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    • 4. 发明授权
    • Organic nickel compounds, production and use thereof as catalysts in the
polymerization of olefins
    • 有机镍化合物,其在烯烃聚合中的生产和用途作为催化剂
    • US4620021A
    • 1986-10-28
    • US654227
    • 1984-09-25
    • Karl-Heinz A. O. StarzewskiJosef WitteHerbert Bartl
    • Karl-Heinz A. O. StarzewskiJosef WitteHerbert Bartl
    • C08L67/00C07F15/04C08F4/26C08F4/60C08F4/80C08F10/00C08J3/24C08L69/00
    • C07F15/04C08F10/00
    • Olefins such as ethylene can be polymerized with a catalyst which comprises nickel compounds obtained by reacting a nickel-(O) compound or a nickel compound which may be converted in situ into a nickel-(O) compound with an adduct or a mixture of a quinoid compound and a tertiary phosphine and with a compound corresponding to the following general formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.6 -C.sub.12 aryl or C.sub.3 -C.sub.8 cycloalkyl optionally substituted by halogen, hydroxy, C.sub.1 -C.sub.20 alkoxy, nitro or C.sub.6 -C.sub.12 aryloxy; also C.sub.6 -C.sub.12 aryl-C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.12 aryl-C.sub.2 -C.sub.20 alkenyl, C.sub.1 -C.sub.20 alkyl-C.sub.6 -C.sub.12 aryl, C.sub.1 -C.sub.20 alkyl-C.sub.3 -C.sub.8 cycloalkyl and C.sub.6 -C.sub.12 aryl-C.sub.3 -C.sub.8 cycloalkyl, di-C.sub.1 -C.sub.4 alkylamino, optionally substituted phenoxy or alkoxy; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen, silyl, halogen, cyano or R.sup.1 andX represents O, NR.sub.4 or ##STR2##
    • 烯烃如乙烯可以与催化剂聚合,所述催化剂包括通过使镍 - (O)化合物或镍化合物原位转化成镍 - (O)化合物而获得的镍化合物与加合物或其混合物 喹啉化合物和叔膦,并具有对应于下列通式的化合物:其中R 1,R 2和R 3独立地表示C 1 -C 20烷基,C 2 -C 20烯基,C 6 -C 12芳基或C 3 -C 8环烷基 任选被卤素,羟基,C 1 -C 20烷氧基,硝基或C 6 -C 12芳氧基取代; 还有C 6 -C 12芳基-C 1 -C 20烷基,C 6 -C 12芳基-C 2 -C 20烯基,C 1 -C 20烷基-C 6 -C 12芳基,C 1 -C 20烷基-C 3 -C 8环烷基和C 6 -C 12芳基-C 3 -C 8环烷基 ,二-C 1 -C 4烷基氨基,任选取代的苯氧基或烷氧基; R4,R5和R6表示氢,甲硅烷基,卤素,氰基或R1,X表示O,NR4或