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1. 发明授权

US5288848A Process for preparation of high molecular weight, optionally branched polyarylene sulphides 失效
标题翻译：制备高分子量，任意支化聚亚芳基硫化物的方法
公开(公告)号：US5288848A
公开(公告)日：1994-02-22
申请号：US978174
申请日：1992-11-17
申请人： Karsten Idel , Wolfgang Ebert , Ludwig Bottenbruch , Dieter Freitag , Rolf-Volker Meyer
发明人： Karsten Idel , Wolfgang Ebert , Ludwig Bottenbruch , Dieter Freitag , Rolf-Volker Meyer
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0231 , C08G75/0254
摘要： The invention relates to a process for the preparation of optionally branched, high molecular weight polyarylene sulphides with melt viscosities which can be established at defined values and low corrosion.These polyarylene sulphides are obtained by reacting alkali metal sulphides, if appropriate mixed with alkali metal bisulphides and reaction accelerators, with dihalogenoaromatics and, if appropriate, polyhalogenoaromatics, with the addition of particular monohalogenoaromatics as chain stoppers.
摘要翻译：本发明涉及一种制备任选支化的高分子量聚亚芳基硫醚的方法，其熔融粘度可以在确定的值和低腐蚀下确定。这些聚亚芳基硫化物是通过使碱金属硫化物（如果适用的话）与碱金属二硫化物和反应促进剂混合，与二卤代芳族化合物反应，如果合适的话，通过加入特定的一卤代芳族化合物作为连锁停止剂。

2. 发明授权

US4786712A Process for the preparation of optionally branched polyarylene sulphides having reduced corrosiveness with ketone diluent and organic solvent 失效
标题翻译：用酮稀释剂和有机溶剂制备具有降低腐蚀性的任选支化聚亚芳基硫醚的方法
公开(公告)号：US4786712A
公开(公告)日：1988-11-22
申请号：US661936
申请日：1984-10-17
申请人： Edgar Ostlinning , Karsten Idel , Rolf-Volker Meyer
发明人： Edgar Ostlinning , Karsten Idel , Rolf-Volker Meyer
IPC分类号： C08G75/0281 , C08G75/06 , C08G75/14
CPC分类号： C08G75/0281
摘要： This invention relates to a process for the preparation of optionally branched polyarylene sulphides which are distinguished by their substantially lower corrosiveness.
摘要翻译：本发明涉及一种制备任选支化聚亚芳基硫化物的方法，其特征在于它们的较低的腐蚀性。

3. 发明授权

US4946927A Preparation of aromatic polycarbonates, aromatic polyester carbonates and aromatic polyesters with organic phase comprising mixture of hydrocarbons 失效
标题翻译：芳族聚碳酸酯，芳族聚酯碳酸酯和芳族聚酯与有机相的制备，包括烃的混合物
公开(公告)号：US4946927A
公开(公告)日：1990-08-07
申请号：US331313
申请日：1989-03-30
申请人： Wolfgang Ebert , Rolf-Volker Meyer , Rolf Dhein , Udo Oels
发明人： Wolfgang Ebert , Rolf-Volker Meyer , Rolf Dhein , Udo Oels
IPC分类号： C08G63/19 , C08G63/64 , C08G63/79 , C08G64/22 , C08G64/24
CPC分类号： C08G63/64 , C08G63/79 , C08G64/24
摘要： The present invention relates to a process for the preparation of aromatic polycarbonates, aromatic polyester carbonates and aromatic polyesters by the known two phase interface process, which is characterized in that the organic phase used is a mixture of aromatic hydrocarbons with alkanes and/or cycloalkanes.
摘要翻译：本发明涉及通过已知的两相界面方法制备芳族聚碳酸酯，芳族聚酯碳酸酯和芳族聚酯的方法，其特征在于所用的有机相是芳族烃与烷烃和/或环烷烃的混合物。

4. 发明授权

US4874816A Vinyl copolymers with grafted-on polycarbonate chains, their production and use 失效
标题翻译：具有接枝聚碳酸酯链的乙烯基共聚物，其生产和使用
公开(公告)号：US4874816A
公开(公告)日：1989-10-17
申请号：US194648
申请日：1988-05-13
申请人： Ralf Dujardin , Wolfgang Ebert , Rolf-Volker Meyer , Klaus Berg , Ulrich Grigo , Wolfgang Wehnert
发明人： Ralf Dujardin , Wolfgang Ebert , Rolf-Volker Meyer , Klaus Berg , Ulrich Grigo , Wolfgang Wehnert
IPC分类号： C08F8/00 , C08G64/00 , C08G64/18 , C08G64/20 , C08G64/24 , C08G83/00 , C08L25/04 , C08L69/00
CPC分类号： C08G64/18 , C08F8/00
摘要： The invention relates to a process for the production of vinyl copolymers with grafted-on polycarbonate chains, to the grafted vinyl copolymers obtainable by the process according to the invention, to their use as modifiers for mixtures of thermoplastic polycarbonates and thermoplastic polystyrenes, to such mixtures themselves and to the use of such mixtures as substrates for optical discs.
摘要翻译：本发明涉及一种生产具有接枝聚碳酸酯链的乙烯基共聚物，可通过本发明方法获得的接枝乙烯基共聚物，其作为热塑性聚碳酸酯和热塑性聚苯乙烯混合物的改性剂用于这种混合物的方法以及使用这种混合物作为光盘的基片。

5. 发明授权

US4889911A Process for the production of fully aromatic, thermotropic polyesters and polyester carbonates 失效
标题翻译：用于生产完全芳香族，热致变性聚酯和聚酯碳酸酯的方法
公开(公告)号：US4889911A
公开(公告)日：1989-12-26
申请号：US231071
申请日：1988-08-11
申请人： Harald Pielartzik , Wolfgang Ebert , Rolf-Volker Meyer , Hans-Joachim Traenckner , Edgar Ostlinning
发明人： Harald Pielartzik , Wolfgang Ebert , Rolf-Volker Meyer , Hans-Joachim Traenckner , Edgar Ostlinning
IPC分类号： C08G63/60 , C08G63/64 , C08G63/87
CPC分类号： C08G63/605 , C08G63/64 , C08G63/87
摘要： Thermotropic, fully aromatic polyesters and polyester carbonates are produced by esterification of optionally substituted p-hydroxybenzoic acids and aromatic dicarboxylic acids with diaryl carbonate at temperatures in the range from 100.degree. to 220.degree. C. and subsequent transesterification of the aryl ester obtained with diphenols and, optinally, more diaryl carbonate, accompanied by polycondensation, at temperatures in the range from 250.degree. to 330.degree. C., the esterification, the transesterification and the polycondensation being carried out in the presence of heterocyclic compounds containing 1 to 3 nitrogen atoms.
摘要翻译：通过任选取代的对羟基苯甲酸和芳族二羧酸与碳酸二芳基酯在100℃至220℃的温度下酯化制备热致全芳香族聚酯和聚酯碳酸酯，然后由二酚得到的芳基酯和在250-330℃的温度下，优选碳酸二芳基酯，伴随着缩聚反应，酯化，酯交换反应和缩聚反应在含1-3个氮原子的杂环化合物的存在下进行。

6. 发明授权

US4535149A Process for the production of polyarylene sulphides 失效
标题翻译：生产聚亚芳基硫化物的方法
公开(公告)号：US4535149A
公开(公告)日：1985-08-13
申请号：US607957
申请日：1984-05-07
申请人： Wolfgang Ebert , Rolf-Volker Meyer , Karsten-Josef Idel , Rolf Dhein
发明人： Wolfgang Ebert , Rolf-Volker Meyer , Karsten-Josef Idel , Rolf Dhein
IPC分类号： C08G75/02 , C08G75/06 , C08G75/14
CPC分类号： C08G75/0268
摘要： This invention relates to a new process for the production of optionally branched polyarylene sulphides from optionally substituted halo-benzenes in admixture with polyhalogen aromatic compounds and alkali sulphides in polar solvents in the presence of disulphide compounds.
摘要翻译：本发明涉及一种用于在二硫化物存在下从极性溶剂中与多卤代芳族化合物和碱金属硫化物混合制备任选取代的卤代苯的任选支化聚亚芳基硫化物的新方法。

7. 发明授权

US4943623A Process for the production of polyesters and their use as binder or binder component in powder lacquers 失效
标题翻译：生产聚酯的方法及其作为粉末涂料中的粘合剂或粘合剂成分的用途
公开(公告)号：US4943623A
公开(公告)日：1990-07-24
申请号：US273949
申请日：1988-11-21
申请人： Wolfgang Ebert , Rolf-Volker Meyer , Hans-Joachim Kreuder
发明人： Wolfgang Ebert , Rolf-Volker Meyer , Hans-Joachim Kreuder
IPC分类号： C08G63/12 , C08G63/60 , C08G63/81 , C09D5/46 , C09D167/00
CPC分类号： C09D167/00 , C08G63/60 , C08G63/81 , Y10T428/31565 , Y10T428/31786
摘要： Polyesters useful as a binder or a component of a binder for powder lacquers and which contain hydroxyls, carboxyls or both and which have an acid value of up to 50, a hydroxyl value of up to 200 and a sum of hydroxyl value and acid value of from 20 to 200 is produced by reacting:(a) an acid component selected from the group consisting of (a1) at least one poly-functional organic carboxylic acid, (a2) at least one ester-forming derivative of a poly-functional organic carboxylic acid, (a3) at least one organic hydroxycarboxylic acid, (a4) at least one lactone of an organic hydroxycarboxylic acid, and mixtures thereof, with the proviso that at least 50 mol-% of component (a) consists of aromatic species of components (a1), (a2), (a3), (a4), or mixtures thereof,with(b) a polyol component which is at least one polyhydric alcohol having a molecular weight in the range from 62 to 250,while maintaining an equivalent ratio of carboxyl groups to hydroxyl groups of form 0.65:1 to 1.5:1, with the proviso that component (b) is used in a quantity of at least 30% by weight, based on the weight of component (a), and the reaction is carried out in the presence of(c) at least 5% by weight, based on the weight of components (a) and (b), of a solvent containing amide groups, lactam groups, or both and said solvent is free from any nitrogenhydrogen bonds.
摘要翻译：可用作粘合剂或用于粉末涂料的粘合剂组分的聚酯，其含有羟基，羧基或两者，并且其酸值高达50，羟值高达200，羟基值和酸值之和通过使（a）选自（a1）至少一种多官能有机羧酸的酸成分，（a2）至少一种多官能有机羧酸的成酯衍生物，羧酸，（a3）至少一种有机羟基羧酸，（a4）至少一种有机羟基羧酸的内酯及其混合物，条件是至少50摩尔％的组分（a）由芳族物质组分（a1），（a2），（a3），（a4）或其混合物与（b）至少一种分子量为62-250的多元醇的多元醇组分，同时保持羧基与羟基的当量比为0.65：1至1.5：1 条件是组分（b）以基于组分（a）的重量为至少30重量％的量使用，并且反应在（c）至少5重量％的存在下进行，基于组分（a）和（b）的重量，含有酰胺基，内酰胺基或二者的溶剂，所述溶剂不含任何氮氢键。

8. 发明授权

US4585856A Process for the preparation of polyarylene sulphides 失效
标题翻译：聚亚芳基硫醚的制备方法
公开(公告)号：US4585856A
公开(公告)日：1986-04-29
申请号：US768575
申请日：1985-08-23
申请人： Wolfgang Ebert , Rolf-Volker Meyer , Karsten-Josef Idel , Rudiger Schubart
发明人： Wolfgang Ebert , Rolf-Volker Meyer , Karsten-Josef Idel , Rudiger Schubart
IPC分类号： C08G75/02 , C08G75/06 , C08G75/14
CPC分类号： C08G75/0254
摘要： This invention relates to a new process for the preparation of optionally branched polyarylene sulphides from optionally substituted halogen benzenes in admixture with aromatic polyhalogen compounds and alkali metal sulphides in polar solvents in the presence of thio salts.
摘要翻译：本发明涉及一种用于在硫代盐存在下由极性溶剂中的芳族多卤素化合物和碱金属硫化物混合制备任选取代的卤代苯任选支化的聚亚芳基硫化物的新方法。

9. 发明授权

US4973652A Process for the production of aromatic polycarbonates, aromatic polyester carbonates and aromatic polyesters with p containing catalyst and mixture of hydrocarbons 失效
标题翻译：用于生产芳族聚碳酸酯，芳族聚酯碳酸酯和芳族聚酯与含p催化剂和烃混合物的方法
公开(公告)号：US4973652A
公开(公告)日：1990-11-27
申请号：US361876
申请日：1989-06-06
申请人： Wolfgang Ebert , Rolf-Volker Meyer , Rolf Dhein , Udo Oels
发明人： Wolfgang Ebert , Rolf-Volker Meyer , Rolf Dhein , Udo Oels
IPC分类号： C08G63/81 , C08G63/19 , C08G63/60 , C08G63/64 , C08G63/79 , C08G63/87 , C08G64/20 , C08G64/24 , C08G64/30
CPC分类号： C08G63/64 , C08G63/79 , C08G63/87 , C08G64/24
摘要： The invention relates to a process for the production of aromatic polycarbonates, aromatic polyester carbonates and aromatic polyesters by the known two-phase interfacial method which is characterized in that a mixture of aromatic hydrocarbons with alkanes and/or cycloalkanes is used as the organic phase and in that phosphines or phosphine oxides are used as the catalysts.
摘要翻译：本发明涉及通过已知的两相界面方法生产芳族聚碳酸酯，芳族聚酯碳酸酯和芳族聚酯的方法，其特征在于使用芳族烃与烷烃和/或环烷烃的混合物作为有机相，其中使用膦或氧化膦作为催化剂。

10. 发明授权

US4837301A Process for the preparation of high molecular weight optionally branched polyarylenesulphides 失效
标题翻译：用于制备高分子量任选支化的聚芳基硫化物的方法
公开(公告)号：US4837301A
公开(公告)日：1989-06-06
申请号：US142186
申请日：1988-01-06
申请人： Volker Glock , Wolfgang Ebert , Rolf-Volker Meyer
发明人： Volker Glock , Wolfgang Ebert , Rolf-Volker Meyer
IPC分类号： C08G75/04
CPC分类号： C08G75/04
摘要： This invention relates to a process for the preparation of high molecular weight, optionally branched polyarylenesulphides from alkali metal sulphides, optionally in admixture with alkali metal hydrogen sulphides and aromatic dihalogen compounds, in a polar solvent in the presence of from 0.1 to 6.0 mol-%, preferably from 0.25 to 4.0 mol-%, of an aromatic monoalkoxy or monoalkylthio compound. The polyarylenesulphides obtained have reproducibly adjustable melt viscosities and molecular weights and are distinguished by their reduced tendency to corrosion.
摘要翻译：本发明涉及一种制备高分子量，任选支化的聚芳基硫化物的方法，其中碱金属硫化物任选与碱金属硫化氢和芳族二卤素化合物混合，在极性溶剂中，存在0.1-60mol％，优选0.25至4.0mol％的芳族单烷氧基或单烷硫基化合物。获得的聚芳基硫化物具有可重复调节的熔体粘度和分子量，并且其腐蚀倾向降低。

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