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1. 发明授权

US5777175A Preparation of polyoxyalkylene polyols, polymer polyols and flexible polyurethane foams 失效
标题翻译：聚氧化烯多元醇，聚合物多元醇和柔性聚氨酯泡沫的制备
公开(公告)号：US5777175A
公开(公告)日：1998-07-07
申请号：US420596
申请日：1995-04-12
申请人： Kazuhiko Ohkubo , Tomoki Tsutsui , Yoshitsugu Sakaki , Tamotsu Kunihiro , Ariko Nishikawa , Tsukuru Izukawa , Kaoru Ueno , Seijiro Sakai , Yukichi Tanaka
发明人： Kazuhiko Ohkubo , Tomoki Tsutsui , Yoshitsugu Sakaki , Tamotsu Kunihiro , Ariko Nishikawa , Tsukuru Izukawa , Kaoru Ueno , Seijiro Sakai , Yukichi Tanaka
IPC分类号： C08F283/06 , C08G18/40 , C08G18/48 , C08G18/63 , C08G18/65 , C08G65/26 , C08G65/28 , C08L71/02 , C07C41/03
CPC分类号： C08G65/2696 , C08F283/06 , C08G18/4072 , C08G18/4829 , C08G18/4866 , C08G18/632 , C08G18/6564 , C08G18/657 , C08G65/2609 , C08G65/2648 , C08L71/02 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： Propylene oxide is added to an active hydrogen compound in the presence of an alkali metal hydroxide catalyst in an amount of from 0.05 to 0.5 mole per mole of the active hydrogen compound at a reaction temperature of from 60.degree. to 98.degree. C. at a reaction pressure less than or equal to 4 kg/cm.sup.2 to prepare a polyoxyalkylene polyol which has a hydroxyl value of from 10 to 35 mg KOH/g, a monool content less than or equal to 15 mol %, a Head-to-Tail bond selectivity greater than or equal to 96 percent, and low viscosity. A polymer polyol is prepared by polymerizing an ethylenically unsaturated monomer in the polyoxyalkylene polyol. A flexible polyurethane foam is prepared by reacting the polyoxyalkylene polyol or the polymer polyol with an organic polyisocyanate compound in the presence of a foaming agent, a catalyst, a surfactant, a crosslinking agent and other additives. The thus-obtained polyurethane foams have less closed cells and are more excellent in properties such as hardness, humid aged compression set and impact resiliency.
摘要翻译：在碱金属氢氧化物催化剂存在下，在反应温度为60-98℃的反应中，将环氧丙烷加入到活性氢化合物中，其量为每摩尔活性氢化合物0.05至0.5摩尔压力小于或等于4kg / cm 2，以制备羟基值为10至35mg KOH / g，一元醇含量小于或等于15mol％的聚氧化烯多元醇，头 - 尾键合选择性大于或等于96％，低粘度。通过在聚氧化烯多元醇中聚合烯属不饱和单体制备聚合物多元醇。通过在发泡剂，催化剂，表面活性剂，交联剂和其它添加剂的存在下使聚氧化烯多元醇或聚合物多元醇与有机多异氰酸酯化合物反应来制备软质聚氨酯泡沫。由此获得的聚氨酯泡沫体具有较少的闭孔，并且在诸如硬度，湿老化压缩永久变形和冲击弹性等性能方面更优异。

2. 发明授权

US6156864A Preparation of flexible polyurethane foams 失效
标题翻译：柔性聚氨酯泡沫的制备
公开(公告)号：US6156864A
公开(公告)日：2000-12-05
申请号：US961532
申请日：1997-10-30
申请人： Kazuhiko Ohkubo , Tomoki Tsutsui , Yoshitsugu Sakaki , Tamotsu Kunihiro , Ariko Nishikawa , Tsukuru Izukawa
发明人： Kazuhiko Ohkubo , Tomoki Tsutsui , Yoshitsugu Sakaki , Tamotsu Kunihiro , Ariko Nishikawa , Tsukuru Izukawa
IPC分类号： C08F283/06 , C08G18/40 , C08G18/48 , C08G18/63 , C08G18/65 , C08G65/26 , C08G65/28 , C08L71/02 , C08G18/32
CPC分类号： C08G65/2696 , C08F283/06 , C08G18/4072 , C08G18/4829 , C08G18/4866 , C08G18/632 , C08G18/6564 , C08G18/657 , C08G65/2609 , C08G65/2648 , C08L71/02 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083
摘要： Propylene oxide is added to an active hydrogen compound in the presence of an alkali metal hydroxide catalyst in an amount of from 0.05 to 0.5 mole per mole of the active hydrogen compound at a reaction temperature of from 60 to 98.degree. C. at a reaction pressure less than or equal to 4 kg/cm.sup.2 to prepare a polyoxyalkylene polyol which has a hydroxyl value of from 10 to 35 mg KOH/g, a monool content less than or equal to 15 mol %, a Head-to-Tail bond selectivity greater than or equal to 96 percent, and low viscosity. A polymer polyol is prepared by polymerizing an ethylenically unsaturated monomer in the polyoxyalkylene polyol. A flexible polyurethane foam is prepared by reacting the polyoxyalkylene polyol or the polymer polyol with an organic polyisocyanate compound in the presence of a foaming agent, a catalyst, a surfactant, a crosslinking agent and other additives. The thus-obtained polyurethane foams have less closed cells and are more excellent in properties such as hardness, humid aged compression set and impact resiliency.
摘要翻译：在碱金属氢氧化物催化剂的存在下，在反应温度为60至98℃的反应压力下，将环氧丙烷加入到活性氢化合物中，其量为每摩尔活性氢化合物0.05至0.5摩尔小于或等于4kg / cm 2，以制备羟值为10-35mg KOH / g，一元醇含量小于或等于15mol％的聚氧化烯多元醇，头 - 尾键合选择性更大大于等于96％，粘度低。通过在聚氧化烯多元醇中聚合烯属不饱和单体制备聚合物多元醇。通过在发泡剂，催化剂，表面活性剂，交联剂和其它添加剂的存在下使聚氧化烯多元醇或聚合物多元醇与有机多异氰酸酯化合物反应来制备软质聚氨酯泡沫。由此获得的聚氨酯泡沫体具有较少的闭孔，并且在诸如硬度，湿老化压缩永久变形和冲击弹性等性能方面更优异。

3. 发明授权

US5545712A Preparation process for polyoxyalkylene polyol 失效
标题翻译：聚氧化烯多元醇的制备方法
公开(公告)号：US5545712A
公开(公告)日：1996-08-13
申请号：US518279
申请日：1995-08-23
申请人： Tomoki Tsutsui , Tsukuru Izukawa , Kazuhiko Ohkubo , Yoshitsugu Sakaki
发明人： Tomoki Tsutsui , Tsukuru Izukawa , Kazuhiko Ohkubo , Yoshitsugu Sakaki
IPC分类号： C08G65/30 , C08G59/68
CPC分类号： C08G65/30 , Y02P20/584
摘要： An alkali metal compound such as metallic cesium, cesium hydroxide, cesium hydroxide monohydrate, metallic rubidium, rubidium hydroxide or rubidium hydroxide monohydrate is used as a catalyst, crude polyoxyalkylene polyol containing the catalyst is neutralized with a mineral acid or an organic acid, an aqueous solution layer containing an alkali metal salt is brought into contact with an anion exchange resin to adsorb mineral acid anion or organic acid anion, the alkali metal compound catalyst is recovered, alkylene oxide undergoes ring-opening addition polymerization on an active hydrogen compound in the presence of the recovered alkali metal compound catalyst to prepare polyoxyalkylene polyol, the catalyst is thereafter separated, recovered and reused, and such recycle of the alkali metal compound catalyst provides an economical process.
摘要翻译：使用金属铯，氢氧化铯，氢氧化铯一水合物，金属铷，氢氧化铷或氢氧化铷一水合物等碱金属化合物作为催化剂，用无机酸或有机酸中和含有催化剂的粗聚氧化烯多元醇，含有碱金属盐的溶液层与阴离子交换树脂接触以吸附无机酸阴离子或有机酸阴离子，回收碱金属化合物催化剂，烯化氧在存在下在活性氢化合物上进行开环加成聚合的回收的碱金属化合物催化剂以制备聚氧化烯多元醇，然后分离，回收和再利用催化剂，并且这种碱金属化合物催化剂的再循环提供了经济的方法。

4. 发明授权

US5468840A Preparation process of polyoxyalkylene polyols and process of alkylene oxide recovery 失效
标题翻译：聚氧化烯多元醇的制备方法和环氧烷回收方法
公开(公告)号：US5468840A
公开(公告)日：1995-11-21
申请号：US296604
申请日：1994-08-29
申请人： Tomoki Tsutsui , Tsukuru Izukawa , Kazuhiko Ohkubo , Yoshitsugu Sakaki
发明人： Tomoki Tsutsui , Tsukuru Izukawa , Kazuhiko Ohkubo , Yoshitsugu Sakaki
IPC分类号： C08G65/30 , C08G59/68
CPC分类号： C08G65/30 , Y02P20/584
摘要： An alkali metal compound such as metallic cesium, cesium hydroxide, cesium hydroxide monohydrate, metallic rubidium, rubidium hydroxide or rubidium hydroxide monohydrate is used as a catalyst, crude polyoxyalkylene polyol containing the catalyst is neutralized with a mineral acid or an organic acid, an aqueous solution layer containing an alkali metal salt is brought into contact with an anion exchange resin to adsorb mineral acid anion or organic acid anion, the alkali metal compound catalyst is recovered. alkylene oxide undergoes ring-opening addition polymerization on an active hydrogen compound in the presence of the recovered alkali metal compound catalyst to prepare polyoxyalkylene polyol, the catalyst is thereafter separated, recovered and reused, and such recycle of the alkali metal compound catalyst provides an economical process.
摘要翻译：使用金属铯，氢氧化铯，氢氧化铯一水合物，金属铷，氢氧化铷或氢氧化铷一水合物等碱金属化合物作为催化剂，用无机酸或有机酸中和含有催化剂的粗聚氧化烯多元醇，使含有碱金属盐的溶液层与阴离子交换树脂接触以吸附无机酸阴离子或有机酸阴离子，回收碱金属化合物催化剂。在回收的碱金属化合物催化剂的存在下，氧化烯在活性氢化合物上进行开环加成聚合以制备聚氧化烯多元醇，然后分离，回收和重新使用催化剂，并且这种碱金属化合物催化剂的再循环提供了经济的处理。

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