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1. 发明申请

US20100034972A1 INK JET INK, INK JET RECORDING METHOD, INK CARTRIDGE, RECORDING UNIT, AND INK JET RECORDING APPARATUS 审中-公开
标题翻译：墨水喷射墨水，喷墨记录方法，墨盒，记录单元和喷墨记录装置
公开(公告)号：US20100034972A1
公开(公告)日：2010-02-11
申请号：US12535073
申请日：2009-08-04
申请人： Fumihiko Mukae , Katsuhiro Shirota , Yoshihisa Yamashita , Masashi Tsujimura , Katsuhiko Suzuki , Hiromitsu Kishi , Takashi Saito , Hirofumi Ichinose , Sayoko Nagashima
发明人： Fumihiko Mukae , Katsuhiro Shirota , Yoshihisa Yamashita , Masashi Tsujimura , Katsuhiko Suzuki , Hiromitsu Kishi , Takashi Saito , Hirofumi Ichinose , Sayoko Nagashima
IPC分类号： B05D5/06 , C08L51/08 , B41J2/01 , C09D11/10
CPC分类号： C09D11/322 , C08F290/068 , C09D11/10 , C09D11/107 , C09D11/38
摘要： Provided is an ink jet ink capable of recording an image having an unprecedentedly high level of scratch resistance and excellent glossiness while satisfying reliability of the ink such as ejection stability. The ink jet ink contains at least a pigment and a graft polymer, and is characterized in that the graft polymer includes at least a specific nonionic unit and a unit having a polysiloxane structure.
摘要翻译：提供一种能够记录具有前所未有的高水平的耐擦伤性和优异光泽度的图像的喷墨墨，同时满足诸如喷射稳定性的墨的可靠性。喷墨墨水至少含有颜料和接枝聚合物，其特征在于接枝聚合物至少包含特定的非离子单元和具有聚硅氧烷结构的单元。

2. 发明申请

US20100033523A1 INK SET, INK JET RECORDING METHOD, AND INK JET RECORDING APPARATUS 有权
标题翻译：墨盒，喷墨记录方法和喷墨记录装置
公开(公告)号：US20100033523A1
公开(公告)日：2010-02-11
申请号：US12534969
申请日：2009-08-04
申请人： Katsuhiko Suzuki , Katsuhiro Shirota , Hirofumi Ichinose , Masashi Tsujimura , Hiromitsu Kishi , Takashi Saito , Sayoko Nagashima , Fumihiko Mukae , Yoshihisa Yamashita
发明人： Katsuhiko Suzuki , Katsuhiro Shirota , Hirofumi Ichinose , Masashi Tsujimura , Hiromitsu Kishi , Takashi Saito , Sayoko Nagashima , Fumihiko Mukae , Yoshihisa Yamashita
IPC分类号： B41J29/38 , C09D11/10
CPC分类号： B41J29/00 , B41J2/1752 , C09D11/322 , C09D11/54
摘要： Provided are an ink jet ink set, an ink jet recording method, and an ink jet recording apparatus each of which can reduce the graininess of an image to be recorded and improve the water fastness of the image even in a recording medium such as plain paper. The ink jet ink set has a first ink and a second ink independently, and is used so that the first and second inks overlap each other at least partly upon application of the inks to a recording medium. The first ink contains at least a pigment and a silicone oil. The second ink contains at least a pigment and a graft polymer that includes at least a nonionic unit represented by the general formula (I) and a unit having a polysiloxane structure.
摘要翻译：提供了一种喷墨油墨组，喷墨记录方法和喷墨记录装置，其中每一种都可以降低要记录的图像的颗粒度，并且即使在诸如普通纸的记录介质中也能提高图像的耐水性。喷墨油墨组独立地具有第一油墨和第二油墨，并且被使用以使得第一和第二油墨至少部分地在将油墨施加到记录介质上时彼此重叠。第一油墨至少含有颜料和硅油。第二油墨含有至少含有由通式（I）表示的非离子单元和具有聚硅氧烷结构的单元的至少一种颜料和接枝聚合物。

3. 发明授权

US08389600B2 Ink jet recording method, and ink jet recording apparatus 有权
标题翻译：喷墨记录方法和喷墨记录装置
公开(公告)号：US08389600B2
公开(公告)日：2013-03-05
申请号：US12534969
申请日：2009-08-04
申请人： Katsuhiko Suzuki , Katsuhiro Shirota , Hirofumi Ichinose , Masashi Tsujimura , Hiromitsu Kishi , Takashi Saito , Sayoko Nagashima , Fumihiko Mukae , Yoshihisa Yamashita
发明人： Katsuhiko Suzuki , Katsuhiro Shirota , Hirofumi Ichinose , Masashi Tsujimura , Hiromitsu Kishi , Takashi Saito , Sayoko Nagashima , Fumihiko Mukae , Yoshihisa Yamashita
IPC分类号： A61Q19/00 , B41J2/01 , B41J2/015 , B41J2/17 , B41J2/175 , B60C1/00 , C08F290/06 , C08J3/00 , C08K5/54 , C08L31/00 , C08L33/00 , C08L33/06 , C09B67/00 , C09D5/00 , C09D11/00 , G01D11/00
CPC分类号： B41J29/00 , B41J2/1752 , C09D11/322 , C09D11/54
摘要： Provided are an ink jet ink set, an ink jet recording method, and an ink jet recording apparatus each of which can reduce the graininess of an image to be recorded and improve the water fastness of the image even in a recording medium such as plain paper. The ink jet ink set has a first ink and a second ink independently, and is used so that the first and second inks overlap each other at least partly upon application of the inks to a recording medium. The first ink contains at least a pigment and a silicone oil. The second ink contains at least a pigment and a graft polymer that includes at least a nonionic unit represented by the general formula (I) and a unit having a polysiloxane structure.
摘要翻译：提供了一种喷墨油墨组，喷墨记录方法和喷墨记录装置，其中每一种都可以降低要记录的图像的颗粒度，并且即使在诸如普通纸的记录介质中也能提高图像的耐水性。喷墨油墨组独立地具有第一油墨和第二油墨，并且被使用以使得第一和第二油墨至少部分地在将油墨施加到记录介质上时彼此重叠。第一油墨至少含有颜料和硅油。第二油墨含有至少含有由通式（I）表示的非离子单元和具有聚硅氧烷结构的单元的至少一种颜料和接枝聚合物。

4. 发明申请

US20100033522A1 INK SET, INK JET RECORDING METHOD AND INK JET RECORDING APPARATUS 有权
标题翻译：墨盒，喷墨记录方法和喷墨记录装置
公开(公告)号：US20100033522A1
公开(公告)日：2010-02-11
申请号：US12512481
申请日：2009-07-30
申请人： Takashi Saito , Katsuhiro Shirota , Hirofumi Ichinose , Hiromitsu Kishi , Masashi Tsujimura , Fumihiko Mukae , Fumiaki Fujioka , Katsuhiko Suzuki , Sayoko Nagashima
发明人： Takashi Saito , Katsuhiro Shirota , Hirofumi Ichinose , Hiromitsu Kishi , Masashi Tsujimura , Fumihiko Mukae , Fumiaki Fujioka , Katsuhiko Suzuki , Sayoko Nagashima
IPC分类号： B41J2/01 , C09D11/02 , C09D11/10
CPC分类号： C09D11/54 , C09D11/322
摘要： An object of the invention is to provide an ink set which enables to improve image density and scratch resistance of the images recorded using an ink containing a self-dispersion pigment and an ink containing a modified siloxane compound. An ink set to be used for ink jet recording including plural inks having a first ink and a second ink independently, wherein the first ink contains at least a pigment having functional groups on surface of pigment particles and a compound having adsorptivity to the pigment and the functional group density on the surface of the pigment particles is 1.5 μmol/m2 or more and less than 2.6 μmol/m2 and the second ink contains at least a pigment and a modified siloxane compound.
摘要翻译：本发明的目的是提供一种油墨组，其能够改善使用含有自分散颜料和含有改性硅氧烷化合物的油墨的油墨记录的图像的图像密度和耐擦伤性。一种用于喷墨记录的油墨组，包括独立地具有第一油墨和第二油墨的多种油墨，其中第一油墨至少含有颜料颗粒表面具有官能团的颜料和对颜料具有吸附性的化合物，颜料颗粒表面的官能团密度为1.5μmol/ m 2以上且小于2.6μmol/ m 2，第二油墨至少含有颜料和改性硅氧烷化合物。

5. 发明授权

US08469504B2 Ink set, ink jet recording method and ink jet recording apparatus 有权
标题翻译：油墨组，喷墨记录方法和喷墨记录装置
公开(公告)号：US08469504B2
公开(公告)日：2013-06-25
申请号：US12512481
申请日：2009-07-30
申请人： Takashi Saito , Katsuhiro Shirota , Hirofumi Ichinose , Hiromitsu Kishi , Masashi Tsujimura , Fumihiko Mukae , Fumiaki Fujioka , Katsuhiko Suzuki , Sayoko Nagashima
发明人： Takashi Saito , Katsuhiro Shirota , Hirofumi Ichinose , Hiromitsu Kishi , Masashi Tsujimura , Fumihiko Mukae , Fumiaki Fujioka , Katsuhiko Suzuki , Sayoko Nagashima
IPC分类号： B41J2/01
CPC分类号： C09D11/54 , C09D11/322
摘要： An object of the invention is to provide an ink set which enables to improve image density and scratch resistance of the images recorded using an ink containing a self-dispersion pigment and an ink containing a modified siloxane compound. An ink set to be used for ink jet recording including plural inks having a first ink and a second ink independently, wherein the first ink contains at least a pigment having functional groups on surface of pigment particles and a compound having adsorptivity to the pigment and the functional group density on the surface of the pigment particles is 1.5 μmol/m2 or more and less than 2.6 μmol/m2 and the second ink contains at least a pigment and a modified siloxane compound.
摘要翻译：本发明的目的是提供一种油墨组，其能够改善使用含有自分散颜料和含有改性硅氧烷化合物的油墨的油墨记录的图像的图像密度和耐擦伤性。一种用于喷墨记录的油墨组，包括独立地具有第一油墨和第二油墨的多种油墨，其中第一油墨至少含有颜料颗粒表面具有官能团的颜料和对颜料具有吸附性的化合物，颜料颗粒表面的官能团密度为1.5μmol/ m 2以上且小于2.6μmol/ m 2，第二油墨至少含有颜料和改性硅氧烷化合物。

6. 发明申请

US20080193647A1 PIGMENT INK, INK JET RECORDING METHOD, INK CARTRIDGE, RECORDING UNIT AND INK JET RECORDING APPARATUS 有权
标题翻译：颜料墨水，喷墨记录方法，墨盒，记录单元和墨水记录装置
公开(公告)号：US20080193647A1
公开(公告)日：2008-08-14
申请号：US12025893
申请日：2008-02-05
申请人： Takashi Saito , Katsuhiro Shirota , Shinichi Hakamada , Masashi Tsujimura , Fumihiko Mukae , Katsuhiko Suzuki
发明人： Takashi Saito , Katsuhiro Shirota , Shinichi Hakamada , Masashi Tsujimura , Fumihiko Mukae , Katsuhiko Suzuki
IPC分类号： B05D5/04 , C08L33/10 , C08L33/08 , B41J2/175 , G01D11/00 , C08L25/04 , C09D11/02
CPC分类号： C09D11/40 , C09D11/322
摘要： A pigment ink is provided which has good ink reliability and storage stability and can achieve superior scratch resistance of images at such a level that coloring materials are hardly scraped off even when images are scratched with finger nails under application of such strong pressure as to scratch a recording medium at its non-recorded areas. The pigment ink contains a pigment, a modified siloxane compound having a specific structure, and a polymer whose acid value and hydrogen bond parameter (δh) are specified.
摘要翻译：提供了具有良好的油墨可靠性和储存稳定性的颜料油墨，并且可以在使得着色材料几乎不被刮掉的水平下达到优异的耐刮擦性，即使在施加如此强烈的压力下刮擦图像时，手指指甲也不会刮伤记录介质在其非记录区域。颜料墨水含有颜料，具有特定结构的改性硅氧烷化合物和指定了酸值和氢键参数（deltah）的聚合物。

7. 发明授权

US07918928B2 Pigment ink, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus 有权
标题翻译：颜料油墨，喷墨记录方法，墨盒，记录单元和喷墨记录装置
公开(公告)号：US07918928B2
公开(公告)日：2011-04-05
申请号：US12025893
申请日：2008-02-05
申请人： Takashi Saito , Katsuhiro Shirota , Shinichi Hakamada , Masashi Tsujimura , Fumihiko Mukae , Katsuhiko Suzuki
发明人： Takashi Saito , Katsuhiro Shirota , Shinichi Hakamada , Masashi Tsujimura , Fumihiko Mukae , Katsuhiko Suzuki
IPC分类号： C09D11/00 , B41J2/175 , C07F7/00
CPC分类号： C09D11/40 , C09D11/322
摘要： A pigment ink is provided which has good ink reliability and storage stability and can achieve superior scratch resistance of images at such a level that coloring materials are hardly scraped off even when images are scratched with finger nails under application of such strong pressure as to scratch a recording medium at its non-recorded areas. The pigment ink contains a pigment, a modified siloxane compound having a specific structure, and a polymer whose acid value and hydrogen bond parameter (δh) are specified.
摘要翻译：提供了具有良好的油墨可靠性和储存稳定性的颜料油墨，并且可以在使得着色材料几乎不被刮掉的水平下达到优异的耐刮擦性，即使在施加如此强烈的压力下刮擦图像时，手指指甲也不会刮伤记录介质在其非记录区域。颜料墨水含有颜料，具有特定结构的改性硅氧烷化合物和指定酸值和氢键参数（δh）的聚合物。

8. 发明申请

US20110175964A1 INK, INK-JET RECORDING METHOD, AND INK CARTRIDGE 有权
标题翻译： INK，INK-JET记录方法和INK CARTRIDGE
公开(公告)号：US20110175964A1
公开(公告)日：2011-07-21
申请号：US13008664
申请日：2011-01-18
申请人： Takashi Saito , Fumiaki Fujioka , Hiromitsu Kishi
发明人： Takashi Saito , Fumiaki Fujioka , Hiromitsu Kishi
IPC分类号： B41J2/175 , C09D11/10
CPC分类号： C09D11/324
摘要： An ink containing a plurality of polymers and carbon black, wherein the plurality of polymers include a polymer A having an acid value of 200 mgKOH/g or more and 300 mgKOH/g or less and a polymer B having an acid value of 80 mgKOH/g or more and 180 mgKOH/g or less, the weight average molecular weight of the polymer A is larger than the weight average molecular weight of the polymer B, the carbon black has a DBP oil absorption of 75 mL/100 g or less and a specific surface area of 200 m2/g or more, and each of -Ph-(CH2)n—NH2 and -Ph-(CH2)n—NH—R serving as a functional group is bonded to surfaces of the carbon black particles, wherein in these formulae, Ph represents a phenylene group, n represents an integer of 0 to 2, and R represents the polymer A.
摘要翻译：一种含有多种聚合物和炭黑的油墨，其中所述多种聚合物包括酸值为200mgKOH / g以上且300mgKOH / g以下的聚合物A和酸值为80mgKOH / g的聚合物B， g以上且180mgKOH / g以下，聚合物A的重均分子量大于聚合物B的重均分子量，碳黑的DBP吸油量为75mL / 100g以下，比表面积为200m 2 / g以上，作为官能团的-Ph-（CH2）n-NH2和-Ph-（CH2）n-NH-R中的每一个键合到炭黑粒子的表面其中，在这些式中，Ph表示亚苯基，n表示0〜2的整数，R表示聚合物A.

9. 发明授权

US08474964B2 Ink, ink-jet recording method, and ink cartridge 有权
标题翻译：墨水，喷墨记录方法和墨盒
公开(公告)号：US08474964B2
公开(公告)日：2013-07-02
申请号：US13008664
申请日：2011-01-18
申请人： Takashi Saito , Fumiaki Fujioka , Hiromitsu Kishi
发明人： Takashi Saito , Fumiaki Fujioka , Hiromitsu Kishi
IPC分类号： C09D11/02 , B41J2/17
CPC分类号： C09D11/324
摘要： An ink containing a plurality of polymers and carbon black, wherein the plurality of polymers include a polymer A having an acid value of 200 mgKOH/g or more and 300 mgKOH/g or less and a polymer B having an acid value of 80 mgKOH/g or more and 180 mgKOH/g or less, the weight average molecular weight of the polymer A is larger than the weight average molecular weight of the polymer B, the carbon black has a DBP oil absorption of 75 mL/100 g or less and a specific surface area of 200 m2/g or more, and each of -Ph-(CH2)n—NH2 and -Ph-(CH2)n—NH—R serving as a functional group is bonded to surfaces of the carbon black particles, wherein in these formulae, Ph represents a phenylene group, n represents an integer of 0 to 2, and R represents the polymer A.
摘要翻译：一种含有多种聚合物和炭黑的油墨，其中所述多种聚合物包括酸值为200mgKOH / g以上且300mgKOH / g以下的聚合物A和酸值为80mgKOH / g的聚合物B， g以上且180mgKOH / g以下，聚合物A的重均分子量大于聚合物B的重均分子量，碳黑的DBP吸油量为75mL / 100g以下，比表面积为200m 2 / g以上，作为官能团的-Ph-（CH2）n-NH2和-Ph-（CH2）n-NH-R中的每一个键合到炭黑粒子的表面其中，在这些式中，Ph表示亚苯基，n表示0〜2的整数，R表示聚合物A.

10. 发明申请

US20120127233A1 INK JET INK, INK CARTRIDGE, AND INK JET RECORDING METHOD 有权
标题翻译： INK喷墨墨盒，墨盒和喷墨记录方法
公开(公告)号：US20120127233A1
公开(公告)日：2012-05-24
申请号：US13291984
申请日：2011-11-08
申请人： Yoshihisa Yamashita , Takashi Saito , Tsuyoshi Furuse , Nobuyuki Matsumoto
发明人： Yoshihisa Yamashita , Takashi Saito , Tsuyoshi Furuse , Nobuyuki Matsumoto
IPC分类号： B41J2/175 , C08K5/3417
CPC分类号： C09D11/322 , B41J2/2107 , C08K5/0091 , C09D11/326
摘要： An ink jet ink contains a resin A, a resin B, and a pigment, in which the pigment is a halogenated metal phthalocyanine pigment being dispersed by the resin B, the resin A is a random copolymer having a carboxy group, the resin B is a block copolymer having a carboxy group, the acid value of the resin A is less than the acid value of the resin B, and the ink further includes a polybasic acid having a functional group whose pKa is 4.3 or less and a functional group whose pKa is 5.0 or more and 6.6 or less.
摘要翻译：喷墨油墨包含树脂A，树脂B和颜料，其中颜料是由树脂B分散的卤化金属酞菁颜料，树脂A是具有羧基的无规共聚物，树脂B是具有羧基的嵌段共聚物，树脂A的酸值小于树脂B的酸值，并且墨水还包含具有pKa为4.3以下的官能团的多元酸和pKa 为5.0以上且6.6以下。

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