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1. 发明申请

US20110021680A1 Polyol Ester Plasticizers and Process of Making the Same 审中-公开
标题翻译：多元醇酯增塑剂及其制造方法
公开(公告)号：US20110021680A1
公开(公告)日：2011-01-27
申请号：US12934294
申请日：2009-03-18
申请人： Karla S. Colle , Phillippe Louis Buess , Eddy Theophile Van Driessche , Allen D. Godwin , Ramzi Yanni Saleh , Jon E.R. Stanat , Raphael Frans Caers
发明人： Karla S. Colle , Phillippe Louis Buess , Eddy Theophile Van Driessche , Allen D. Godwin , Ramzi Yanni Saleh , Jon E.R. Stanat , Raphael Frans Caers
IPC分类号： C08L91/00 , C07C69/66 , C07C69/76 , C07C69/34
CPC分类号： C08K5/11 , C07B41/12 , C07C45/50 , C07C51/235 , C07C67/08 , C07C69/30 , C08K5/0016 , C08K5/103 , C08K5/12 , C07C69/78 , C08L27/06 , C07C47/02
摘要： Triglyceride and other polyol ester PVC plasticizers can be produced by recovery of branched C6 to C9 aldehydes from a hydroformylation product, optional hydrogenation to the alcohol, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, ethylene glycol, propylene glycol or mixtures thereof. The branched alkyl chains comprise at least 10% methyl branching. Special triglycerides are derived from branched aliphatic acids having alkyl chains with average carbon numbers from 6 to 9 and at least 10% methyl branching. These triglycerides are fast fusing plasticisers if before esterification with glycerol, an aryl acid is introduced together with the aliphatic acids.
摘要翻译：甘油三酯和其它多元醇酯类PVC增塑剂可以通过从加氢甲酰化产物回收支链C6至C9醛，任选的氢化成醇，用氧气和/或空气氧化成酸，回收所得酸，并用甘油酯化，乙二醇，丙二醇或其混合物。支链烷基链包含至少10％的甲基支链。特别的甘油三酸酯衍生自具有平均碳数为6至9和至少10％甲基支链的烷基链的支链脂族酸。如果在用甘油酯化之前，这些甘油三酯是快速熔化增塑剂，芳基酸与脂肪酸一起引入。

2. 发明授权

US07586017B2 Hydrogenation 有权
标题翻译：氢化
公开(公告)号：US07586017B2
公开(公告)日：2009-09-08
申请号：US10582742
申请日：2004-12-16
申请人： Eddy Theophyle Andrea Van Driessche , Philippe Louis Buess , Raphael Frans Caers , Arie Van Vliet , Ramzi Yanni Saleh , Jose Manuel Vargas , Kenneth Lloyd Riley , Magdiel Agosto
发明人： Eddy Theophyle Andrea Van Driessche , Philippe Louis Buess , Raphael Frans Caers , Arie Van Vliet , Ramzi Yanni Saleh , Jose Manuel Vargas , Kenneth Lloyd Riley , Magdiel Agosto
IPC分类号： C07C29/141
CPC分类号： C07C29/16 , C07C11/02 , C07C29/141 , C07C29/175 , C07C45/50 , C07C31/125 , C07C47/02
摘要： The use of a controlled amount of water in a hydrogenation stage of the oxo process for the production of alcohols which uses at least two reactors in series improves the efficiency of the hydrogenation reaction and catalyst life as does a reduction in the amount of sulphur, chlorine and hydroformylation catalyst residues in the feed to hydrogenation.
摘要翻译：在氧化方法的氢化阶段中使用受控量的水来生产使用至少两个串联的反应器的醇的提高氢化反应和催化剂寿命的效率，同时硫，氯的量的减少和加氢甲酰化催化剂残余物在进料中进行氢化。

3. 发明申请

US20100137630A1 Manufacture of Purified Alcohols 有权
标题翻译：精制醇的制造
公开(公告)号：US20100137630A1
公开(公告)日：2010-06-03
申请号：US12531759
申请日：2008-02-27
申请人： Ronald Dean Garton , Corey W. Reed , Rao Krishna Kulai , Bruce D. Lilly , Ramzi Yanni Saleh , Raphael Frans Caers
发明人： Ronald Dean Garton , Corey W. Reed , Rao Krishna Kulai , Bruce D. Lilly , Ramzi Yanni Saleh , Raphael Frans Caers
IPC分类号： C07C29/141 , C07C69/74 , C07C69/78 , C07C69/75 , C07C69/73 , C07C69/67 , C07C67/00 , B01J19/00
CPC分类号： C07C41/28 , B01D3/009 , B01J8/025 , B01J8/0278 , B01J2219/00006 , C07C29/141 , C07C29/88 , C07C41/48 , C07C41/56 , C07C45/50 , C07C67/08 , C07C67/303 , C07C2601/14 , Y02P20/127 , C07C69/78 , C07C69/80 , C07C69/75 , C07C47/02 , C07C43/15 , C07C43/303 , C07C31/125
摘要： Acetals are formed from an aldehyde hydrogenation product mixture comprising alcohols and at most 2% of alde-hydes and the product is distilled to yield purified alcohols and a second stream containing acetals and/or unsaturated ethers.
摘要翻译：缩醛由包含醇和至多2％的二水合物的醛氢化产物混合物形成，并将产物蒸馏以产生纯化的醇和含有缩醛和/或不饱和醚的第二料流。

4. 发明授权

US08288596B2 Manufacture of purified alcohols 有权
标题翻译：精制醇的制造
公开(公告)号：US08288596B2
公开(公告)日：2012-10-16
申请号：US12531759
申请日：2008-02-27
申请人： Ronald Dean Garton , Corey W. Reed , Krishna Kulai Rao , Bruce D. Lilly , Ramzi Yanni Saleh , Raphael Frans Caers
发明人： Ronald Dean Garton , Corey W. Reed , Krishna Kulai Rao , Bruce D. Lilly , Ramzi Yanni Saleh , Raphael Frans Caers
IPC分类号： C07C29/88 , C07C27/74
CPC分类号： C07C41/28 , B01D3/009 , B01J8/025 , B01J8/0278 , B01J2219/00006 , C07C29/141 , C07C29/88 , C07C41/48 , C07C41/56 , C07C45/50 , C07C67/08 , C07C67/303 , C07C2601/14 , Y02P20/127 , C07C69/78 , C07C69/80 , C07C69/75 , C07C47/02 , C07C43/15 , C07C43/303 , C07C31/125
摘要： Acetals are formed from an aldehyde hydrogenation product mixture comprising alcohols and at most 2% of alde-hydes and the product is distilled to yield purified alcohols and a second stream containing acetals and/or unsaturated ethers.
摘要翻译：缩醛由包含醇和至多2％的二水合物的醛氢化产物混合物形成，并将产物蒸馏以产生纯化的醇和含有缩醛和/或不饱和醚的第二料流。

5. 发明授权

US08389625B2 Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks 有权
标题翻译：从可再生原料生产合成烃流体，增塑剂和合成润滑剂基础油
公开(公告)号：US08389625B2
公开(公告)日：2013-03-05
申请号：US12653742
申请日：2009-12-17
申请人： Margaret May-Som Wu , Karla Schall Colle , Ramzi Yanni Saleh , Allen D. Godwin , Jon Edmond Randolph Stanat
发明人： Margaret May-Som Wu , Karla Schall Colle , Ramzi Yanni Saleh , Allen D. Godwin , Jon Edmond Randolph Stanat
IPC分类号： C08K5/09
CPC分类号： C07D317/36 , C08L21/00 , C10G3/44 , C10G3/48 , C10G29/205 , C10G2300/1014 , C10G2300/1018 , C10G2300/1092 , C10G2300/30 , C10G2300/302 , C10G2300/304 , C10G2400/06 , C10G2400/10 , C10M107/10 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2270/00 , Y02P30/20
摘要： This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.
摘要翻译：本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。

6. 发明申请

US20100160506A1 Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks 有权
标题翻译：从可再生原料生产合成烃流体，增塑剂和合成润滑剂基础油
公开(公告)号：US20100160506A1
公开(公告)日：2010-06-24
申请号：US12653742
申请日：2009-12-17
申请人： Margaret May-Som Wu , Karla Schall Colle , Ramzi Yanni Saleh , Allen D. Godwin , John Edmond Randolph Stanat
发明人： Margaret May-Som Wu , Karla Schall Colle , Ramzi Yanni Saleh , Allen D. Godwin , John Edmond Randolph Stanat
IPC分类号： C08K5/1515 , C08K5/109 , C07D301/03 , C07D317/24 , C07C1/207
CPC分类号： C07D317/36 , C08L21/00 , C10G3/44 , C10G3/48 , C10G29/205 , C10G2300/1014 , C10G2300/1018 , C10G2300/1092 , C10G2300/30 , C10G2300/302 , C10G2300/304 , C10G2400/06 , C10G2400/10 , C10M107/10 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2270/00 , Y02P30/20
摘要： This disclosure is directed to an integrated method for making synthetic hydrocarbon fluids, plasticizers and polar synthetic lubricant base stocks from a renewable feedstock. More particularly, the disclosure is directed to a metathesis reaction of natural oil or its derivative ester and ethylene in the presence of an effective amount of a metathesis catalyst to form linear alpha-olefins, internal olefins and reduced chain length triglycerides. The linear alpha-olefins and/or internal olefins are polymerized to produce synthetic hydrocarbon fluids in the presence of a suitable catalyst. The reduced chain length triglycerides are converted into polar synthetic lubricant base stocks or plasticizers by hydrogenation, isomerization, followed by hydrogenations, or by hydroisomerization processes. Alternatively, the reduced chain length triglycerides can also be epoxidized to form epoxidized triglyceride plasticizers, optionally followed by carbonation, to form carbonated triglyceride plasticizers.
摘要翻译：本发明涉及从可再生原料制备合成烃流体，增塑剂和极性合成润滑剂基础油的综合方法。更具体地，本公开涉及天然油或其衍生物酯和乙烯在有效量的复分解催化剂存在下的复分解反应，以形成线性α-烯烃，内烯烃和还原链长度甘油三酯。在合适的催化剂存在下，将线性α-烯烃和/或内烯烃聚合以产生合成烃流体。还原的链长度甘油三酯通过氢化，异构化，随后氢化或通过加氢异构化方法转化为极性合成润滑剂基础油料或增塑剂。或者，还原链长度甘油三酯也可以被环氧化以形成环氧化甘油三酯增塑剂，任选地随后碳酸化形成碳酸化甘油三酯增塑剂。

7. 发明授权

US06562996B2 Alkyl aromatic aldehydes 失效
公开(公告)号：US06562996B2
公开(公告)日：2003-05-13
申请号：US09933519
申请日：2001-08-20
申请人： Ramzi Yanni Saleh
发明人： Ramzi Yanni Saleh
IPC分类号： C07C6300
CPC分类号： C07C63/307 , C07C7/14858 , C07C45/49 , C07C45/82 , C07C47/542 , C07C51/235 , C07C51/265 , C07C63/16 , C07C63/26 , C07C15/08
摘要： A composition containing isomeric mixtures of arylaldehydes prepared from a mixed alkyl aromatic feedstock. A composition containing isomeric mixtures of dimethylbenzaldehydes prepared from a mixed xylene feedstock using a Gatterman-Koch type reaction. A composition of isomeric mixtures of tolualdehydes prepared from a toluene feedstock using a Gatterman-Koch type reaction.

8. 发明授权

US08815992B2 Tetracarboxylic ester plasticizers 有权
标题翻译：四羧酸酯增塑剂
公开(公告)号：US08815992B2
公开(公告)日：2014-08-26
申请号：US13085905
申请日：2011-04-13
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
IPC分类号： A61L15/62 , C08K5/12 , C07C69/34 , C07C69/74 , C08K5/11
CPC分类号： C07C69/34 , C07C69/74 , C07C2601/08 , C08K5/11 , C08K5/12
摘要： Tetraesters of a C4-C5 aliphatic tetracarboxylic acid and OXO-alcohols and plasticized compositions containing said tetraesters are provided.
摘要翻译：提供C4-C5脂族四羧酸和OXO-醇的四酯和含有所述四酯的增塑组合物。

9. 发明授权

US06320083B1 Process for making aromatic aldehydes using ionic liquids 失效
标题翻译：使用离子液体制备芳香族醛的方法
公开(公告)号：US06320083B1
公开(公告)日：2001-11-20
申请号：US09393651
申请日：1999-09-10
申请人： Ramzi Yanni Saleh
发明人： Ramzi Yanni Saleh
IPC分类号： C07C4500
CPC分类号： C07C47/542 , C07C7/14858 , C07C45/49 , C07C45/82 , C07C51/235 , C07C51/265 , C07C63/16 , C07C63/26 , C07C63/307 , C07C15/08
摘要： A process for the carbonylation of alkyl aromatic compounds uses acidic ionic liquids. In one embodiment, the ionic liquid is intrinsically acidic, having an anion mole fraction of greater than 0.5. The ionic liquids include those comprised of a quaternary nitrogen-containing cation and a metal halide anion. The process provides for good conversion and selectivity in the production of the corresponding aromatic aldehyde compound.
摘要翻译：烷基芳族化合物的羰基化方法使用酸性离子液体。在一个实施方案中，离子液体本征酸性，阴离子摩尔分数大于0.5。离子液体包括由含季氮的阳离子和金属卤化物阴离子组成的离子液体。该方法在相应的芳族醛化合物的制备中提供良好的转化率和选择性。

10. 发明授权

US06303827B1 Process for making aromatic aldehydes 失效
标题翻译：制备芳香族醛的方法
公开(公告)号：US06303827B1
公开(公告)日：2001-10-16
申请号：US09393664
申请日：1999-09-10
申请人： Ramzi Yanni Saleh , Christopher L. Becker , Robert C. Michaelson , Richard H. Schlosberg
发明人： Ramzi Yanni Saleh , Christopher L. Becker , Robert C. Michaelson , Richard H. Schlosberg
IPC分类号： C07C4500
CPC分类号： C07C47/542 , C07C7/14858 , C07C45/49 , C07C45/82 , C07C51/235 , C07C51/265 , C07C63/16 , C07C63/26 , C07C63/307 , C07C15/08
摘要： Alkyl aromatic compounds are converted to alkyl aromatic aldehydes by a carbonylation reaction. The carbonylation catalyst can be a high boiling point carbonylation catalyst which allows for the separation of the aldehyde product by selective volatilization. Alternatively, the carbonylation catalyst can be selected from perfluoroalkyl sulfonic acids having 2 to 18 carbon atoms, perfluoroether sulfonic acids having 2 to 18 carbon atoms, BF3(ROH)x wherein R represents CH3 or H and X is a number within the range of from 0.2 to 2, GaBr3, GaCl3, TaF5, NbF5, and NbBr5, with the proviso that when the catalyst is TaF5, NbF5, or NbBr5, then the reaction takes place in the absence of added HF. Preferably, all of the carbonylation reactions take place in the absence of added HF. The alkyl aromatic aldehydes can be oxidized to form an aromatic acid. A mixed xylene feed stock can be converted to a mixture of dimethylbenzaldehydes and then oxidized to form trimellitic acid without the need to separate the xylene or dimethylbenzaldehyde isomers.
摘要翻译：烷基芳族化合物通过羰基化反应转化成烷基芳族醛。羰基化催化剂可以是高沸点羰基化催化剂，其允许通过选择性挥发来分离醛产物。或者，羰基化催化剂可以选自具有2至18个碳原子的全氟烷基磺酸，具有2至18个碳原子的全氟醚磺酸，BF 3（ROH）x其中R表示CH 3或H，X是在 0.2至2，GaBr 3，GaCl 3，TaF 5，NbF 5和NbBr 5，条件是当催化剂为TaF 5，NbF 5或NbBr 5时，则在不加入HF的情况下进行反应。优选地，所有的羰基化反应都在不加入HF的情况下进行。烷基芳族醛可被氧化形成芳族酸。混合二甲苯原料可以转化成二甲基苯甲醛的混合物，然后氧化形成偏苯三酸，而不需要分离二甲苯或二甲基苯甲醛异构体。

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