一种具有至少一个卤素取代基（氟，氯或溴）并在常温常压下为液体的有机酸的％，和（b）0.01-10重量％基于100wt。所述混合物的一部分，光敏剂。涂料组合物可以含有0.05-25wt。％的至少一种具有丙烯酰胺或甲基丙烯酰胺基团和羟基或基团的化合物。

10. 发明授权

US4518472A Delustering coating composition excellent in abrasion resistance 失效
标题翻译：具有优异耐磨性的清漆涂料组合物
公开(公告)号：US4518472A
公开(公告)日：1985-05-21
申请号：US525895
申请日：1983-08-24
申请人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Masahiro Sugimori
发明人： Kazuo Kishida , Isao Sasaki , Kenji Kushi , Masahiro Sugimori
IPC分类号： C08F2/48 , C08F285/00 , C08J7/04 , C09D4/06 , C08F220/00 , C09D3/00
CPC分类号： C08J7/047 , C08F285/00 , C09D4/06 , C08J2333/06 , C08J2433/00
摘要： A coating composition curable by an activation energy ray, which comprises (a) 100 parts by weight of a monomer mixture (A) comprising at least 30% by weight of a compound having at least 3 acryloyloxy and/or methacryloyloxy groups in the molecule and up to 70% by weight of a compound having 1 to 2 .alpha.,.beta.-ethylenically unsaturated bonds in the molecule, (b) 0.01 to 6.0 parts by weight of at least one photosensitizer and (c) 0.5 to 30 parts by weight of an emulsion type crosslinked polymer or copolymer of a reactive monomer having one .alpha.,.beta.-ethylenically unsaturated bond in the molecule and a reactive monomer having at least two .alpha.,.beta.-ethylenically unsaturated bonds in the molecule.
摘要翻译：一种由活化能射线固化的涂料组合物，其包含（a）100重量份的包含至少30重量％的分子中具有至少3个丙烯酰氧基和/或甲基丙烯酰氧基的化合物的单体混合物（A），和至多70重量％的分子中具有1至2个α，β-烯属不饱和键的化合物，（b）0.01至6.0重量份的至少一种光敏剂和（c）0.5至30重量份的分子中具有一个α，β-烯属不饱和键的反应性单体的乳液型交联聚合物或共聚物，以及在分子中具有至少两个α，β-烯属不饱和键的反应性单体。

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