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1. 发明授权

US5072605A Process for production of covered deep-drawn can 失效
标题翻译：生产覆盖深加工罐的方法
公开(公告)号：US5072605A
公开(公告)日：1991-12-17
申请号：US538044
申请日：1990-06-13
申请人： Katsuhiro Imazu , Masanori Aizawa , Tetsuo Miyazawa , Nobuyuki Satoh , Seishichi Kobayashi
发明人： Katsuhiro Imazu , Masanori Aizawa , Tetsuo Miyazawa , Nobuyuki Satoh , Seishichi Kobayashi
IPC分类号： B21D22/20 , B21D22/30 , B21D51/26 , B32B15/08 , B65D1/16
CPC分类号： B21D51/26
摘要： Disclosed is a process for the production of a covered deep-drawn can, which comprises subjecting a metal sheet covered with a thermoplastic resin to drawing and deep-drawing. By heat-treating the formed covered deep-drawn can at a temperature higher than the glass transition point of the thermoplastic resin covering but lower than the melting point of the thermoplastic resin covering, the corrosion resistance, heat resistance and denting resistance of the can are improved, and the adhesion of the resin covering to the metal sheet and the heat resistance of the resin covering to the metal sheet and the heat resistance of the resin covering are improved without degradation of film characteristics inherently possessed by the resin covering.

2. 发明授权

US5249447A Process for preparation of thickness-reduced deep-draw-formed can 失效
标题翻译：制备厚度减小的深拉制罐的方法
公开(公告)号：US5249447A
公开(公告)日：1993-10-05
申请号：US22859
申请日：1993-02-25
申请人： Masanori Aizawa , Tetsuo Miyazawa , Katsuhiro Imazu , Seishichi Kobayashi , Hiroshi Ueno
发明人： Masanori Aizawa , Tetsuo Miyazawa , Katsuhiro Imazu , Seishichi Kobayashi , Hiroshi Ueno
IPC分类号： B21D22/20 , B29C51/14 , B29C51/42 , B21C27/02
CPC分类号： B29C51/426 , B21D22/201 , B29C51/14 , B29C51/42 , B29C2043/3615 , B29C2043/3631 , B29C43/18 , B29K2705/00 , B29K2995/005 , B29L2031/565 , B29L2031/712
摘要： Disclosed is a process for the preparation of a thickness-reduced deep-draw-formed can, which comprises the steps of (i) coating a crystalline thermoplastic resin on a metal plate, (ii) heating the coated metal plate at a temperature higher than the glass transition point (Tg) of the thermoplastic resin and draw-forming the coated metal plated, and (iii) heating the obtained preliminarily drawn cup at a temperature higher than the glass transition temperature (Tg) of the thermoplastic resin and redrawing the cup at a bend-pulling speed of at least 1 m/min. According to this process, damage of the coating layer can be drastically moderated, and a deep-draw-formed can having prominently improved corrosion resistance and heat resistance can be obtained.
摘要翻译： PCT No.PCT / JP90 / 00190 Sec。 371 1990年12月12日第 102（e）1990年12月12日日期PCT提交1990年2月16日PCT公布。出版物WO90 / 09269 日期为1990年8月23日。公开是制备厚度减小的深拉成形罐的方法，其包括以下步骤：（i）在金属板上涂覆结晶热塑性树脂，（ii）金属板的温度高于热塑性树脂的玻璃化转变温度（Tg）并拉伸成形镀覆的镀金属，（iii）在高于玻璃化转变温度（Tg）的温度下加热获得的预拉伸杯热塑性树脂，并以至少1米/分钟的弯曲拉拔速度重新绘制杯子。根据该方法，可以显着降低涂层的损伤，并且可以获得显着地提高耐腐蚀性和耐热性的深拉成形体。

3. 发明授权

US5228588A Thickness-reduced deep-draw-formed can 失效
标题翻译：厚度减薄的深拉成形罐
公开(公告)号：US5228588A
公开(公告)日：1993-07-20
申请号：US841290
申请日：1992-02-28
申请人： Masanori Aizawa , Tetsuo Miyazawa , Katsuhiro Imazu , Seishichi Kobayashi , Hiroshi Ueno
发明人： Masanori Aizawa , Tetsuo Miyazawa , Katsuhiro Imazu , Seishichi Kobayashi , Hiroshi Ueno
IPC分类号： B21D51/26 , B65D1/16
CPC分类号： B21D51/26 , B65D1/165 , B29C2043/3615 , B29C2043/3631 , B29C43/18 , B29K2705/00 , B29L2031/712 , Y10S220/917
摘要： Disclosed is a thickness-reduced deep-draw-formed can formed of a metal plate having an organic coating. In this can, at least the inner surface organic coating is composed of a crystalline thermoplastic resin, the thickness of the barrel wall is made smaller than the thickness of the bottom, the thermoplastic resin of the barrel wall is molecularly oriented mainly in the axial direction, and the roughness of the metal surface of the barrel wall is larger than that of the metal surface of the bottom. Since the organic coating is crystalline and is molecularly oriented, the coating can resist processing deformation when the thickness is reduced by deep-draw forming and the coating is not damaged by a tool or the like at all, and therefore, the barrier property to corrosive components and the heat resistance are prominently improved.
摘要翻译： PCT No.PCT / JP90 / 00189 Sec。 371 1990年12月12日第 102（e）1990年12月12日日期PCT提交1990年2月16日PCT公布。第WO90 / 09321号公报日期1990年8月23日。公开是由具有有机涂层的金属板形成的厚度减小的深拉成形罐。在这种情况下，至少内表面有机涂层由结晶性热塑性树脂构成，筒壁的厚度小于底部的厚度，筒壁的热塑性树脂主要在轴向方向上分子取向并且筒壁的金属表面的粗糙度大于底部的金属表面的粗糙度。由于有机涂层是结晶的并且是分子取向的，所以当通过深拉成形减少厚度并且涂层不被工具等完全损坏时，涂层可以抵抗加工变形，因此，腐蚀性的阻隔性组件和耐热性显着提高。

4. 发明授权

US5137762A Laminated metal plate for drawn can, and drawn can prepared therefrom 失效
标题翻译：层压金属板，可以制作，可以制作
公开(公告)号：US5137762A
公开(公告)日：1992-08-11
申请号：US584022
申请日：1990-09-18
申请人： Masanori Aizawa , Katsuhiro Imazu , Tetsuo Miyazawa , Nobuyuki Satoh
发明人： Masanori Aizawa , Katsuhiro Imazu , Tetsuo Miyazawa , Nobuyuki Satoh
IPC分类号： B65D1/12 , B21D22/20 , B32B15/08 , B32B15/09 , B65D1/28 , C08J5/12 , C08J7/04 , C09J163/00
CPC分类号： C08J7/047 , B32B15/08 , B65D1/28 , C08J5/125 , C09J163/00 , C08J2367/02 , C08J2463/00 , Y10T428/1355 , Y10T428/31515 , Y10T428/31529 , Y10T428/31681 , Y10T428/31786 , Y10T428/31797
摘要： Disclosed is a laminated metal plate for a drawn can, which comprises a laminate comprising a base metal, a layer of a film of a polyester composed mainly of ethylene terephthalate units and, if desried, an adhesive primer layer interposed between the base metal and the polyester film layer, wherein the X-ray diffraction intensity ratio, defined by the following formula (I), of the polyester film layer is in the range of from 0.5 to 15:R.sub.X =I.sub.A /I.sub.B (I)wherein R.sub.X represents the X-ray diffraction intensity ratio, I.sub.A represents the X-ray diffraction intensity by the diffraction plane parallel to the surface of the polyester film, which has a spacing of about 0.34 nm (CuK.alpha. X-ray diffraction angle is 24.degree. to 28.degree.), and I.sub.B represents the X-ray diffraction intensity by the diffraction plane parallel to the polyester film surface, which has a spacing of about 0.39 nm (CuK.alpha. X-ray diffraction angle is 21.5.degree. to 24.degree. ).and the in-plane anisotropy index of the crystal of the film layer is less than 30.When this laminated metal plate is subjected to the drawing, cracking or formation of pinholes is prevented, and the laminated metal plate shows excellent formability and corrosion resistance. An excellent drawn can is prepared from this laminated metal plate.
摘要翻译：公开了一种用于拉制罐的层压金属板，其包括层压体，其包含基体金属，主要由对苯二甲酸乙二醇酯单元组成的聚酯膜层，如果需要，则介于基体金属和基体金属之间的粘合底漆层聚酯薄膜层，其中聚酯薄膜层由下式（I）定义的X射线衍射强度比在0.5至15的范围内：RX = IA / IB（I）其中RX表示X 射线衍射强度比，IA表示平行于聚酯膜的表面的衍射面的X射线衍射强度，其间隔为约0.34nm（CuKαX射线衍射角为24°至28°），IB表示与聚酯膜表面平行的衍射面的X射线衍射强度，其间隔为约0.39nm（CuKαX射线衍射角为21.5°〜24°）。并且膜层的晶体的面内各向异性指数小于30.当该层压金属板经受拉伸时，防止了针孔的开裂或形成，并且层压金属板显示出优异的成形性和耐腐蚀性。从该层压金属板制备出优良的拉伸罐。

5. 发明授权

US5512365A Laminated sheet metal for container manufacture and primer used in conjunction with same 失效
标题翻译：用于容器制造的层压板材和与其一起使用的底漆
公开(公告)号：US5512365A
公开(公告)日：1996-04-30
申请号：US304940
申请日：1994-09-13
申请人： Tetsuo Miyazawa , Kazuhiro Sato , Katsuhiro Imazu , Seishichi Kobayashi , Toshio Sue
发明人： Tetsuo Miyazawa , Kazuhiro Sato , Katsuhiro Imazu , Seishichi Kobayashi , Toshio Sue
IPC分类号： B32B7/02 , B21D51/26 , B21D51/38 , B32B15/08 , B32B27/38 , B65D1/00 , B65D25/14 , B65D25/34 , C09D163/00 , C09D163/10 , C09J163/00 , B05D1/36 , B21D22/22
CPC分类号： B21D51/26 , B21D51/38 , B32B15/08 , Y10T428/1359 , Y10T428/26 , Y10T428/261 , Y10T428/31522 , Y10T428/31728 , Y10T428/31739
摘要： A laminated sheet metal for the manufacture of containers is made from a sheet metal and, a layered thermoplastic resin film wherein the primer resin includes from about 50 to about 98 weight percent of polyamidodicarboxylic acid-modified epoxy resin, from about 2 to about 50 weight percent of curing agent resin, and from about 0.05 to about 10 weight percent of curing catalyst; also disclosed is a primer resin composition for use in the manufacture of laminated sheet metal for use in the manufacture of containers, made from about 50 to about 98 weight percent of polyamidodicarboxylic acid-modified epoxy resin, from about 2 to about 50 weight percent of curing agent resin, and from about 0.05 to about 10 weight percent of curing catalyst.
摘要翻译：用于制造容器的层压金属片由片状金属和层状热塑性树脂膜制成，其中底漆树脂包含约50至约98重量％的聚酰胺基二羧酸改性环氧树脂，约2至约50重量％固化剂树脂的百分比，和约0.05至约10重量％的固化催化剂; 还公开了用于制造用于制造容器的层压金属板的底漆树脂组合物，其由约50至约98重量％的聚酰胺基二羧酸改性环氧树脂制成，约2至约50重量％固化剂树脂和约0.05至约10重量％的固化催化剂。

6. 发明授权

US5753328A Polyester-metal laminated sheet and seamless cans using the same 失效
标题翻译：聚酯金属层压板和无缝罐使用相同
公开(公告)号：US5753328A
公开(公告)日：1998-05-19
申请号：US731834
申请日：1996-10-21
申请人： Tetsuo Miyazawa , Masashi Ichishima , Sachiko Machii , Kenichiro Nakamaki , Katsuhiro Imazu , Masanori Aizawa
发明人： Tetsuo Miyazawa , Masashi Ichishima , Sachiko Machii , Kenichiro Nakamaki , Katsuhiro Imazu , Masanori Aizawa
IPC分类号： B65D8/04 , B21D22/20 , B32B15/08 , B32B15/09 , B65D1/16 , B65D1/28 , B65D25/14
CPC分类号： B32B15/08 , B65D1/165 , B65D1/28 , Y10S220/906 , Y10S220/917 , Y10T428/1355 , Y10T428/1359 , Y10T428/31681
摘要： A laminated metal sheet obtained by laminating a polyester film on a metal sheet, wherein the polyester film has a double refraction represented by the following relation, .DELTA.n=n.sub.m -n.sub.t wherein n.sub.m is a refractive index in the direction of a maximum orientation of the film, and n.sub.t is a refractive index in the direction of thickness of the film, which is higher on the side of the front surface of the polyester film than on the side of the metal sheet, and has a peak in the double refraction in a way of thickness from the side of the front surface toward the side of the metal sheet. A seamless can formed from such a laminated metal sheet exhibits excellent shock resistance, flavor-retaining property, corrosion resistance and like properties.
摘要翻译：通过将聚酯膜层叠在金属板上而得到的层叠金属片，其中聚酯膜具有由以下关系式表示的双折射，其中，nm = nm-nt，其中，nm是膜的最大取向方向的折射率，nt是在聚酯膜前表面侧比金属片侧更高的膜的厚度方向的折射率，以这种方式在双折射中具有峰值的厚度从前表面侧向金属板侧。由这种层压金属板形成的无缝罐表现出优异的抗冲击性，香味保持性，耐腐蚀性等性质。

7. 发明授权

US5300335A Laminated draw-formed container having excellent shock resistance and process for producing the same 失效
标题翻译：具有优异抗冲击性的叠层拉制容器及其制造方法
公开(公告)号：US5300335A
公开(公告)日：1994-04-05
申请号：US982625
申请日：1992-11-27
申请人： Tetsuo Miyazawa , Masashi Ichishima , Masanori Aizawa , Katsuhiro Imazu , Yasufumi Tadaki
发明人： Tetsuo Miyazawa , Masashi Ichishima , Masanori Aizawa , Katsuhiro Imazu , Yasufumi Tadaki
IPC分类号： B21D22/20 , B21D22/28 , B32B15/08 , B32B15/09 , B65D8/16 , C08L67/02
CPC分类号： B32B15/08 , C08L67/02 , Y10S220/906 , Y10S220/917 , Y10T428/1352 , Y10T428/1355 , Y10T428/1359 , Y10T428/31681 , Y10T428/31786 , Y10T428/31797
摘要： A laminated draw-formed container obtained by draw-forming a laminated material of a metal plate on which a resin film is laminated into a cup with bottom, wherein the resin film comprises a polyester composition which contains a polyethylene terephthalate component as a chief component and further contains a polyethylene isophthalate component and a polybutylene terephthalate component, the resin film having a density of from 1.32 to 1.39 g/cc at any part of the container and further having, on the upper part of the container, a trans ratio of ethylene glycol residue of from 0.1 to 1.5 as found by the ATR method, as well as a process for producing the container. The draw-formed container exhibits excellent shock resistance irrespective of the passage of time, and particularly dent resistance and barrier property against corrosive components, as well as intimate adhesion to the metal substrate.
摘要翻译：通过将其上层叠有树脂膜的金属板的层压材料层叠成具有底部的杯而获得的层叠拉制容器，其中所述树脂膜包含含有聚对苯二甲酸乙二醇酯成分作为主要成分的聚酯组合物，还含有聚间苯二甲酸乙二醇酯组分和聚对苯二甲酸丁二醇酯组分，树脂薄膜在容器的任何部分具有1.32至1.39g / cc的密度，并且在容器的上部还具有乙二醇的反式比通过ATR法得到的残留量为0.1〜1.5，以及容器的制造方法。拉伸成型容器不管时间的流逝，都具有优异的抗冲击性，特别是耐腐蚀性的耐凹陷性和阻隔性，以及与金属基材的密合性。

8. 发明授权

US5759651A Seamless can 失效
标题翻译：无缝可以
公开(公告)号：US5759651A
公开(公告)日：1998-06-02
申请号：US613197
申请日：1996-03-06
申请人： Sachiko Machii , Tetsuo Miyazawa , Kenichirou Nakamaki , Katsuhiro Imazu
发明人： Sachiko Machii , Tetsuo Miyazawa , Kenichirou Nakamaki , Katsuhiro Imazu
IPC分类号： B65D1/00 , B65D1/12 , B65D1/28 , B32B15/08
CPC分类号： B65D1/28 , Y10S220/906 , Y10S220/917 , Y10T428/1355 , Y10T428/31681 , Y10T428/31786
摘要： A thin-walled, deep-draw-ironed seamless can comprising a laminate of a metal sheet and a biaxially stretched film of polyester or copolyester mainly comprising an ethylene terephthalate unit. The thickness of the side wall portion of the can is reduced to from 30 to 85% of the original thickness of the laminate. The film layer on the side wall portion of the can has a parallel component orientation (D1) defined by formula (1) of 65% or more and a half width (Wh) of the peak at an angle of diffraction 2.theta. of from 14.degree. to 20.degree. falling within 1.8.degree..
摘要翻译：一种薄壁，深拉制的无缝罐，其包括金属片和主要包含对苯二甲酸乙二醇酯单元的聚酯或共聚酯的双轴向拉伸膜的层压体。罐的侧壁部分的厚度减小到层压体的原始厚度的30％至85％。罐的侧壁部分上的膜层具有由式（1）定义的平行分量取向（D1）为65％以上，并且在衍射角θ为14°的峰的半宽度（Wh） DEG至20°在1.8°以内。

9. 发明授权

US5653357A Laminated draw-formed container having excellent flavor-retentivity and shock resistance 失效
标题翻译：叠层拉制容器具有优异的香味保持性和抗冲击性
公开(公告)号：US5653357A
公开(公告)日：1997-08-05
申请号：US322560
申请日：1994-10-13
申请人： Tetsuo Miyazawa , Toshio Sue , Katsuhiro Imazu
发明人： Tetsuo Miyazawa , Toshio Sue , Katsuhiro Imazu
IPC分类号： B65D8/16 , B21D22/20 , B21D22/28 , B21D51/26 , B32B15/08 , B32B15/09 , B65D1/28 , B65D25/14 , B32B1/00
CPC分类号： B21D51/26 , B21D22/28 , B32B15/08 , B65D1/28
摘要： A laminated draw-formed container that is obtained by draw-forming a laminated material of a metal plate on which a resin film is laminated into a cup having bottom, wherein said resin film comprises a surface layer of a high molecular oriented copolymerized polyester derived from acid components of 85 to 97% of terephthalic acid and 3 to 15% of isophthalic acid, and a diol component, and a lower layer of a low molecular oriented copolymerized polyester (B) derived from acid components of 84.5 to 96.5% of terephthalic acid and 3.5 to 15.5% of isophthalic acid, the amount of the isophthalic acid being larger than that of the copolymerized polyester (A) of the surface layer, and a diol component, and said surface layer having a double refraction method orientation degree (.DELTA. n) as represented by the following relation,.DELTA. n=n.sub.1 -n.sub.2wherein n.sub.1 is a refractive index in the direction of a maximum orientation of the film, and n.sub.2 is a refractive index in the direction of thickness of the film,which is not smaller than 0.02. The laminated draw-formed container exhibits markedly improved dent resistance and corrosion resistance even after the container is preserved, as well as improved adhesion property and workability, and prevents the adsorption of flavor components and the elution of resin components into the content, making it possible to greatly improve flavor retentivity of the content.
摘要翻译：一种叠层拉制容器，其通过将其上层叠有树脂膜的金属板的层压材料层叠到具有底部的杯中而获得，其中所述树脂膜包括来自高分子量的共聚聚酯的表层 85〜97％的对苯二甲酸和3〜15％的间苯二甲酸的酸成分和二醇成分，以及由酸成分得到的低分子量取向共聚聚酯（B）的下层为84.5〜96.5％的对苯二甲酸和3.5〜15.5％的间苯二甲酸，间苯二甲酸的量大于表层的共聚聚酯（A）的量，以及二醇成分，所述表面层具有双折射方向取向度（DELTA n ）如下面的关系所示：DELTA n = n1-n2其中n1是膜最大取向方向的折射率，n2是厚度方向上的折射率薄膜，不小于0.02。即使在保持容器之后，层叠拉制容器也具有显着提高的耐凹陷性和耐腐蚀性，以及改进的粘合性和加工性，并且防止了香料成分的吸附和树脂成分的洗脱，使其成为可能大大提高内容的风味保持性。

10. 发明授权

US4525497A Process for producing epoxy-type-lacquer 失效
标题翻译：环氧树脂漆的生产工艺
公开(公告)号：US4525497A
公开(公告)日：1985-06-25
申请号：US574081
申请日：1984-01-26
申请人： Seishichi Kobayashi , Tetsuo Miyazawa , Hiroshi Ueno
发明人： Seishichi Kobayashi , Tetsuo Miyazawa , Hiroshi Ueno
IPC分类号： C08G59/00 , C08G59/02 , C08G59/06 , C08G59/44 , C08J3/11 , C09D163/00 , C09D163/02 , C09D3/52 , C09D3/58 , C09D3/66 , C09D3/76
CPC分类号： C08J3/11 , C08G59/066 , C09D163/00 , C08J2363/02
摘要： A process for producing an epoxy-type lacquer, which comprises reacting a liquid epoxy resin having about one bisphenol A skeleton on an average in the molecular chain and derived from bisphenol A and an epihalohydrin, with bisphenol A in the presence of a catalyst in an inert organic solvent to prepare a concentrated solution of an epoxy resin having a number average molecular weight of from 2,000 to 10,000, adding an organic solvent to the concentrated solution to dilute it and maintain it at a temperature lower than that at which the catalyst is active, and mixing the resulting diluted solution with a solution of a resin acting as a curing agent for the epoxy resin. The resulting lacquer is especially useful for coating metallic containers.
摘要翻译：一种环氧型漆的制造方法，其特征在于，在催化剂的存在下，在双酚A的存在下，将具有约1个双酚A骨架的液晶环氧树脂在分子链中平均衍生并衍生自双酚A和表卤代醇惰性有机溶剂，以制备数均分子量为2,000至10,000的环氧树脂的浓缩溶液，向浓缩溶液中加入有机溶剂以稀释并保持在低于催化剂活性的温度，并将得到的稀释溶液与作为环氧树脂固化剂的树脂溶液混合。所得的漆对于涂覆金属容器特别有用。

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