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    • 3. 发明授权
    • Nonlinear optical element and process for the preparation of same
    • 非线性光学元件及其制备方法
    • US5963360A
    • 1999-10-05
    • US10845
    • 1998-01-22
    • Katsuhiro SatoYoshiyuki OnoShigetoshi Nakamura
    • Katsuhiro SatoYoshiyuki OnoShigetoshi Nakamura
    • G02F1/355G02F1/361G02F1/35
    • B82Y20/00G02F1/3551G02F1/361
    • The present invention provides a nonlinear optical element having a sufficient thickness that can be used as a thin film insusceptible to crack and a process for the preparation thereof. A novel nonlinear optical element which gives a nonlinear response to incident light is provided, comprising finely divided grains of a semiconductor or metal, which grains have been separated out with the reaction of a functional group in a matrix-forming substance containing said functional group, dispersed in a matrix. A process for the preparation of a nonlinear optical element which gives a nonlinear response to incident light is also provided, which comprises mixing a solution of a matrix-forming substance containing a functional group with a metal, a semiconductor or a precursor thereof to form a uniform solution, and then allowing said functional group to undergo reaction to form a matrix while allowing finely divided grains of said metal or semiconductor to be separated out in said matrix.
    • 本发明提供了一种具有足够的厚度的非线性光学元件,其可以用作不易破裂的薄膜及其制备方法。 提供了一种对入射光产生非线性响应的新型非线性光学元件,其包括半导体或金属的细碎晶粒,该晶粒已经通过含有所述官能团的基质形成物质中的官能团的反应分离出来, 分散在矩阵中。 还提供了一种制备对入射光具有非线性响应的非线性光学元件的方法,其包括将含有官能团的基质形成物质与金属,半导体或其前体的溶液混合,形成 然后使所述官能团进行反应以形成基质,同时允许所述金属或半导体的细碎颗粒在所述基质中分离出来。
    • 6. 发明授权
    • Non-linear optical material and process for the preparation thereof
    • 非线性光学材料及其制备方法
    • US6140404A
    • 2000-10-31
    • US762942
    • 1996-12-10
    • Yoshiyuki OnoKatsuhiro Sato
    • Yoshiyuki OnoKatsuhiro Sato
    • G02F1/35C08G73/10C08K3/16G02F1/355G02F1/361C08J5/10C08K3/10C08L79/08
    • G02F1/361C08G73/10C08K3/16
    • The present invention provides a non-linear optical material having an excellent non-linear optical effect which is insusceptible to modification of a cuprous halide incorporated therein. The present invention also provides a process which enables the preparation of such a non-linear optical material at a low temperature by means of a simple apparatus. The non-linear optical material of the present invention exhibits a nonlinear response to incident light and comprises a particulate cuprous halide dispersed in a matrix, said particulate cuprous halide having been separated out with the reaction of a functional group contained in a matrix-forming substance having a functional group, wherein said matrix contains a compound for inhibiting the modification of said cuprous halide. The preparation of the non-linear optical material of the present invention can be accomplished by a process which comprises mixing a mixture of a matrix-forming substance having a functional group and a compound for inhibiting the modification of a cuprous halide with a cuprous halide to form a uniform solution, and then allowing said functional group to undergo reaction to form a matrix while causing a particulate cuprous halide to separate out in said matrix.
    • 本发明提供一种具有优异的非线性光学效应的非线性光学材料,该光学效应对于掺入其中的卤化亚铜的改性是不可察觉的。 本发明还提供一种能够通过简单的装置在低温下制备这种非线性光学材料的方法。 本发明的非线性光学材料对入射光呈现非线性响应,并且包含分散在基质中的颗粒状卤化亚铜,所述颗粒状亚硫化亚铜已经被包含在基质形成物质中的官能团的反应分离出来 具有官能团,其中所述基质含有用于抑制所述氯化亚铜的改性的化合物。 本发明的非线性光学材料的制备可以通过一种方法来实现,该方法包括将具有官能团的基质形成物质和用于抑制卤化亚铜改性的化合物与卤化亚铜的混合物混合 形成均匀的溶液,然后使所述官能团进行反应以形成基质,同时使颗粒状亚硫酸铜在所述基质中分离出来。