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    • 5. 发明授权
    • Water developable photosensitive resin composition
    • 水可显影光敏树脂组合物
    • US5736298A
    • 1998-04-07
    • US536494
    • 1995-10-02
    • Katsuo KoshimuraTakayoshi TanabeHozumi SatoNoboru OhshimaTakashi Nishioka
    • Katsuo KoshimuraTakayoshi TanabeHozumi SatoNoboru OhshimaTakashi Nishioka
    • G03F7/027G03F7/033G03C1/73
    • G03F7/027G03F7/033
    • A photo-sensitive resin composition is provided which contains (1) a particulate polymer of a carboxy-group-containing-diene having a cross-linked structure; (2) a polymer having two or more photo-polymerizable unsaturated groups at its molecular chain terminals, and, optionally, a photo-polymerizable unsaturated group, carboxyl group, hydroxy group, amino group, or epoxy group in side chains, or (2') a non-diene-type polymer having a photo-polymerizable unsaturated group, carboxyl group, hydroxy group, amino group, or epoxy group in side chains, or a low molecular weight linear diene-type polymer; (3) a photo-polymerizable unsaturated monomer; (4) a polymer containing an amino group; and (5) a photo-polymerization initiator. The photo-sensitive resin composition has excellent water-developing capability and shows almost no swelling in water, causing minimal reduction in strength and only minimal dimensional changes during development. Resin plates prepared from the composition possess excellent strength after exposure to light, excellent elongation at break, impact resilience and superb transparency, providing a good characteristic balance of properties.
    • 提供了一种光敏树脂组合物,其包含(1)具有交联结构的含羧基的二烯的颗粒状聚合物; (2)在其分子链末端具有两个以上的光聚合性不饱和基团的聚合物,以及任选的侧链中的光聚合性不饱和基团,羧基,羟基,氨基或环氧基,或(2 ')侧链中具有光聚合性不饱和基团,羧基,羟基,氨基或环氧基的非二烯类聚合物,或低分子线型二烯类聚合物; (3)光聚合性不饱和单体; (4)含有氨基的聚合物; 和(5)光聚合引发剂。 感光树脂组合物具有优异的水显影能力,并且在水中几乎没有溶胀,在显影期间几乎不降低强度并且只有极小的尺寸变化。 由组合物制备的树脂板在曝光后具有优异的强度,优异的断裂伸长率,抗冲击弹性和极好的透明度,提供良好的性能特征平衡。
    • 9. 发明授权
    • Rubber composition comprising a thermosetting resin and a functional
rubber-like copolymer
    • 包含热固性树脂和功能橡胶状共聚物的橡胶组合物
    • US4599382A
    • 1986-07-08
    • US714032
    • 1985-03-20
    • Hozumi SatoShin-ichiro IwanagaHiroji EnyoYasuhiko TakemuraYoshiaki Kawamura
    • Hozumi SatoShin-ichiro IwanagaHiroji EnyoYasuhiko TakemuraYoshiaki Kawamura
    • C08F236/04C08L19/00C08L33/06C08L61/00C08L61/10
    • C08L19/006C08F236/04C08L33/062C08L61/00C08L61/06C08L61/24C08L61/28
    • A rubber composition consisting essentially of 5-99 parts by weight of a thermosetting resin and 94-1 parts by weight of one of the following functional rubber-like copolymers (I) to (III) having a Mooney viscosity ML.sub.1+4.sup.100 of 20-120:(I) a functional rubber-like copolymer consisting of 1-20% by weight of a monomer having epoxy groups, hydroxyl groups or amino groups, 15-50% by weight of acrylonitrile and 40-80% by weight of butadiene and/or isoprene as monomer units constituting the polymer,(II) a functional rubber-like copolymer consisting of 1-20% by weight of a monomer having epoxy groups, hydroxyl groups or amino groups, 40-99% by weight of an alkyl (meth)acrylate and/or an alkoxyalkyl (meth)acrylate and 0-30% by weight of monomers copolymerizable therewith other than butadiene and isoprene, as the monomer units constituting the polymer, and(III) a functional rubber-like copolymer consisting of 1-20% by weight of a monomer having epoxy groups, hydroxyl groups or amino groups, 15-50% by weight of acrylonitrile, 20-60% by weight of butadiene and/or isoprene and 5-65% by weight of an alkyl (meth)acrylate and/or an alkoxy (meth)acrylate as the monomer units constituting the polymer.Said functional rubber copolymer may include 10% by weight or less of a polyfunctional monomer as a monomer unit constituting the polymer. In this case, the ratio of the thermosetting resin to the functional rubber-like copolymer is 50-99 parts by weight of the former to 1-50 parts by weight of the latter.
    • 基本上由5-99重量份的热固性树脂和94-1重量份具有门尼粘度ML1 + 4100为20〜20的功能性橡胶状共聚物(I)〜(III)之一组成的橡胶组合物, 120:(I)由1-20重量%的具有环氧基,羟基或氨基的单体,15-50重量%的丙烯腈和40-80重量%的丁二烯组成的功能性橡胶状共聚物,以及 /或异戊二烯作为构成聚合物的单体单元,(II)由1-20重量%的具有环氧基,羟基或氨基的单体组成的官能橡胶状共聚物,40-99重量%的烷基( (甲基)丙烯酸酯和/或(甲基)丙烯酸烷氧基烷基酯和0-30重量%的除丁二烯和异戊二烯之外可共聚的单体作为构成聚合物的单体单元,和(III)由1 -20重量%的具有环氧基,羟基或氨基的单体,15 -50重量%的丙烯腈,20-60重量%的丁二烯和/或异戊二烯和5-65重量%的(甲基)丙烯酸烷基酯和/或烷氧基(甲基)丙烯酸酯作为构成聚合物的单体单元 。 所述功能橡胶共聚物可以包含10重量%以下的作为构成聚合物的单体单元的多官能单体。 在这种情况下,热固性树脂与官能橡胶状共聚物的比例为前者的50-99重量份,后者的1-50重量份。