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1. 发明授权

US07291392B2 Inorganic/organic complex nano-beads and method for manufacturing the same 失效
标题翻译：无机/有机复合纳米珠及其制造方法
公开(公告)号：US07291392B2
公开(公告)日：2007-11-06
申请号：US10469531
申请日：2001-09-12
申请人： Katsuhiko Naoi , Shunzo Suematsu
发明人： Katsuhiko Naoi , Shunzo Suematsu
IPC分类号： B32B5/16 , B05D1/04
CPC分类号： H01G9/155 , H01L51/0034 , H01L51/0035 , Y02E60/13 , Y10S977/773 , Y10T428/2982 , Y10T428/2991
摘要： An inorganic/organic composite material which is advantageous in physical characteristics (mechanical strength), chemical characteristics (thermal stability) and electric characteristics (electric conductivity), as compared with a sole system, as being compounded in nano order. An improved energy storage device using the inorganic/organic composite nano-beads, and especially an improved electrochemical capacitor for covering the range of a power energy density which cannot be achieved with devices of the prior art. A method of producing the inorganic/-organic composite nano-beads.The inorganic/organic composite nano-beads have a three-dimensional structure in which nuclei are made of an inorganic material having a particle diameter of nano order and a high electronic conductivity, and are covered with thin films of an organic conductive material.
摘要翻译：无机/有机复合材料与单体系统相比，其纳米级复合材料的物理特性（机械强度），化学特性（热稳定性）和电特性（导电性）都有利。使用无机/有机复合纳米珠的改进的能量存储装置，特别是用于覆盖现有技术的装置无法实现的功率能量密度范围的改进的电化学电容器。一种无机/无机复合纳米珠的制造方法。无机/有机复合纳米珠具有三维结构，其中核由具有纳米级粒径和高电子导电性的无机材料制成，并被有机导电材料的薄膜覆盖。

2. 发明申请

US20090026085A1 METHOD FOR PRODUCING ELECTRODE FOR ELECTROCHEMICAL ELEMETN AND METHOD FOR PRODUCING ELECTROCHEMICAL ELEMENT WITH THE ELECTRODE 审中-公开
标题翻译：用于生产电化学电极的电极的方法和用电极生产电化学元件的方法
公开(公告)号：US20090026085A1
公开(公告)日：2009-01-29
申请号：US11917002
申请日：2005-06-10
申请人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
发明人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
IPC分类号： C25B3/00
CPC分类号： H01G11/48 , H01G11/24 , H01G11/28 , H01G11/30 , H01G11/32 , H01G11/86 , H01M4/0438 , H01M4/0466 , H01M4/137 , H01M4/1399 , H01M4/60 , H01M4/602 , H01M4/606 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： A method for producing an electrode for an electrochemical element absorbs monomers for polymerization on a surface having a specific surface area of 100 to 3000 m2g−1 and having an average pore diameter in the range of 0.4 to 100 nm, performing electrolysis polymerization by applying pulse voltage, and forming a conductive polymer layer on the surface of the conductive porous material, forming a thin and uniform electrode film. In a method for producing an electrochemical element, a conductive polymer layer is formed on the conductive porous material by absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area and pore diameter as above forming a electrochemical cell by using the conductive porous material, the monomers are absorbed in the pores, putting the electrochemical cell and the electrolyte solution in an outer casing, and performing electrolysis polymerization of the monomers in the electrolyte solution.
摘要翻译：一种电化学元件用电极的制造方法，在比表面积为100〜3000m 2 / g的表面吸收聚合用单体，平均孔径为0.4〜100nm，通过施加脉冲进行电解聚合电压，并在导电性多孔材料的表面上形成导电聚合物层，形成薄而均匀的电极膜。在电化学元件的制造方法中，通过在上述形成电化学电池的比表面积和孔径以上的导电性多孔质材料的表面上吸收用于聚合的单体，在导电性多孔质材料上形成导电性聚合物层，导电多孔材料，单体被吸收在孔中，将电化学电池和电解质溶液放入外壳中，并进行电解液中单体的电解聚合。

3. 发明授权

US08427811B2 Electrode for electric double layer capacitor and method for producing the same 有权
标题翻译：双电层电容器用电极及其制造方法
公开(公告)号：US08427811B2
公开(公告)日：2013-04-23
申请号：US12679470
申请日：2008-09-29
申请人： Kenji Machida , Shunzo Suematsu , Kenji Tamamitsu
发明人： Kenji Machida , Shunzo Suematsu , Kenji Tamamitsu
IPC分类号： H01G9/00
CPC分类号： H01G11/36 , H01G9/016 , H01G9/058 , H01G9/155 , H01G11/28 , H01G11/70 , Y02E60/13 , Y10T29/417
摘要： An electrical double-layer capacitor electrode with excellent capacitance characteristics is obtained together with a manufacturing method therefor. Paper-molded sheet 2 of carbon nanotubes is integrated with etched foil 1 constituting a collector, by means of bumps and indentations 1a formed on the surface of etched foil 1 to prepare an electrical double-layer capacitor electrode. Alternatively, carbon nanotubes 4 grown around core catalyst particles on substrate 3 are integrated with etched foil 1 by means of bumps and indentations 1a formed on the surface of etched foil 1 to prepare an electrical double-layer capacitor electrode. To manufacture these electrodes, this carbon nanotube sheet 2 or substrate 3 with carbon nanotubes grown thereon is laid over bumps and indentations 1a on the surface of etched foil 1, and the sheet or substrate and the foil are pressed under 0.01 to 100 t/cm2 of pressure to integrate the carbon nanotubes with the etched foil.
摘要翻译：获得具有优异的电容特性的电双层电容器电极及其制造方法。通过形成在蚀刻箔1的表面上的凸起和凹陷1a，将碳纳米管的纸模制片2与构成收集器的蚀刻箔1集成，以制备双电层电容器电极。或者，通过形成在蚀刻箔1的表面上的凸起和凹陷1a，与蚀刻箔1一体地在基板3上的核心催化剂颗粒周围生长的碳纳米管4，以制备双电层电容器电极。为了制造这些电极，将碳纳米管片2或其上生长有碳纳米管的基板3放置在蚀刻箔1的表面上的凸起和凹槽1a上，并且在0.01至100t / cm 2下压制片材或基底和箔的压力以将碳纳米管与蚀刻箔整合。

4. 发明申请

US20100259867A1 ELECTRODE FOR ELECTRIC DOUBLE LAYER CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：电双层电容器用电极及其制造方法
公开(公告)号：US20100259867A1
公开(公告)日：2010-10-14
申请号：US12679470
申请日：2008-09-29
申请人： Kenji Machida , Shunzo Suematsu , Kenji Tamamitsu
发明人： Kenji Machida , Shunzo Suematsu , Kenji Tamamitsu
IPC分类号： H01G9/058 , B32B37/10 , B32B38/00 , B32B38/10
CPC分类号： H01G11/36 , H01G9/016 , H01G9/058 , H01G9/155 , H01G11/28 , H01G11/70 , Y02E60/13 , Y10T29/417
摘要： An electrical double-layer capacitor electrode with excellent capacitance characteristics is obtained together with a manufacturing method therefor.Paper-molded sheet 2 of carbon nanotubes is integrated with etched foil 1 constituting a collector, by means of bumps and indentations 1a formed on the surface of etched foil 1 to prepare an electrical double-layer capacitor electrode. Alternatively, carbon nanotubes 4 grown around core catalyst particles on substrate 3 are integrated with etched foil 1 by means of bumps and indentations 1a formed on the surface of etched foil 1 to prepare an electrical double-layer capacitor electrode. To manufacture these electrodes, this carbon nanotube sheet 2 or substrate 3 with carbon nanotubes grown thereon is laid over bumps and indentations la on the surface of etched foil 1, and the sheet or substrate and the foil are pressed under 0.01 to 100 t/cm2 of pressure to integrate the carbon nanotubes with the etched foil.
摘要翻译：获得具有优异的电容特性的电双层电容器电极及其制造方法。通过形成在蚀刻箔1的表面上的凸起和凹陷1a，将碳纳米管的纸模制片2与构成收集器的蚀刻箔1集成，以制备双电层电容器电极。或者，通过形成在蚀刻箔1的表面上的凸起和凹陷1a，与蚀刻箔1一体地在基板3上的核心催化剂颗粒周围生长的碳纳米管4，以制备双电层电容器电极。为了制造这些电极，将碳纳米管片2或其上生长有碳纳米管的基板3放置在蚀刻箔1的表面上的凸起和凹槽1a上，并且将片或基板和箔压制在0.01至100t / cm 2 的压力以将碳纳米管与蚀刻箔整合。

5. 发明申请

US20080300381A1 Electrode Material and Electrochemical Device 审中-公开
标题翻译：电极材料和电化学装置
公开(公告)号：US20080300381A1
公开(公告)日：2008-12-04
申请号：US11664281
申请日：2004-09-30
申请人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
发明人： Hidenori Uchi , Kenji Tamamitsu , Shunzo Suematsu , Satoru Tsumeda , Alexander M. Timonov , Sergey A. Logvinov , Nikolay Shkolnik , Sam Kogan
IPC分类号： C08G79/00
CPC分类号： H01M4/60 , H01G9/155 , H01M4/0452 , H01M4/0466 , H01M4/137 , H01M4/602 , H01M10/0525 , H01M2004/028 , Y02E60/13
摘要： To provide an electrode material excellent in output characteristics and cycle property and an electrochemical device using the electrode material. The electrode material comprising polymer complex compound represented by the following graphical formula: and the electrochemical device using the electrode material. Even if such a large size ion is employed, enhanced output characteristics could be obtained in the present invention. Polymer complex compound is polarized due to an electron attracting substituent, or steric hindrance occurs due to a substituent having a branch structure so that interval of polymer complex compound formed on the electrode is increased and doping reaction. Therefore, even if using large size ions smooth and rapid doping and undoping reaction could take place.
摘要翻译：提供输出特性和循环特性优异的电极材料和使用电极材料的电化学装置。该电极材料包含由以下图示式表示的聚合物复合化合物：和使用电极材料的电化学装置。即使采用这样大的离子，本发明也可以得到增强的输出特性。聚合物复合化合物由于吸电子取代基而极化，或者由于具有分支结构的取代基而发生空间位阻，使得在电极上形成的聚合物络合物的间隔增加和掺杂反应。因此，即使使用大尺寸离子，也可以进行平滑，快速的掺杂和非掺杂反应。

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