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    • 10. 发明申请
    • Semiconductor device
    • 半导体器件
    • US20050001251A1
    • 2005-01-06
    • US10834928
    • 2004-04-30
    • Hiroshi ItokawaKoji YamakawaKatsuaki Natori
    • Hiroshi ItokawaKoji YamakawaKatsuaki Natori
    • H01L21/316H01L21/02H01L21/8246H01L27/105H01L27/108H01L27/115
    • H01L27/11502H01L27/11507H01L28/55H01L28/65
    • A semiconductor device comprising a semiconductor substrate, and a capacitor provided above the semiconductor substrate, and including a bottom electrode, a top electrode and a dielectric film between the bottom and top electrodes, the bottom electrode including a conductive film selected from a noble metal film and a noble metal oxide film, a metal oxide film having a perovskite structure, provided between the dielectric film and the conductive film, expressed by ABO3, and containing first metal element as B-site element, and a metal film provided between the conductive film and the metal oxide film, and containing second metal element which is B-site element of a metal oxide having a perovskite structure, a decrease of Gibbs free energy when the second metal element forms oxide being larger than that when the first metal element forms oxide, a thickness of the metal oxide film being 5 nm or less.
    • 一种半导体器件,包括半导体衬底和设置在半导体衬底之上的电容器,并且在底电极和顶电极之间包括底电极,顶电极和电介质膜,底电极包括选自贵金属膜 和由ABO3表示的电介质膜和导电膜之间具有钙钛矿结构的金属氧化物膜,并且含有作为B位元素的第一金属元素的金属氧化物膜和设置在导电膜之间的金属膜 和金属氧化物膜,并且含有作为具有钙钛矿结构的金属氧化物的B位元素的第二金属元素,当第二金属元素形成氧化物时,吉布斯自由能的降低大于第一金属元素形成氧化物时的吉布斯自由能的降低 ,金属氧化物膜的厚度为5nm以下。