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    • 1. 发明授权
    • Polymerizable liquid crystal composition and optically anisotropic thin film
    • 可聚合液晶组合物和光学各向异性薄膜
    • US07378135B2
    • 2008-05-27
    • US11391194
    • 2006-03-29
    • Kazuhiko SaigusaMaiko ItoRyushi Shundo
    • Kazuhiko SaigusaMaiko ItoRyushi Shundo
    • C09K19/32C09K19/20C09K19/38
    • C09K19/32C09K19/3861C09K2019/0448C09K2219/03G02B5/3016Y10T428/10Y10T428/1036Y10T428/1041
    • In order to obtain such a liquid crystal thin film having optical anisotropy that suffers less change in optical characteristics thereof under heating to 200° C., the following polymerizable liquid crystal composition is provided as a raw material therefor. The composition contains Compound (1) and at least one of Compound (2) and Compound (3), with a proportion of Compound (1) being from 50 to 99% by weight, a proportion of Compound (2) being from 0 to 50% by weight, and a proportion of Compound (3) being from 0 to 50% by weight: wherein R is alkyl; each of W1 and W2 is independently hydrogen, chlorine, fluorine or —CH3; each of W3 and W4 is independently hydrogen, chlorine, fluorine, —CH3 or —CF3; W5 is alkyl having, alkoxy, chlorine, fluorine, —CN or —OCF3; X is a single bond, —CH═CH— or —CH2CH2—; Z is a single bond, —COO—, —OCO— or —CH2CH2—; and q is an integer of from 1 to 20.
    • 为了得到这样的具有光学各向异性的液晶薄膜,在加热至200℃时光学特性变化较小,提供以下可聚合液晶组合物作为原料。 组合物含有化合物(1)和化合物(2)和化合物(3)中的至少一种,化合物(1)的比例为50-99重量%,化合物(2)的比例为0〜 50重量%,化合物(3)的比例为0〜50重量%:其中R为烷基; W 1和W 2各自独立地是氢,氯,氟或-CH 3; W 3和W 4中的每一个独立地是氢,氯,氟,-CH 3或-CF 3 ; W 5是具有烷氧基,氯,氟,-CN或-OCF 3 N的烷基; X是单键,-CH-CH-或-CH 2 CH 2 - 。 Z是单键,-COO - , - OCO-或-CH 2 CH 2 - 。 q为1〜20的整数。
    • 2. 发明申请
    • Polymerizable liquid crystal composition and optically anisotropic thin film
    • 可聚合液晶组合物和光学各向异性薄膜
    • US20060222784A1
    • 2006-10-05
    • US11391194
    • 2006-03-29
    • Kazuhiko SaigusaMaiko ItoRyushi Shundo
    • Kazuhiko SaigusaMaiko ItoRyushi Shundo
    • C09K19/32C09K19/52C09K19/38
    • C09K19/32C09K19/3861C09K2019/0448C09K2219/03G02B5/3016Y10T428/10Y10T428/1036Y10T428/1041
    • In order to obtain such a liquid crystal thin film having optical anisotropy that suffers less change in optical characteristics thereof under heating to 200° C., the following polymerizable liquid crystal composition is provided as a raw material therefor. The composition contains Compound (1) and at least one of Compound (2) and Compound (3), with a proportion of Compound (1) being from 50 to 99% by weight, a proportion of Compound (2) being from 0 to 50% by weight, and a proportion of Compound (3) being from 0 to 50% by weight: wherein R is alkyl; each of W1 and W2 is independently hydrogen, chlorine, fluorine or —CH3; each of W3 and W4 is independently hydrogen, chlorine, fluorine, —CH3 or —CF3; W5 is alkyl having, alkoxy, chlorine, fluorine, —CN or —OCF3; X is a single bond, —CH═CH— or —CH2CH2—; Z is a single bond, —COO—, —OCO— or —CH2CH2—; and q is an integer of from 1 to 20.
    • 为了得到这样的具有光学各向异性的液晶薄膜,在加热至200℃时光学特性变化较小,提供以下可聚合液晶组合物作为原料。 组合物含有化合物(1)和化合物(2)和化合物(3)中的至少一种,化合物(1)的比例为50-99重量%,化合物(2)的比例为0〜 50重量%,化合物(3)的比例为0〜50重量%:其中R为烷基; W 1和W 2各自独立地是氢,氯,氟或-CH 3; W 3和W 4中的每一个独立地是氢,氯,氟,-CH 3或-CF 3 ; W 5是具有烷氧基,氯,氟,-CN或-OCF 3 N的烷基; X是单键,-CH-CH-或-CH 2 CH 2 - 。 Z是单键,-COO - , - OCO-或-CH 2 CH 2 - 。 q为1〜20的整数。