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    • 8. 发明授权
    • Mixtures of thermoplastic polymers in powder form
    • 粉末形式的热塑性聚合物的混合物
    • US5112910A
    • 1992-05-12
    • US743678
    • 1991-08-12
    • Karl-Erwin PiejkoChristian LindnerRalph OstarekHans-Eberhard BraeseKarl-Heinz Ott
    • Karl-Erwin PiejkoChristian LindnerRalph OstarekHans-Eberhard BraeseKarl-Heinz Ott
    • C08J3/00C08L21/00C08L25/12C08L33/06C08L33/12C08L51/04
    • C08L33/06C08J3/005C08L21/00C08L25/12C08L33/12C08L51/04
    • Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.
    • 制备粉末形式的热塑性聚合物的混合物的方法,该方法由以下混合物的水性乳液制备:a)丙烯酸C 2 -C 8烷基酯和/或丁二烯与(基于共聚物)的至少40重量%的颗粒部分交联的橡胶状共聚物。 丙烯腈,苯乙烯或甲基丙烯酸C 1 -C 4烷基酯,b)热塑性树脂,如果合适,c)在二烯或烷基上的苯乙烯,α-甲基苯乙烯,丙烯腈,甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物 丙烯酸酯橡胶,其橡胶含量为50〜95重量% %,其中a)和b)和如果合适的水性乳液c)具有15至50重量%的聚合物含量。 %与凝固溶液同时混合,但在单独的流中,在20℃至100℃连续或半连续,聚合物a)和b),如果合适,c)凝结,将流合并,聚合物 混合物然后分离出来。