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    • 3. 发明授权
    • Modification of wood
    • 修改木材
    • US5652026A
    • 1997-07-29
    • US653026
    • 1996-05-24
    • Shiro SakaHisashi MiyafujiFumie TannoAkira YamamotoMasaki TanakaKenji Yamamoto
    • Shiro SakaHisashi MiyafujiFumie TannoAkira YamamotoMasaki TanakaKenji Yamamoto
    • B27K3/15B05D7/06
    • B27K3/15C08L97/02C08L83/08
    • Wood is modified by impregnating wood with a methylsiloxane oligomer and heating the impregnated wood to cure the oligomer. The oligomer is of the average compositional formula: (CH.sub.3 SiO.sub.3/2).sub.m (MO.sub.3/2).sub.n or [CH.sub.3 SiO.sub.3/2 ].sub.x [(CH.sub.3).sub.a SiO.sub.(4-a)/2 ].sub.y [MO .sub.3/2 ].sub.z wherein M is P, PO and/or B, m and n are positive numbers with an average ratio of m:n ranging from 99:1 to 50:50, x, y, and z are positive numbers with an average ratio of (x+y):z ranging from 99:1 to 50:50 and an average ratio of x:y ranging from 99:1 to 50:50, and a is 2 or 3, and has a hydroxyl group and/or an alkoxyl group at a terminal end. This treatment of wood is safe. Since the methylsilicone resins thus incorporated and fixed within wood are not leached out in water, the modified wood maintains flame retardance for a very long time upon exposure to rain and dew and has water repellence, decay resistance and dimensional stability.
    • 木材通过用甲基硅氧烷低聚物浸渍木材进行改性,并加热浸渍的木材以固化低聚物。 低聚物具有平均组成式:(CH 3 SiO + E,3/2 + EE)m(MO + E,3/2 + EE)n或[CH 3 SiO + E,3/2 + EE] (CH3)aSiO(4-a)/ 2] y [MO + E,fra 3/2 + EE] z其中M是P,PO和/或B,m和n是正数, n的范围从99:1至50:50,x,y和z是正数,平均比例为(x + y):z为99:1至50:50,平均比例x:y范围为 99:1-50:50,a为2或3,末端具有羟基和/或烷氧基。 这种木材的处理是安全的。 由于在木材中结合并固定的甲基硅氧烷树脂不会在水中浸出,所以改性木材在暴露于雨水和露水后保持很长时间的阻燃性,并具有防水性,耐腐蚀性和尺寸稳定性。