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1. 发明授权

US4965019A Use of selected end-group closed fatty alcohol ethoxylates for low-foam, cold-sprayable cleaning agents 失效
标题翻译：使用选择的端基封闭脂肪醇乙氧基化物用于低泡沫，可冷喷涂的清洁剂
公开(公告)号：US4965019A
公开(公告)日：1990-10-23
申请号：US295334
申请日：1989-01-10
申请人： Karl-Heinz Schmid , Alfred Meffert , Gilbert Schenker , Adolf Asbeck , Juergen Geke
发明人： Karl-Heinz Schmid , Alfred Meffert , Gilbert Schenker , Adolf Asbeck , Juergen Geke
IPC分类号： C11D3/20 , C11D1/72 , C11D3/00
CPC分类号： C11D3/0026 , C11D1/721
摘要： Foam-depressing additives comprising polyethyleneglycol ethers of formula IR.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2 (I)in which R.sup.1 represents a straight-chain or branched alkyl radical with 6 to 13 carbon atoms, R.sup.2 represents an alkyl radical with 1 to 3 carbon atoms and n is a number from 2 to 6, for low-foam, preferably sprayable cleaning agents.
摘要翻译：包含式I的聚乙二醇醚的泡沫抑制添加剂R1-O-（CH2CH2O）n-R2（Ⅰ）其中R1代表具有6至13个碳原子的直链或支链烷基，R2代表具有1至 3个碳原子，n为2至6的数，对于低泡沫，优选可喷雾的清洁剂。

2. 发明授权

US4973423A Foam-inhibiting additives in low-foam cleaning compositions: polyethylene glycol ethers 失效
标题翻译：低泡沫清洁组合物中的泡沫抑制添加剂：聚乙二醇醚
公开(公告)号：US4973423A
公开(公告)日：1990-11-27
申请号：US233649
申请日：1988-08-17
申请人： Juergen Geke , Erich Boebers , Gilbert Schenker , Robert Piorr , Karl-Heinz Schmid
发明人： Juergen Geke , Erich Boebers , Gilbert Schenker , Robert Piorr , Karl-Heinz Schmid
IPC分类号： B01D19/04 , C11D1/72 , C11D3/00 , C11D3/20
CPC分类号： C11D3/0026 , C11D1/721
摘要： Short-chain polyethlene glycol ethers corresponding to the formula:R.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2wherein:R.sup.1 is a linear or branched C.sub.6 -C.sub.18 alkyl or alkenyl radical,R.sup.2 is a C.sub.4 -C.sub.8 alkyl radical, andN is an integer of from 2 to 6,are used as foam-inhibiting additives for low-foam cleaning compositions.
摘要翻译：对应于下式的短链聚乙二醇醚：R1-O-（CH2CH2O）n-R2其中：R1是直链或支链C6-C18烷基或烯基，R2是C4-C8烷基，N是 2至6的整数被用作低泡沫清洁组合物的泡沫抑制添加剂。

3. 发明授权

US4937011A Detergent compositions containing active chlorine and ketone foam inhibitors 失效
标题翻译：含有活性氯和酮泡沫抑制剂的洗涤剂组合物
公开(公告)号：US4937011A
公开(公告)日：1990-06-26
申请号：US295880
申请日：1989-01-11
申请人： Karl-Heinz Schmid , Adolf Asbeck , Christoph Breucker , Bernhard Gutsche , Alfred Meffert , Horst Rutzen
发明人： Karl-Heinz Schmid , Adolf Asbeck , Christoph Breucker , Bernhard Gutsche , Alfred Meffert , Horst Rutzen
IPC分类号： B01D19/04 , C11D3/20 , C11D3/395
CPC分类号： C11D3/0026 , C11D3/2072 , C11D3/395
摘要： Alkaline dishwashing machine detergent compositions containing an active chlorine composition and a foam inhibiting amount of a ketone containing at least 25 carbon atoms. A process for their preparation wherein the ketone is introduced into the composition as a dispersion in a liquid.
摘要翻译：含有活性氯组合物和泡沫抑制量的含有至少25个碳原子的酮的碱性餐具洗涤机洗涤剂组合物。其制备方法，其中酮作为液体中的分散体引入组合物中。

4. 发明授权

US4981893A Foam inhibitors for polymer dispersions 失效
标题翻译：用于聚合物分散体的泡沫抑制剂
公开(公告)号：US4981893A
公开(公告)日：1991-01-01
申请号：US136237
申请日：1987-12-21
申请人： Rainer Hoefer , Karl-Heinz Schmid , Adolf Asbeck , Uwe Held
发明人： Rainer Hoefer , Karl-Heinz Schmid , Adolf Asbeck , Uwe Held
IPC分类号： B01J13/00 , B01D19/04 , B01F17/42 , C08F2/30
CPC分类号： C08F2/30 , B01D19/0404
摘要： Compounds corresponding to the following formulaR.sub.1 --(CH.sub.2).sub.m --O--(CH.sub.2 CH.sub.2).sub.n --R.sub.2in which R.sub.1 is the phenyl radical or a phenyl radical which is substituted by linear or branched alkyl radicals containing a total of from 1 to 18 carbon atoms, R.sub.2 is a C.sub.4 -C.sub.8 alkyl radical, m=0 or 1 and n=3 to 30, are used as dispersants with foam-inhibiting properties in aqueous polymer dispersions and latices.
摘要翻译：对应于下式R1-（CH2）mO-（CH2CH2）n-R2的化合物，其中R 1是苯基或被含有总共1至18个碳原子的直链或支链烷基取代的苯基， R2是C4-C8烷基，m = 0或1，n = 3〜30，在聚合物水分散体和胶乳中用作具有泡沫抑制性质的分散剂。

5. 发明授权

US4780237A Low foam surfactant mixtures 失效
标题翻译：低泡沫表面活性剂混合物
公开(公告)号：US4780237A
公开(公告)日：1988-10-25
申请号：US77257
申请日：1987-07-24
申请人： Karl-Heinz Schmid , Adolf Asbeck , Detlev Stanislowski
发明人： Karl-Heinz Schmid , Adolf Asbeck , Detlev Stanislowski
IPC分类号： B01F17/42 , C11D1/72 , C11D1/722 , C11D1/825 , C11D3/00
CPC分类号： C11D1/8255 , C11D1/721 , C11D3/0026 , C11D1/72 , C11D1/722
摘要： Low-foam or foam-depressing surfactant mixtures based on water-soluble and/or water-emulsifiable polyalkylene glycol ethers of relatively long-chain alcohols containing components I, II and, if desired, III in the quantities indicated:(I) from 20 to 80% by weight of polyethylene glycol ethers corresponding to the following general formulaR.sub.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sub.2 (I) in which R.sub.1 is a straight-chain or branched C.sub.8 -C.sub.18 alkyl or alkenyl radical, R.sub.2 is a C.sub.4 -C.sub.8 alkyl radical and n is a number of from 3 to 7,(II) from 10 to 40% by weight of alkyl polyalkylene glycol mixed ethers corresponding to the following general formula ##STR1## in which R.sub.3 is a straight-chain or branched C.sub.8 -C.sub.18 alkyl radical, x is a number of from 1 to 3 and y is a number of from 3 to 6, and(III) from 0 to 40% by weight of alkyl (poly)propylene glycol ethers corresponding to the following general formula ##STR2## in which R.sub.4 is a straight-chain or branched C.sub.16 -C.sub.22 alkyl or alkenyl radical and z is a number of from 1 to 3.
摘要翻译：基于水溶性和/或水可乳化的相对长链醇的聚亚烷基二醇醚的低泡沫或泡沫抑制表面活性剂混合物，其含有组分I，II，如果需要，III为所示量：（I）为20 至80重量％的对应于以下通式的R 1 -O-（CH 2 CH 2 O）n -R 2（I）的聚乙二醇醚，其中R 1是直链或支链C 8 -C 18烷基或烯基，R 2是C 4 -C8烷基，n为3至7，（II）10至40重量％的烷基聚亚烷基二醇混合醚，其对应于下列通式（II），其中R 3为直链 - 链或支链C 8 -C 18烷基，x是1至3的数，y是3至6的数，和（III）0至40重量％的对应于其中R 4是直链或支链C 16 -C 22烷基或链烯基的以下通式（Ⅰa）（Ⅲ），z是多个 m 1〜3。

6. 发明授权

US4853145A Alkyl and alkenyl diethanolamine compounds as solubilizers for low-foam surfactants 失效
标题翻译：烷基和烯基二乙醇胺化合物作为低泡表面活性剂的增溶剂
公开(公告)号：US4853145A
公开(公告)日：1989-08-01
申请号：US136048
申请日：1987-12-21
申请人： Karl-Heinz Schmid , Adolf Asbeck , Detlev Stanislowski
发明人： Karl-Heinz Schmid , Adolf Asbeck , Detlev Stanislowski
IPC分类号： B01F17/38 , B01F17/16 , B01F17/42 , B01F17/46 , C11D1/42 , C11D1/835 , C11D3/30 , C11D17/08
CPC分类号： C11D3/0026 , C11D1/42 , C11D1/835
摘要： Aqueous low-foam cleaning compositions containing at least one surfactant which is a water-soluble or water-emulsifiable polyalkylene glycol ether of a long-chain alcohol, and at least one diethanolamine derivative of the formula ##STR1## in which R.sub.1 and R.sub.2 are linear or branched alkyl or alkenyl radicals containing 8 to 14 carbon atoms for R.sub.1 and 9 to 17 carbon atoms for R.sub.2, andr, s, t, u, v and w are integers of from 1 to 3.
摘要翻译：含有至少一种作为长链醇的水溶性或水可乳化的聚亚烷基二醇醚的表面活性剂的水性低泡沫清洗组合物和至少一种下式的二乙醇胺衍生物（Ⅰ）（IIa）（IIb）其中R 1和R 2为R 2为碳原子数为8〜14，碳原子数为9〜17的直链或支链烷基或烯基，r，s，t，u，v，w 是从1到3的整数。

7. 发明授权

US4745231A Alkylene oxide block polymers usable as defoamers 失效
标题翻译：可用作消泡剂的环氧烷嵌段聚合物
公开(公告)号：US4745231A
公开(公告)日：1988-05-17
申请号：US893756
申请日：1986-08-06
申请人： Fritz Lange , Rainer Hoefer , Karl-Heinz Schmid , Adolf Asbeck , Klaus Herrmann
发明人： Fritz Lange , Rainer Hoefer , Karl-Heinz Schmid , Adolf Asbeck , Klaus Herrmann
IPC分类号： B01D19/04 , C08G65/26 , C08G65/28 , C08G65/32 , C08G65/34 , C11D3/37 , C07C43/11
CPC分类号： B01D19/04 , B01D19/0404 , C08G65/2609 , C11D3/0026 , C11D3/3707 , Y10S516/92
摘要： Block polymers usable as defoamers have the following formula ##STR1## in which R represents a glycerol or polyglycerol function having a degree of polymerization x of from 1 to 6 and the indices y is equal to (x-z+2), z is equal to (x-y+2), a is equal to 1 to 15, b is equal to 50 to 200 c is equal to 1 to 15, d is equal to 20 to 150 and e is equal to 1 to 15, with the proviso that the sums (a+c+e) is equal to 2 to 20, (b+d) is equal to 50 to 250 and (c+e) is equal to 1 to 15, and y has a value of at least 1.The block polymers are prepared by reaction of glycerol or polyglycerol having a degree of polymerization x with ethylene oxide, then with propylene oxide and, finally, again with ethylene oxide, preferably in the presence of alkaline etherification catalysts.
摘要翻译：可用作消泡剂的嵌段聚合物具有下式（IMAGE），其中R表示聚合度x为1至6且指数y等于（x-z + 2）的甘油或聚甘油官能团，z等于至（x-y + 2），a等于1至15，b等于50至200c等于1至15，d等于20至150，e等于1至15，其中条件是（a + c + e）之和等于2至20，（b + d）等于50至250，（c + e）等于1至15，y至少为嵌段聚合物通过具有聚合度x与环氧乙烷然后与环氧丙烷的甘油或聚甘油反应制备，最后再次与环氧乙烷反应，优选在碱性醚化催化剂的存在下进行。

8. 发明授权

US5921910A Polyglycol ether mixtures as foam inhibitors 失效
标题翻译：聚乙二醇醚混合物作为泡沫抑制剂
公开(公告)号：US5921910A
公开(公告)日：1999-07-13
申请号：US835913
申请日：1992-02-26
申请人： Karl-Heinz Schmid , Gilbert Schenker
发明人： Karl-Heinz Schmid , Gilbert Schenker
IPC分类号： C11D1/72 , C11D1/825 , C11D3/00 , B01D19/04 , C11D7/08
CPC分类号： C11D3/0026 , C11D1/721 , C11D1/825
摘要： A process for suppressing the foaming properties of a cleaning product by adding to the cleaning product a foam-suppressing additive consisting of polyethylene glycol ethers corresponding to formula IR.sub.1 O--(CH.sub.2 CH.sub.2 O).sub.n --R.sub.2 (I)wherein R.sub.1 is a long-chain branched alkyl or alkenyl radical, R.sub.2 is an alkyl radical containing 4 to 8 carbon atoms and n is a number from 4 to 9, and wherein the radical R.sub.1 O is derived from an alcohol mixture consisting of at least 45 mol percent of an equimolar isomer mixture of 2-hexyl-1-dodecanol and 2-octyl-1-decanol and 0 to 55 mol percent of 2-hexyl-1-decanol.
摘要翻译： PCT No.PCT / EP90 / 01380 Sec。 371日期：1992年2月26日 102（e）日期1992年2月26日PCT提交1990年8月21日PCT公布。出版物WO91 / 03537 1991年3月21日1991日本公开了一种抑制清洗剂发泡性能的方法，该方法是向清洗剂中添加由对应于式IR1O-（CH2CH2O）n-R2（Ⅰ）的聚乙二醇醚组成的泡沫抑制添加剂，其中R1为长链支链烷基或烯基，R2是含有4至8个碳原子的烷基，n是4至9的数，并且其中基团R1O衍生自由以下物质组成的醇混合物：至少45摩尔％ 2-己基-1-十二烷醇和2-辛基-1-癸醇和0-55mol％2-己基-1-癸醇的等摩尔异构体混合物。

9. 发明授权

US5057247A High-viscosity, neutral polyol esters 失效
标题翻译：高粘度，中性多糖酯
公开(公告)号：US5057247A
公开(公告)日：1991-10-15
申请号：US136037
申请日：1987-12-21
申请人： Karl-Heinz Schmid , Uwe Ploog , Alfred Meffert
发明人： Karl-Heinz Schmid , Uwe Ploog , Alfred Meffert
IPC分类号： C07C69/33 , C07C69/34 , C10M105/38 , C10M105/40 , C10M105/42 , C10M129/74 , C10N40/04 , C10N50/10
CPC分类号： C10M105/42 , C10M105/38 , C10M105/40 , C10M2203/10 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10N2240/02 , C10N2240/08
摘要： Synthetic polyol esters with lubricating oil properties based on substantially neutral esterification products of a polyhydric alcohol with selected monocarboxylic acids and, optionally, polybasic carboxylic acids, wherein the polyfunctional alcohol component is dipentaerythritol which is esterified withI--branched C.sub.8 -C.sub.16 fatty acids (class A acids) or withII--mixtures of linear C.sub.8 -C.sub.14 fatty acids (class B acids) with branched fatty acids of class Aand, optionally, limited quantities of polybasic carboxylic acids of the following classes C, D and/or E incorporated in the polyester molecular by condensation:class C acids: di- and/or tricarboxylic acids in the range from C.sub.6 to C.sub.54class D acids: difunctional fatty acids which have been obtained by addition of acrylic acid onto the double bonds of oleic acid, linoleic acid and/or linolenic acidclass E acids: aromatic and/or paraffinic, cyclic polycarboxylic acids containing from 2 to 6 acid functions.
摘要翻译：具有润滑油性能的合成多元醇酯基于多元醇与选择的一元羧酸和任选的多元羧酸的基本上中性的酯化产物，其中多官能醇组分是用I支链C8-C16脂肪酸酯化的二季戊四醇（类一种酸）或与线性C8-C14脂肪酸（B类酸）与A类支链脂肪酸的II-混合物，以及任选的有限量的下列C类，D和/或E类中的多元羧酸聚酯分子通过缩合：C类酸：C6至C54范围内的二羧酸和/或三羧酸D类：通过将丙烯酸加入到油酸，亚油酸双键上获得的双官能脂肪酸和/或亚麻酸类E酸：含有2至6个酸官能团的芳族和/或链烷烃，环状多元羧酸。

10. 发明授权

US5276204A Fatty alcohol mixtures and ethoxylates thereof showing improved low-temperature behavior 失效
标题翻译：脂肪醇混合物和其乙氧基化物显示改善的低温行为
公开(公告)号：US5276204A
公开(公告)日：1994-01-04
申请号：US965551
申请日：1992-10-23
申请人： Karl-Heinz Schmid , Hans Peter Kubersky , Guenter Demmering , Alfred Meffert
发明人： Karl-Heinz Schmid , Hans Peter Kubersky , Guenter Demmering , Alfred Meffert
IPC分类号： C07C29/149 , C07C43/178 , C11D1/72 , C07C43/11 , C07C43/15
CPC分类号： C07C43/178 , C07C29/149 , C11D1/72 , Y10S516/01
摘要： Fatty alcohol mixtures R.sub.mix --OH of natural and, in particular, purely vegetable origin and ethoxylates thereof showing improved low-temperature behavior and corresponding to the general formula R.sub.mix --O--(CH.sub.2 CH.sub.2 O).sub.x --H, in which x is a number of 2 to 10 and R.sub.mix represents selected mixtures of saturated and olefinically unsaturated fatty alcohol hydrocarbon radicals in the C 6-20 or C 12-20 ranges correspond to specification I for the chain length range R.sub.mix --=6-20 and to specification II for the chain length range R.sub.mix --=C 12-20:______________________________________ Specification I II structurally analogous to % by weight ______________________________________ C 6 caproic acid 0.1-0.6 -- C 8 caprylic acid 2.5-10 -- C 10 capric acid 2.5-14 -- C 12 lauric acid 37-52 39-69 C 14 myristic acid 10-20 10-27 C 16 palmitic acid 6-10 6-14 C 18 stearic acid 1-5 1-7 C 18' oleic acid 5-23 6-31 C 18" linoleic acid 1-4 1-6 C 18"' linolenic acid 0.1-1 0.1-2 C 20 arachic acid 0.1-1 0.1-2 ______________________________________
摘要翻译：天然的，特别是纯植物来源的脂肪醇混合物Rmix-OH，其乙氧基化物显示出改进的低温行为，并且对应于通式Rmix-O-（CH2CH2O）xH，其中x为2至10的数 Rmix表示C 6-20或C 12-20范围内饱和和烯属不饱和脂肪醇烃基的选定混合物，对应于链长范围Rmix- = 6-20的规范I，链长范围为规范II Rmix- = C 12-20：-21规格30-21 I25 II-8结构类似于21重量％30 C 6己酸0.1-0.6 C 8辛酸2.5-10 C 10癸酸2.5-14 - -C 12月桂酸37-5239-69-C 14肉豆蔻酸10-2010-27-C 16棕榈酸6-10 6-14-C 18硬脂酸-51-7-C 18油酸5-23 6-31-C 18“ 亚油酸1-41-6-C 18“'亚麻酸0.1-1 0.1-2 -C 20arachic acid 0.1-1 0.1-2 -

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