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1. 发明授权

US5630920A Electrochemical sensor for determining the oxygen concentration in gas mixtures 失效
标题翻译：用于测定气体混合物中氧浓度的电化学传感器
公开(公告)号：US5630920A
公开(公告)日：1997-05-20
申请号：US545865
申请日：1996-01-19
申请人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Frank Stanglmeier
发明人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Frank Stanglmeier
IPC分类号： G01N27/409 , G01N27/407 , G01N27/26
CPC分类号： G01N27/4071 , G01N27/4075
摘要： An electrochemical sensor for determining the oxygen concentration in gas mixtures is proposed. The sensor has a solid electrolyte (10) with oxygen ionic conductivity, which has a measuring electrode (11) that does not catalyze establishment of equilibrium of the gas mixture and is exposed to the gas mixture. The measuring electrode (11) contains platinum and bismuth. The effect of these materials is that the free oxygen contained in the gas mixture is preferentially adsorbed, without reacting with the other gas components such as CO and HC.
摘要翻译： PCT No.PCT / DE95 / 00253 Sec。 371日期1996年1月19日 102（e）日期1996年1月19日PCT提交1995年2月28日PCT公布。出版物WO95 / 25276 日期1995年9月21日提出了一种用于测定气体混合物中氧浓度的电化学传感器。传感器具有氧离子导电性的固体电解质（10），其具有不催化气体混合物平衡并暴露于气体混合物的测量电极（11）。测量电极（11）含有铂和铋。这些材料的作用是优先吸附气体混合物中所含的游离氧，而不与其他气体组分如CO和HC反应。

2. 发明授权

US5698267A Method for fabricating high-activity electrodes for exhaust gas sensors 失效
标题翻译：制造废气传感器高活性电极的方法
公开(公告)号：US5698267A
公开(公告)日：1997-12-16
申请号：US728797
申请日：1996-10-10
申请人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Frank Stanglmeier
发明人： Karl-Hermann Friese , Hans-Martin Wiedenmann , Frank Stanglmeier
IPC分类号： B22F7/00 , C04B35/486 , C04B41/52 , C04B41/89 , C23C26/00 , G01N27/407 , B05D1/18 , G01N27/406
CPC分类号： C04B41/009 , B22F7/002 , C04B35/486 , C04B41/52 , C04B41/89 , C23C26/00 , G01N27/4075 , C04B2111/00844 , Y10S264/36
摘要： A method for fabricating a high-activity cermet electrode which is applied on an exhaust gas sensor including an oxygen ion conducting solid electrolyte, which is composed of a cermet material composed of at least one catalytically active material and at least one oxygen ion conducting ceramic material, which is bonded to the solid electrolyte of the exhaust sensor by co-sintering the cermet electrode and the solid electrolyte at a temperature ranging from 1300.degree. to 1600.degree. C. to provide a porous cermet electrode, and which contains at least one further catalytically active material which is embedded in the pores of the porous cermet electrode after co-sintering, the method including bonding together an unsintered solid electrolyte which conducts oxygen ions and a cermet electrode by co-sintering at from 1300.degree. to 1600.degree. C. to provide a porous cermet electrode; and subsequently introducing at least one further catalytically active material into pores of the porous cermet electrode.
摘要翻译：一种制造高活性金属陶瓷电极的方法，其应用于包括氧离子传导固体电解质的废气传感器，所述废气传感器由由至少一种催化活性材料和至少一种氧离子导电陶瓷材料构成的金属陶瓷材料组成，其通过在1300℃至1600℃的温度下共烧烧金属陶瓷电极和固体电解质而结合到排气传感器的固体电解质，以提供多孔金属陶瓷电极，并且其至少包含一个催化剂共烧结后嵌入多孔金属陶瓷电极的孔隙中的活性物质，该方法包括在1300℃〜1600℃下共烧结而将导电氧离子的未烧结固体电解质和金属陶瓷电极结合在一起，以提供多孔金属陶瓷电极; 随后将至少一种其它催化活性材料引入多孔金属陶瓷电极的孔中。

3. 发明授权

US07361620B2 Catalytically active layer 失效
标题翻译：催化活性层
公开(公告)号：US07361620B2
公开(公告)日：2008-04-22
申请号：US10284887
申请日：2002-10-31
申请人： Hans-Martin Wiedenmann , Frank Stanglmeier , Karl-Hermann Friese
发明人： Hans-Martin Wiedenmann , Frank Stanglmeier , Karl-Hermann Friese
IPC分类号： G01N27/407
CPC分类号： B01J25/00 , B01J23/40 , G01N27/4075 , Y10T29/49002
摘要： A catalytically active layer that is used, for example, as an electrode for a solid electrolyte-based sensor element of a gas sensor for determining a gas component in a gas mixture. The catalytically active layer includes a metallic component, that includes a noble metal in the form of platinum, rhodium, and/or palladium, and additionally a base metal. At least a portion of the originally present base metal is replaced by cavities in the metallic component.
摘要翻译：一种催化活性层，其用作例如用于确定气体混合物中的气体成分的气体传感器的基于固体电解质的传感器元件的电极。催化活性层包括金属组分，其包括铂，铑和/或钯形式的贵金属，以及另外的贱金属。原来存在的贱金属的至少一部分由金属部件中的空腔代替。

4. 发明授权

US6074694A Process of applying material, in particular for the production of electrodes for exhaust gas sensors 失效
标题翻译：施加材料的方法，特别是用于生产废气传感器的电极
公开(公告)号：US6074694A
公开(公告)日：2000-06-13
申请号：US827679
申请日：1997-04-10
申请人： Karl-Hermann Friese , Siegfried Nees , Frank Stanglmeier , Hans Baumann
发明人： Karl-Hermann Friese , Siegfried Nees , Frank Stanglmeier , Hans Baumann
IPC分类号： B05D5/12 , B05B7/08 , B05B7/14 , B05B13/06 , B05B15/00 , B05D7/00 , C04B41/45 , C04B41/81 , G01N27/407 , H05K3/12 , B05D1/02 , B05D3/12
CPC分类号： B05B7/1436 , B05B13/0645 , B05B13/069 , B05B15/003 , B05B7/0807 , C04B41/4535 , C04B41/81 , G01N27/4075 , H05K3/1241
摘要： A process for applying materials to a carrier, for which the material is atomized just prior to applying it by compressed air that is supplied separately. The process is particularly suited for the application of electrically conductive material to carriers of ceramics materials.
摘要翻译：将材料施加到载体上的方法，在将载体分开供给的压缩空气施加之前，材料被雾化。该方法特别适用于将导电材料应用于陶瓷材料的载体。

5. 发明授权

US5690800A Electrochemical measuring element having a potential-free sensor element 失效
标题翻译：具有无电位传感器元件的电化学测量元件
公开(公告)号：US5690800A
公开(公告)日：1997-11-25
申请号：US687339
申请日：1996-08-01
申请人： Karl-Hermann Friese , Frank Stanglmeier
发明人： Karl-Hermann Friese , Frank Stanglmeier
IPC分类号： G01N27/409 , G01N27/407 , G01N27/26
CPC分类号： G01N27/4078 , G01N27/407
摘要： Proposed is an electrochemical measuring instrument (10) for determining the oxygen content in gas mixtures, in particular exhaust gases from combustion engines, with a sensor element (14) that is installed potential-free in a metal casing (11). The sensor element (14) has an oxygen ion conducting solid electrolyte body (23) in the shape of a tube closed on one side, with electrodes (25, 26) and connections (27, 28), and is fitted inside the casing (11) with a metal sealing ring (20). The connection (27) which runs along the outer surface of solid electrolyte body (23) is covered with an electrically insulating layer (21), at least in the area surrounding sealing ring (20). In addition, a ductile cover layer (31) that spans solid electrolyte body (23) is applied over insulating layer (21) in the area surrounding sealing ring (20), with which the sensor element (14) rests on sealing ring (20).
摘要翻译： PCT No.PCT / DE95 / 01684第 371日期：1996年8月1日 102（e）日期1996年8月1日PCT提交1995年11月28日PCT公布。 WO96 / 21147 PCT出版物日期1996年7月11日提出了一种电化学测量仪器（10），用于确定气体混合物中的氧含量，特别是来自内燃发动机的废气，其中传感器元件（14）在金属壳体（11）中无电势地安装）。传感器元件（14）具有氧气离子传导固体电解质体（23），该氧离子传导固态电解质体（23）的形状为一侧封闭，电极（25,26）和连接部分（27,28） 11）与金属密封环（20）。至少在密封环（20）周围的区域中，沿固体电解质体（23）的外表面延伸的连接部分（27）被电绝缘层（21）覆盖。此外，跨越固体电解质体（23）的延展性覆盖层（31）被施加在密封环（20）周围的区域的绝缘层（21）上，传感器元件（14）通过该密封环（20）靠在密封环）。

6. 发明授权

US09605776B2 Stopper for sealing the housing of an exhaust gas sensor, exhaust gas sensor, and manufacturing method for an exhaust gas sensor 有权
公开(公告)号：US09605776B2
公开(公告)日：2017-03-28
申请号：US14377712
申请日：2013-01-07
申请人： Frank Stanglmeier , Jens Schneider , Bernd Rattay
发明人： Frank Stanglmeier , Jens Schneider , Bernd Rattay
IPC分类号： F16L5/10 , H02G15/013 , F01N11/00 , G01N27/407 , H01R13/52
CPC分类号： F16L5/10 , F01N11/007 , G01N27/4078 , H01R13/5208 , H02G15/013 , Y10T29/49826
摘要： A stopper for sealing a housing of an exhaust gas sensor has: a base body which contains polytetrafluoroethylene; at least one through channel for leading through a connecting cable; and a seal situated, at least in places, between the base body of the stopper and the through channel, the seal containing at least one perfluoroalkoxy polymer or one tetrafluoroethylene perfluoroproylene or one polychlorotrifluoroethylene or one polyvinylidene fluoride.

7. 发明申请

US20150001813A1 PLUG FOR SEALING A HOUSING OF AN EXHAUST GAS SENSOR, EXHAUST GAS SENSOR AND MANUFACTURE OF AN EXHAUST GAS SENSOR 有权
标题翻译：用于密封排气管传感器的外壳，废气传感器和排气传感器的制造
公开(公告)号：US20150001813A1
公开(公告)日：2015-01-01
申请号：US14376936
申请日：2013-01-04
申请人： Frank Stanglmeier , Jens Schneider , Bernd Rattay
发明人： Frank Stanglmeier , Jens Schneider , Bernd Rattay
IPC分类号： H02G15/013 , B29C65/48 , F01N11/00 , F16J15/02 , B29C65/02
CPC分类号： H02G15/013 , B29C65/02 , B29C65/48 , B29K2027/12 , B29K2027/16 , B29K2027/18 , F01N11/00 , F01N2560/02 , F16J15/022 , G01N27/4078
摘要： A plug for sealing a housing of an exhaust gas sensor, the plug having at least one axial through-channel for leading through a connecting cable, the plug having a main body which includes polytetrafluoroethylene, the plug further including at least one outer seal which is situated on the plug radially on the outside, the outer seal including at least one perfluoroalkoxy polymer or tetrafluoroethylene-perfluoropropylene or polychlorotrifluoroethylene or polyvinylidene fluoride.
摘要翻译：一种用于密封废气传感器的壳体的塞子，所述塞子具有至少一个用于引导连接缆索的轴向通道，所述塞子具有包括聚四氟乙烯的主体，所述塞子还包括至少一个外部密封件，所述外部密封件是位于外壳上的径向插塞上，外部密封件包括至少一种全氟烷氧基聚合物或四氟乙烯 - 全氟丙烯或聚氯三氟乙烯或聚偏二氟乙烯。

8. 发明申请

US20140157869A1 METHOD FOR OPERATING A GAS SENSOR ELEMENT AND DEVICE FOR CARRYING OUT SAID METHOD 有权
标题翻译：用于操作气体传感器元件的方法和用于执行该方法的装置
公开(公告)号：US20140157869A1
公开(公告)日：2014-06-12
申请号：US14111525
申请日：2012-02-17
申请人： Jens Schneider , Helge Schichlein , Frank Stanglmeier , Lothar Diehl , Eckart Reihlen
发明人： Jens Schneider , Helge Schichlein , Frank Stanglmeier , Lothar Diehl , Eckart Reihlen
IPC分类号： G01M15/10
CPC分类号： G01M15/102 , F01N11/00 , G01N33/007
摘要： A method for operating at least one sensor element for detecting at least one property of a gas in a measured-gas space is described. The method comprises at least the following steps: at least one first step, in the first step at least one parameter being ascertained; at least one second step, in the second step the parameter being compared with at least one comparison value, in accordance with that comparison at least one feature being allocated to the sensor element or to at least one part of the sensor element. An apparatus for carrying out the method is also described.
摘要翻译：描述了用于操作至少一个用于检测测量气体空间中的气体的特性的传感器元件的方法。该方法至少包括以下步骤：至少一个第一步骤，在第一步骤中确定至少一个参数; 至少一个第二步骤，在第二步骤中，将参数与至少一个比较值进行比较，根据该比较，将至少一个特征分配给传感器元件或传感器元件的至少一部分。还描述了用于执行该方法的装置。

9. 发明授权

US09234869B2 Data storing exhaust gas probe 有权
标题翻译：数据存储排气探头
公开(公告)号：US09234869B2
公开(公告)日：2016-01-12
申请号：US13395563
申请日：2010-07-27
申请人： Jens Schneider , Frank Stanglmeier , Marc Rosenland , Lothar Diehl
发明人： Jens Schneider , Frank Stanglmeier , Marc Rosenland , Lothar Diehl
IPC分类号： G01M15/10 , G01N27/406 , G01N27/407
CPC分类号： G01N27/4065 , F02D41/1444 , F02D41/1454 , F02D41/1494 , F02D41/2435 , F02D41/2451 , G01N27/4062 , G01N27/407 , G01N27/4175
摘要： The invention relates to an exhaust gas probe (120) for measuring properties of the exhaust gas of internal combustion engines, wherein at least one data storage unit (135) is arranged in a circuit associated with the probe, in particular arranged in a probe plug (130) or a connecting element associated therewith. The following properties and/or adaption functions characterizing the probe (120) are stored or storable in said data storage unit: —fluctuations of heating resistances that are due to the production process and/or—parameters that characterize the aging of the probe (120), and/or—the shut-off state, in particular data that characterize the execution of an interval measurement for regenerating the exhaust gas probe or of a delayed shut-off and/or—data for adapting the probe (120) to different control devices (140) of internal combustion engines and/or—the number of operating hours of the probe and/or—the operating parameters of the probe in a previous specifiable time period.
摘要翻译：本发明涉及一种用于测量内燃机排气性能的排气探测器（120），其中至少一个数据存储单元（135）布置在与探头相关的电路中，特别地布置在探头塞（130）或与其相关联的连接元件。表征探针（120）的以下性质和/或适应功能被存储或存储在所述数据存储单元中： - 由于生产过程导致的加热电阻的差异和/或参数，其表征探针的老化（120 ）和/或关闭状态，特别是表征用于再生排气探针的间隔测量的执行的数据或用于使探针（120）适应不同的延迟关闭和/或数据的数据内部燃烧发动机的控制装置（140）和/或 - 在先前可指定的时间段内的探针的运行时间和/或探针的操作参数。

10. 发明授权

US06953620B2 Coating system and method for its manufacture and its use 失效
标题翻译：涂料体系及其制造方法及其应用
公开(公告)号：US06953620B2
公开(公告)日：2005-10-11
申请号：US09908413
申请日：2001-07-18
申请人： Jens Stefan Schneider , Frank Stanglmeier , Bernd Schumann
发明人： Jens Stefan Schneider , Frank Stanglmeier , Bernd Schumann
IPC分类号： G01N27/409 , C04B41/52 , C04B41/89 , C04B41/90 , G01N27/407 , B23B3/26
CPC分类号： C04B41/009 , C04B41/52 , C04B41/89 , C04B2111/94 , G01N27/4071 , Y10T428/12472 , Y10T428/12611 , Y10T428/12618 , Y10T428/12875 , Y10T428/12889 , Y10T428/12896 , Y10T428/131 , Y10T428/249953 , C04B41/5098 , C04B41/5122 , C04B40/0021 , C04B41/4515 , C04B41/4564 , C04B41/51 , C04B41/4541 , C04B41/522 , C04B41/4582 , C04B35/00
摘要： A coating system and a method for its manufacture are provided. An electrically conductive base coat and a porous overcoat lying over the base coat are arranged on a ceramic substrate. At least one additional deposited layer is arranged on the base coat in such a way that the additional layer is formed in the pores of the porous overcoat adjacent to the base coat. The additional layer is deposited either by currentless or electrolytic deposition. For electrolytic deposition of the additional layer, the ceramic substrate sintered with the base coat and the overcoat is submerged in an electrolytic bath and the base coat is connected as a cathode. The currentless deposition takes place from a solution of the metal to be deposited with the addition of a reducing agent.
摘要翻译：提供涂料体系及其制造方法。位于基底涂层上的导电底涂层和多孔外涂层布置在陶瓷基板上。至少一个另外的沉积层布置在底涂层上，使得附加层形成在邻近底涂层的多孔外涂层的孔中。附加层通过无电流或电沉积沉积。对于附加层的电解沉积，将用基底涂层和外涂层烧结的陶瓷基板浸没在电解浴中，底涂层作为阴极连接。通过添加还原剂，从待沉积金属的溶液中发生无电流沉积。

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