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1. 发明授权

US4650515A Derivative of tetrahydrobenzothiazole and herbicidal composition containing the same as active ingredient 失效
标题翻译：四氢苯并噻唑的衍生物和含有与活性成分相同的除草组合物
公开(公告)号：US4650515A
公开(公告)日：1987-03-17
申请号：US673590
申请日：1984-11-21
申请人： Katsumichi Aoki , Takafumi Shida , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa , Shiro Yamazaki
发明人： Katsumichi Aoki , Takafumi Shida , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa , Shiro Yamazaki
IPC分类号： A01N43/78 , A01N47/06 , C07D277/82 , C07D417/04 , C07D417/14
CPC分类号： C07D417/04 , A01N43/78 , A01N47/06 , C07D277/82 , C07D417/14
摘要： Disclosed herein are the derivatives of tetrahydrobenzothiazole represented by the general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a straight-chain alkyl group having 1 to 6 carbon atoms or branched-chain alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or a phenyl group and R.sup.2 represents a chemical group selected from the group consisting of: ##STR2## wherein R.sup.3 represents a hydrogen atom, a methyl group or an acetyl group and R.sup.4 represents a hydrogen atom, a hydroxyl group, methoxy group or acetoxy group and herbicidal compositions containing at least one of the derivatives of tetrahydrobenzothiazole as an active ingredient.
摘要翻译：本文公开了由通式（I）表示的四氢苯并噻唑的衍生物：其中R 1表示氢原子，具有1至6个碳原子的直链烷基或支链烷基，其具有1至 6个碳原子，具有3至6个碳原子的环烷基或苯基，R 2表示选自以下的化学基团：其中R 3表示氢原子，甲基或乙酰基，R4表示氢原子，羟基，甲氧基或乙酰氧基，以及含有至少一种四氢苯并噻唑衍生物作为有效成分的除草组合物。

2. 发明授权

US4577029A Derivative of tetrahydrobenzothiazole and herbicidal composition containing the same as active ingredient 失效
公开(公告)号：US4577029A
公开(公告)日：1986-03-18
申请号：US491049
申请日：1983-05-03
申请人： Katsumichi Aoki , Takafumi Shida , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa , Shiro Yamazaki
发明人： Katsumichi Aoki , Takafumi Shida , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa , Shiro Yamazaki
IPC分类号： A01N43/78 , A01N47/06 , C07D277/82 , C07D417/04 , C07D417/14
CPC分类号： C07D417/04 , A01N43/78 , A01N47/06 , C07D277/82 , C07D417/14
摘要： Disclosed herein are the derivatives of tetrahydrobenzothiazole represented by the general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a straight-chain alkyl group having 1 to 6 carbon atoms or branched-chain alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or a phenyl group and R.sup.2 represents a chemical group selected from the group consisting of: ##STR2## wherein R.sup.3 represents a hydrogen atom, a methyl group or an acetyl group and R.sup.4 represents a hydrogen atom, a hydroxyl group, methoxy group or acetoxy group and herbicidal compositions containing at least one of the derivatives of tetrahydrobenzothiazole as an active ingredient.

3. 发明授权

US4481027A Derivatives of tetrahydrobenzothiazole and herbicidal compositions _containing the same as an active ingredient 失效
标题翻译：四氢苯并噻唑的衍生物和含有其作为活性成分的除草组合物
公开(公告)号：US4481027A
公开(公告)日：1984-11-06
申请号：US451796
申请日：1982-12-21
申请人： Katsumichi Aoki , Yoichi Kanda , Takafumi Shida , Keigo Satake , Hiroyasu Shinkawa
发明人： Katsumichi Aoki , Yoichi Kanda , Takafumi Shida , Keigo Satake , Hiroyasu Shinkawa
IPC分类号： A01N43/78 , A01N47/06 , C07D277/82 , C07D417/04 , C07D417/14
CPC分类号： C07D417/04 , A01N43/78 , A01N47/06 , C07D277/82 , C07D417/14
摘要： Disclosed is a derivative of tetrahydrobenzothiazole represented by the general formula (I): ##STR1## wherein R.sup.1 represents one of the following groups: ##STR2## wherein R.sup.2 represents a hydrogen atom, methyl group, acetyl group, benzoyl group, phenoxycarbonyl group or 3-pyridylcarbonyl group and R.sup.3 represents a hydrogen atom, hydroxy group, methoxy group or acetoxy group, ##STR3## and a herbicidal composition comprising as active ingredient at least one of the derivatives of tetrahydrobenzothiazole.
摘要翻译：公开了由通式（I）表示的四氢苯并噻唑的衍生物：其中R 1表示以下基团之一：其中R 2表示氢原子，甲基，乙酰基，苯甲酰基基团，苯氧基羰基或3-吡啶基羰基，R 3表示氢原子，羟基，甲氧基或乙酰氧基，和除草组合物，其包含作为活性成分的至少一种四氢苯并噻唑衍生物。

4. 再颁专利

USRE33132E 1,5-diphenyl derivative of 1H-1,2,4-triazole-3-carboxamide and herbicide containing the same 失效
标题翻译： 1H-1,2,4-三唑-3-甲酰胺的1,5-二苯基衍生物和含有它们的除草剂
公开(公告)号：USRE33132E
公开(公告)日：1989-12-19
申请号：US940721
申请日：1986-12-09
申请人： Katsumichi Aoki , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa
发明人： Katsumichi Aoki , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07D249/10
CPC分类号： C07D249/10 , A01N43/653
摘要： A compound of 1,5-disubstituted .Iadd.-1H-.Iaddend.1,2,4-triazole-3-carboxamide represented by the general formula; ##STR1## wherein R.sup.1 is alkyl of one to three carbon atoms, chloro, fluoro, iodo, trifluoromethyl or nitro, R.sup.2 is hydrogen, methyl or chloro, R.sup.3 is hydrogen or methyl is provided in the invention, which shows an excellent herbicidal activity.

5. 发明授权

US4492597A 1,5-Diphenyl derivative of 1,2,4-triazole-3-carboxamide and herbicide containing the same 失效
标题翻译： 1,2,4-三唑-3-甲酰胺的1,5-二苯基衍生物和含有它们的除草剂
公开(公告)号：US4492597A
公开(公告)日：1985-01-08
申请号：US379944
申请日：1982-05-19
申请人： Katsumichi Aoki , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa
发明人： Katsumichi Aoki , Yoichi Kanda , Keigo Satake , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07D249/10 , A01N43/64
CPC分类号： C07D249/10 , A01N43/653
摘要： A compound of 1,5-disubstituted 1,2,4-triazole-3-carboxamide represented by the general formula; ##STR1## wherein R.sup.1 is alkyl of one to three carbon atoms, chloro, fluoro, iodo, trifluoromethyl or nitro, R.sup.2 is hydrogen, methyl or chloro, R.sup.3 is hydrogen or methyl is provided in the invention, which shows an excellent herbicidal activity.
摘要翻译：由通式表示的1,5-二取代的1,2,4-三唑-3-甲酰胺的化合物; 其中R 1是1-3个碳原子的烷基，氯，氟，碘，三氟甲基或硝基，R 2是氢，甲基或氯，R 3是氢或甲基，其显示出优异的除草活性。

6. 发明授权

US4973353A 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide derivatives and herbicidal composition containing the same 失效
标题翻译： 1,5-二苯基-1H-1,2,4-三唑-3-甲酰胺衍生物和含有它们的除草组合物
公开(公告)号：US4973353A
公开(公告)日：1990-11-27
申请号：US162699
申请日：1988-03-01
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07C205/34 , C07C205/35 , C07C217/76 , C07D249/10
CPC分类号： C07C205/34 , A01N43/653 , C07C205/35 , C07C217/76 , C07D249/10
摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I): ##STR1## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; and Y.sup.2 is a hydrogen or a fluorine, and the herbicidal compositions containing said derivatives as active ingredient therefor.The derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I) of the present invention is the compound having high herbicidal activity and also showing excellent selectivity for killing weeds alone without doing any serious harm to the crops such as rice, wheat and corn.

7. 发明授权

US5162583A Benzylether derivatives 失效
标题翻译：苄醚衍生物
公开(公告)号：US5162583A
公开(公告)日：1992-11-10
申请号：US588996
申请日：1990-09-27
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07C201/12 , C07C205/33 , C07C205/34 , C07C205/35 , C07C217/76 , C07D249/10
CPC分类号： A01N43/653 , C07C205/33 , C07C205/34 , C07C205/35 , C07C217/76 , C07D249/10
摘要： Disclosed herein are the derivative of benzyl ether represented by the formula (I) ##STR1## which is useful as an intermediate compound of the derivatives of 1,5-diphenyl-1H-1,2,4- triazole-3-carboxamide represented by the formula (II), ##STR2## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; Y.sup.2 is a hydrogen or a fluorine; and Z is a nitro group or an amino group.
摘要翻译：本文公开了由式（I）表示的苄基醚衍生物，其可用作1,5-二苯基-1H-1,2,4-三唑-3-基的衍生物的中间体化合物，由式（II）表示的羧酰胺，其中R是未取代或被1〜19个氟原子取代的碳原子数为1〜10的直链烷基，具有3个未取代或被1〜19个氟原子取代的10个碳原子，碳原子数3〜10的环状烷基，碳原子数1〜3的被碳数3〜7的脂环结构取代的烷基原子，苯基或碳原子数为7〜9的芳烷基; X1是卤素或具有1至3个碳原子的烷基; X 2是氢，卤素或具有1至3个碳原子的烷基; Y1是氢或氟; Y2是氢或氟; Z为硝基或氨基。

8. 发明授权

US4968345A Phenylhydrazone derivative of oxamide and herbicidal composition containing the same 失效
标题翻译：草酰肼苯并腙衍生物及含有它们的除草组合物
公开(公告)号：US4968345A
公开(公告)日：1990-11-06
申请号：US162934
申请日：1988-03-02
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N37/52 , C07C67/00 , C07C239/00 , C07C257/20 , C07C257/22
CPC分类号： A01N37/52
摘要： Disclosed herein is a phenylhydrazone derivative of oxamide represented by the formula (I): ##STR1## wherein R.sup.1 is straight-chain alkyl group having 2 to 10 carbon atoms, branched alkyl group or cyclic alkyl group having 3 to 10 carbon atoms, alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, phenyl group, halogen-substituted phenyl group, aralkyl group having 7 to 9 carbon atoms, alkenyl group having 3 to 6 carbon atoms, alkyl group having 2 to 4 carbon atoms which is substituted with alkoxy group having 1 to 4 carbon atoms, or alkyl group having 2 to 10 carbon atoms which is substituted with 1 to 19 fluorine atoms; and R.sup.2 is hydrogen, fluorine, chlorine, methyl group or methoxy group, and a herbicidal composition containing the derivative as active ingredient. The phenylhydrazone derivative of oxamide represented by the formula (I) of the present invention shows a high herbicidal activity and also have an excellent selectivity allowing killing of weeds alone without doing any practical harm to the crops such as rice, wheat and corn.

9. 发明申请

US20110124877A1 5-BENZYL-4-AZOLYLMETHYL-4-SPIRO[2.4]HEPTANOL DERIVATIVES, METHODS FOR PRODUCING THE SAME, AND AGRO-HORTICULTURAL AGENTS AND INDUSTRIAL MATERIAL PROTECTING AGENTS THEREOF 审中-公开
标题翻译： 5-苯甲基-4-氨基甲基-4-螺[2.4]庚糖醇衍生物，其制备方法和农业 - 农业试剂及其工业材料保护试剂
公开(公告)号：US20110124877A1
公开(公告)日：2011-05-26
申请号：US12999822
申请日：2009-08-24
申请人： Atsushi Ito , Takashi Shimokawara , Eiyu Imai , Yoichi Kanda , Nobuyuki Kusano , Masaru Mori , Rumi Suzuki
发明人： Atsushi Ito , Takashi Shimokawara , Eiyu Imai , Yoichi Kanda , Nobuyuki Kusano , Masaru Mori , Rumi Suzuki
IPC分类号： C07D249/08 , C07D233/60 , C07D303/08 , C07D303/22 , C07D303/38 , C07C49/697 , C07C49/67 , C07C49/753 , C07C255/56 , C07C69/757
CPC分类号： C07D233/60 , A01N43/50 , A01N43/653 , C07C49/657 , C07C49/697 , C07C69/757 , C07C2601/08 , C07C2602/50 , C07D249/08
摘要： To provide a novel 5-benzyl-4-azolylmethyl-4-spiro[2.4]heptanol derivative, a method for producing the same, and an agro-horticultural agent and an industrial material protecting agent containing as an active ingredient the abovementioned 5-benzyl-4-azolylmethyl-4-spiro[2.4]heptanol derivative.To be a 5-benzyl-4-azolylmethyl-4-spiro[2.4]heptanol derivative represented by Formula (I): wherein X denotes a halogen atom, a C1-C5 alkyl group, a C1-C5 haloalkyl group, a C1-C5 alkoxy group, a C1-C5haloalkoxy group, a phenyl group, a cyano group or a nitro group; n denotes an integer of 0 to 5; when n is not less than 2, Xs may be the same or different; R1, R2, R3, R4 each independently denotes a hydrogen atom, a halogen atom or a C1-C5 alkyl group; and A denotes a nitrogen atom or a methyne group.
摘要翻译：为了提供新的5-苄基-4-吡唑基甲基-4-螺[2.4]庚醇衍生物，其制备方法，以及农业园艺剂和含有作为活性成分的上述5-苄基 -4-噻唑基甲基-4-螺[2.4]庚醇衍生物。作为由式（I）表示的5-苄基-4-吡唑基甲基-4-螺[2.4]庚醇衍生物：其中X表示卤素原子，C1-C5烷基，C1-C5卤代烷基，C1- C5烷氧基，C1-C5卤代烷氧基，苯基，氰基或硝基; n表示0〜5的整数，当n不小于2时，X可以相同或不同; R1，R2，R3，R4各自独立地表示氢原子，卤素原子或C1-C5烷基; A表示氮原子或甲炔基。

10. 发明授权

US06610853B1 N-(phenylsulfonyl)picolinamide derivatives, process for producing the same, and herbicide 失效
标题翻译： N-（苯基磺酰基）吡啶酰胺衍生物，其制备方法和除草剂
公开(公告)号：US06610853B1
公开(公告)日：2003-08-26
申请号：US09601791
申请日：2000-08-08
申请人： Yoichi Kanda , Koki Sato , Tsutomu Sato
发明人： Yoichi Kanda , Koki Sato , Tsutomu Sato
IPC分类号： C07D21381
CPC分类号： C07D213/81 , A01N43/40
摘要： A herbicide containing as the active ingredient an N-(henylsulfonyl)picolinamide derivative represented by general formula (I) wherein X reprcsents a halogeno, a C1-4 alkyl, a C1-4 haloalkyl, a C1-4 alkoxy, a C1-4 haloalkoxy, a (C1-4 alkoxy)carbonyl, a [di(C1-4 alkyl)amino]sulfonyl, an [N—(C1-4 alkyl)-N—(C1-4 alkoxy)amino]sulfonyl, a (C1-4 alkylamino)sulfonyl, a C1-4 alkylthio, a C1-4 alkylsulfinyl, a C1-4 alkylsulfonyl, or nitro; n is an integer of 0 to 5; Y represets a halogeno, a C1-4 alkyl, a C1-4 haloalkyl, a C1-4 alkoxy, C1-4 haloalkoxy, a C1-4 alkylthio, a C1-4 haloalkylthio, amino, a C1-4 alkylamino, a di(C1-4 alkyl)amino, a (C1-4 alkoxy) C1-4 alkyl, a (C1-4 alkylthio) C1-4 alkyl, or nitro; and m is an integer of 0 to 4. This active ingredient is synthesized by condensing a substituted picolinic acid with a substituted benzenesulfonamide under dehydration, or by reacting the phenyl ester of a substituted picolinic acid with a substituted benzenesulfonamide in the presence of a basic compound.
摘要翻译：一种除草剂，其含有由通式（I）表示的N-（乙烯基磺酰基）吡啶甲酰胺衍生物作为活性成分，其中X代表卤代，C1-4烷基，C1-4卤代烷基，C1-4烷氧基，C1-4 卤代烷氧基，（C 1-4烷氧基）羰基，[二（C 1-4烷基）氨基]磺酰基，[N-（C 1-4烷基）-N-（C 1-4烷氧基）氨基]磺酰基， -4-烷基氨基）磺酰基，C 1-4烷硫基，C 1-4烷基亚磺酰基，C 1-4烷基磺酰基或硝基; n为0〜5的整数， Y代表卤代，C 1-4烷基，C 1-4卤代烷基，C 1-4烷氧基，C 1-4卤代烷氧基，C 1-4烷硫基，C 1-4卤代烷硫基，氨基，C 1-4烷基氨基，二（C 1-4烷基）氨基，（C 1-4烷氧基）C 1-4烷基，（C 1-4烷硫基）C 1-4烷基或硝基; m为0〜4的整数。该活性成分通过在取代的吡啶甲酸与取代的苯磺酰胺脱水的情况下缩合，或者在碱性化合物的存在下使取代的吡啶甲酸的苯基酯与取代的苯磺酰胺反应来合成。

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