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    • 5. 发明授权
    • Nonaqueous polyisocyanate formulation
    • 非水多异氰酸酯制剂
    • US5387367A
    • 1995-02-07
    • US206893
    • 1994-03-07
    • Karl HaeberleLothar MaempelUlrich Filges
    • Karl HaeberleLothar MaempelUlrich Filges
    • C08G18/28C08G18/48C08G18/70C08G18/78C08G18/79C09J175/00C08G18/30C09K3/00
    • C08G18/7818C08G18/283C08G18/4833C08G18/70C08G18/706C08G18/792C09J175/00C08G2170/80
    • Nonaqueous polyisocyanate formulation containinga) one or more aliphatic polyisocyanates having a mean NCO functionality of from 2.5 to 3.5 andb) an amount, which ensures that the polyisocyanate is dispersible, of a reaction product of a diisocyanate selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, dodecamethylene diisocyanate, 1,4-diisocyanatocyclohexane, 4,4'-di-(isocyanatocyclohexyl)-methane, diisocyanatotrimethylhexane, diisocyanatotetramethylhexane, 1-isocyanato-3,3,5-trimethyl-5-(isocyanatomethyl)-cyclohexane, toluylene 2,4- and 2,6-diisocyanate, tetramethylxylylene diisocyanate, p-xylylene diisocyanate, 2,4'- and 4,4'-diisocyanatodiphenylmethane and a mixture of two or more of these diisocyanates with a monohydric or polyhydric polyalkylene ether alcohol where the alkylene groups are of 2 to 4 carbon atoms and which contains a polyether chain having 8 or more ethylene oxide units,are prepared and are used in aqueous coating materials and in adhesive dispersions.
    • 含有a)一种或多种平均NCO官能度为2.5至3.5的脂族多异氰酸酯和b)确保多异氰酸酯可分散的量的二异氰酸酯选自四亚甲基二异氰酸酯 ,六亚甲基二异氰酸酯,十二亚甲基二异氰酸酯,1,4-二异氰酸根合环己烷,4,4'-二(异氰酸根合环己基)甲烷,二异氰酸根合三甲基己烷,二异氰酸根合四甲基己烷,1-异氰酸酯基-3,3,5-三甲基-5-(异氰酸甲酯基) 对甲苯基2,4-和2,6-二异氰酸酯,四甲基亚二甲苯基二异氰酸酯,对亚二甲苯基二异氰酸酯,2,4'-和4,4'-二异氰酸二苯基甲烷以及这些二异氰酸酯中的两种或更多种与一元或多元聚亚烷基醚醇 其中亚烷基为2至4个碳原子并且含有具有8个或更多个环氧乙烷单元的聚醚链,并且用于水性涂料材料 als和粘合剂分散体。
    • 6. 发明授权
    • Copolymerizable oxime ethers and copolymers containing them
    • 可共聚的肟醚和含有它们的共聚物
    • US5514762A
    • 1996-05-07
    • US325091
    • 1994-10-17
    • Kaspar BottGerhard BauerKarl Haeberle
    • Kaspar BottGerhard BauerKarl Haeberle
    • C07C271/18C07C271/64C08F20/60C08F226/02
    • C08F20/60C07C271/64
    • Copolymerizable oxime ethers of the general formula ##STR1## where A is a divalent linking member, R.sup.1 and R.sup.2 independently of one another are each C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy, C.sub.5 -C.sub.10 -cycloalkyl or C.sub.5 -C.sub.10 -aryl, each of which may furthermore contain 1-3 nonadjacent nitrogen, oxygen or sulfur atoms as heteroatoms in the carbon chain or in the carbon ring and may be substituted by from one to three C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy groups, R.sup.1 or R.sup.2 may be hydrogen or R.sup.1 and R.sup.2 together form a bridge of 3 to 14 carbon atoms, where some of the carbon atoms may furthermore be part of an aromatic ring, Z is an n-valent organic radical which contains a copolymerizable ethylenically unsaturated group and n is an integer of from 1 to 3.
    • 其中A是二价连接构件的可共聚的肟醚,其中R 1和R 2彼此独立地是C 1 -C 10 - 烷基,C 1 -C 10 - 烷氧基,C 5 -C 10 - 环烷基或C 5 -C 10 - 芳基 ,其中每一个还可以含有1-3个不相邻的氮,氧或硫原子作为碳链或碳环中的杂原子,并且可以被一至三个C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代, R 1或R 2可以是氢或R 1和R 2一起形成3至14个碳原子的桥,其中一些碳原子还可以是芳环的一部分,Z是含有可共聚烯属不饱和基团的n价有机基团 基团,n为1〜3的整数。
    • 8. 发明授权
    • Copolymerizable oxime ethers
    • 可共聚肟醚
    • US5393904A
    • 1995-02-28
    • US202215
    • 1994-02-25
    • Kaspar BottGerhard BauerKarl Haeberle
    • Kaspar BottGerhard BauerKarl Haeberle
    • C07C271/18C07C271/64C08F20/60C07C271/08
    • C08F20/60C07C271/64
    • Copolymerizable oxime ethers of the general formula ##STR1## where A is a divalent linking member, R.sup.1 and R.sup.2 independently of one another are each C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.10 -alkoxy, C.sub.5 -C.sub.10 -cycloalkyl or C.sub.5 -C.sub.10 -aryl, each of which may furthermore contain 1-3 nonadjacent nitrogen, oxygen or sulfur atoms as heteroatoms in the carbon chain or in the carbon ring and may be substituted by from one to three C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy groups, R.sup.1 or R.sup.2 may be hydrogen or R.sup.1 and R.sup.2 together form a bridge of 3 to 14 carbon atoms, where some of the carbon atoms may furthermore be part of an aromatic ring, Z is an n-valent organic radical which contains a copolymerizable ethylenically unsaturated group and n is an integer of from 1 to 3.
    • 其中A是二价连接构件的共聚肟醚,其中R 1和R 2彼此独立地是C 1 -C 10 - 烷基,C 1 -C 10 - 烷氧基,C 5 -C 10 - 环烷基或C 5 -C 10 - 芳基,其中每一个还可以含有1-3个不相邻的氮,氧或硫原子作为碳链或碳环中的杂原子,并且可以被一至三个C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代 ,R1或R2可以是氢或R1和R2一起形成3至14个碳原子的桥,其中一些碳原子还可以是芳环的一部分,Z是含有可共聚烯属的n价有机基团 不饱和基团,n为1〜3的整数。