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    • 1. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4493888A
    • 1985-01-15
    • US514216
    • 1983-07-15
    • Katsusuke EndoEiichi KatoNobutaka OhkiTakatoshi Ishikawa
    • Katsusuke EndoEiichi KatoNobutaka OhkiTakatoshi Ishikawa
    • G03C7/26C09B55/00G03C1/42G03C7/392G03C7/413G03C5/24G03C1/02
    • G03C7/4136G03C7/39284Y10S430/16
    • A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one organic metal complex represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein M represents a divalent metal atom; R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms, or R.sup.1 and R.sup.2 may be bonded each other to form a heterocyclic ring together with the nitrogen atom; R.sup.3, represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; and R.sup.4 and R.sup.5, which may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a carboxylic acid group, a sulfonic acid group, an alkoxycarbonyl group, an alkyl group or an alkoxy, or R.sup.4 and R.sup.5 may be bonded to each other to form a 5-membered or 6-membered ring.The compound represented by the general formula (I) is a precursor of a color developing agent which provides a sufficiently high color density on development and causes less desensitization and little fog or stain formation during storage of the photographic light-sensitive material containing thereof. A method of forming a color photographic image using the silver halide photographic light-sensitive material is also disclosed.
    • 一种含有扩散阻抗成色剂,感光卤化银和由以下通式(I)表示的至少一种有机金属络合物的卤化银照相感光材料,在支持体上相同层或不同层。 其中M表示二价金属原子; 可以相同或不同的R 1和R 2各自表示具有1至5个碳原子的烷基,具有1至5个碳原子的羟烷基,具有2至10个碳原子的烷氧基烷基或烷基磺酰胺基烷基 具有2至10个碳原子,或者R 1和R 2可以彼此键合以与氮原子一起形成杂环; R3表示氢原子,具有1至5个碳原子的烷基或具有1至5个碳原子的烷氧基; R 4和R 5可以相同或不同,分别表示氢原子,卤素原子,羟基,氨基,羧酸基,磺酸基,烷氧基羰基,烷基或 烷氧基或R 4和R 5可以彼此键合以形成5元或6元环。 由通式(I)表示的化合物是彩色显影剂的前体,其在显影时提供足够高的色密度,并且在含有它们的照相感光材料的储存期间引起较少的脱敏和很少的灰雾或污迹形成。 还公开了使用卤化银照相感光材料形成彩色照相图像的方法。
    • 2. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4473635A
    • 1984-09-25
    • US495873
    • 1983-05-18
    • Takatoshi IshikawaKatsusuke EndoSigeru KuwazimaEiichi KatoNobutaka Ohki
    • Takatoshi IshikawaKatsusuke EndoSigeru KuwazimaEiichi KatoNobutaka Ohki
    • G03C1/42G03C1/43G03C7/26G03C7/30G03C5/24G03C1/02
    • G03C1/43Y10S430/16
    • A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one compound represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## Wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, or R.sub.1 and R.sub.2 may be bonded to each other to form a heterocyclic ring together with the nitrogen atom; R.sub.3, R.sub.4, R.sub.5 and R.sub.6, which may be the same or different, each represents a hydrogen atom, a halogen atom, a hydroxy group, an amino group, an alkoxy group, an acylamido group, a sulfonamido group, an alkylsulfonamido group or an alkyl group, or R.sub.1 and R.sub.6 or R.sub.2 and R.sub.3 may be bonded to each other to form a 5-membered or 6-membered ring; X represents HPF.sub.6 or HBF.sub.4 ; and n represents an integer from 1 to 3.The compound represented by the general formula (I) is a precursor of a color developing agent which provides a sufficiently high color density on development and causes less desensitization and little formation of fogs or stains during storage of the photographic light-sensitive material containing thereof. A method of forming a color photographic image using the silver halide photographic light-sensitive material is also disclosed.
    • 一种含有扩散阻抗成色剂,感光卤化银和至少一种由下述通式(I)表示的化合物的卤化银照相感光材料,在载体上的相同层或不同层中。 (I)其中R1和R2可以相同或不同,各自表示氢原子或具有1-10个碳原子的烷基,或者R1和R2可以彼此键合形成杂环基 与氮原子一起环; 可以相同或不同的R 3,R 4,R 5和R 6各自表示氢原子,卤素原子,羟基,氨基,烷氧基,酰基酰氨基,亚磺酰氨基,烷基磺酰氨基或 烷基或R 1和R 6或R 2和R 3可以彼此键合形成5元或6元环; X代表HPF6或HBF4; 并且n表示1至3的整数。由通式(I)表示的化合物是彩色显影剂的前体,其在显影时提供足够高的色密度,并且在储存期间引起较少的脱敏和很少的雾或污渍形成 的摄影感光材料。 还公开了使用卤化银照相感光材料形成彩色照相图像的方法。
    • 4. 发明授权
    • Inkjet recording head and inkjet recording device
    • 喷墨记录头和喷墨记录装置
    • US07264329B2
    • 2007-09-04
    • US10946296
    • 2004-09-22
    • Eiichi KatoTakahiro Ishizuka
    • Eiichi KatoTakahiro Ishizuka
    • B41J2/15
    • B41J2/164B41J2/1606B41J2/162
    • To provide an inkjet recording head in which a high ink repelling property is kept even against the repeated use and which is excellent in film strength and abrasion resistance and is excellent with respect to printing quality of the resulting image, the inkjet recording head includes a nozzle having: a hole for discharging a recording liquid including an ink; and a portion capable of repelling the ink at the periphery of the hole, wherein the portion includes a cured film formed from a composition having a block copolymer, and the block copolymer includes: a block polymer having a fluorine-containing polymer; and a block polymer having a repeating unit having a siloxane structure.
    • 为了提供一种喷墨记录头,其中即使不重复使用也能保持高的斥墨性,并且膜强度和耐磨性优异,并且在所得图像的打印质量方面优异,喷墨记录头包括喷嘴 具有:用于排出包括油墨的记录液体的孔; 以及能够在孔周边排斥墨水的部分,其中所述部分包括由具有嵌段共聚物的组合物形成的固化膜,并且所述嵌段共聚物包括:具有含氟聚合物的嵌段聚合物; 和具有具有硅氧烷结构的重复单元的嵌段聚合物。
    • 7. 发明授权
    • Computer-to-cylinder type lithographic printing method and computer-to-cylinder type lithographic printing apparatus
    • 计算机对圆柱型平版印刷方法和计算机对圆柱型平版印刷设备
    • US06470799B2
    • 2002-10-29
    • US09818529
    • 2001-03-28
    • Yusuke NakazawaHideyuki KoguchiKazuo IshiiEiichi Kato
    • Yusuke NakazawaHideyuki KoguchiKazuo IshiiEiichi Kato
    • B41C110
    • B41J2/06B41C1/1066B41J2002/012B41J2002/061
    • A method of computer-to-cylinder lithographic printing, comprising: loading a plate material on a rotative plate cylinder of a lithographic printing apparatus; rotating the plate cylinder having loaded thereon the plate material; forming an image directly onto the plate material by an inkjet image-recording process which comprises ejecting an oil-based ink from a recording head having a plurality of ejecting channels, based on image data signals, utilizing an electrostatic field, to prepare a printing plate; subsequently performing lithographic printing with the thus prepared printing plate, wherein the recording head is driven so that every n'th channel thereof is actuated in a common phase, and wherein the plate cylinder is rotated to give a surface rotational speed V (mm/sec) of the plate material as represented by the following formula: V=25.4×(f×n)/N wherein N represents a recording resolution (dots/25.4 mm) along a rotative direction of the plate cylinder on the plate material, and f represents a driving frequency f (Hz) of each ejecting channel of the recording head.
    • 一种计算机对滚筒平版印刷的方法,包括:将平板印刷材料装载在平版印刷装置的旋转印版滚筒上; 旋转其上装有板材的印版滚筒; 通过喷墨图像记录方法将图像直接形成在板材上,其包括基于图像数据信号,利用静电场从具有多个喷射通道的记录头喷射油性油墨,以制备印刷板 ; 随后用如此制备的印版执行平版印刷,其中记录头被驱动,使得其第n个通道在公共相中被致动,并且其中印版滚筒旋转以提供表面旋转速度V(mm / sec )如下式所示:其中N表示沿着板材上的印版滚筒的旋转方向的记录分辨率(点/ 25.4mm),f表示每个喷射的印刷滚筒的驱动频率f(Hz) 通道的记录头。
    • 9. 发明授权
    • Direct drawing type lithographic printing plate precursor
    • 直接绘图型平版印刷版前体
    • US06393985B1
    • 2002-05-28
    • US09473501
    • 1999-12-28
    • Hiroshi TashiroEiichi Kato
    • Hiroshi TashiroEiichi Kato
    • B41N114
    • B41C1/1066B41N1/14Y10T428/256
    • A direct drawing type lithographic printing plate precursor comprising a water-resistant support having provided thereon an image-receiving layer comprising inorganic particles and a binder resin, wherein the inorganic particles comprise at least one kind of particles selected from: (i) metal oxide particles having an average particle size of from 0.01 to 5 &mgr;m and comprising a metal atom selected from Mg, Ba, Ge, Sn, Zn, Pb, La, Zr, V, Cr, Mo, W, Mn, Co, Ni and Cu; (ii) metal hydroxide particles having an average particle size of from 0.01 to 5 &mgr;m, the metal hydroxide being represented by the formula (I): M(OH)x  (I) wherein M represents a metal atom selected from Mg, Ba, Al, Ti, Zn, Cu, Ni, Sn, Co, Ge, Fe and La, and x represents a valence of the metal M; and (iii) double oxide particles having an average particle size of from 0.01 to 5 &mgr;m and comprising at least one metal atom selected from Mg, Al, Si, Ti, Zr, Cr, V, Mo, Sn, W and Nb, and wherein the binder resin comprises a complex comprising: a resin containing a siloxane bond in which a silicon atom is connected with an oxygen atom; and an organic polymer containing a group capable of forming a hydrogen bond with the resin containing a siloxane bond.
    • 一种直接拉伸型平版印刷版原版,其特征在于,具有防水载体,其上设置有包含无机颗粒和粘合剂树脂的图像接受层,其中所述无机颗粒包含至少一种选自以下的颗粒:(i)金属氧化物颗粒 平均粒径为0.01〜5μm,包含选自Mg,Ba,Ge,Sn,Zn,Pb,La,Zr,V,Cr,Mo,W,Mn,Co,Ni和Cu的金属原子; (ii)平均粒径为0.01〜5μm的金属氢氧化物粒子,所述金属氢氧化物由式(I)表示:其中,M表示选自Mg,Ba,Al,Ti,Zn,Cu, Ni,Sn,Co,Ge,Fe和La,x表示金属M的化合价; 和(iii)平均粒度为0.01〜5μm的二氧化物粒子,其含有选自Mg,Al,Si,Ti,Zr,Cr,V,Mo,Sn,W和Nb中的至少一种金属原子,以及 其中所述粘合剂树脂包含复合物,所述配合物包含:含有硅原子与氧原子连接的硅氧烷键的树脂; 和含有与含有硅氧烷键的树脂形成氢键的基团的有机聚合物。