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1. 发明授权

US06515175B2 Mono-and polyamides of perfluoroalkyl-substituted unsaturated acids 有权
公开(公告)号：US06515175B2
公开(公告)日：2003-02-04
申请号：US09978156
申请日：2001-10-15
申请人： Karl F. Mueller , Michael Bochnik , Marlon Haniff , John Jennings , Shobha Kantamneni
发明人： Karl F. Mueller , Michael Bochnik , Marlon Haniff , John Jennings , Shobha Kantamneni
IPC分类号： C07C22930
CPC分类号： C08G18/3825 , C07C233/38 , C07C237/22
摘要： Novel perfluoroalkyl-substituted mono-, di- and poly-amide compounds which are reaction products of a mono-, di- or polyamine of 60 to 2000 molecular weight with a perfluoroalkyl substituted unsaturated acid or its corresponding lower alkyl ester and optionally a non-fluorinated amino-reactive compound such as an acid, ester, anhydride, epichlorohydrin, isocyanate or urea, are useful as internally or externally applied paper sizes to impart oil and grease resistance to paper, and as oil proofing coatings on textiles, wood, masonry and the like, or as high-performance surface active agents.

2. 发明授权

US5525732A Poly-perfluoroalkyl-substituted alcohols and acids, and derivatives thereof 失效
公开(公告)号：US5525732A
公开(公告)日：1996-06-11
申请号：US455506
申请日：1995-05-31
申请人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
发明人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
IPC分类号： C07D211/06 , C07B61/00 , C07C43/12 , C07C43/17 , C07C43/178 , C07C43/23 , C07C217/08 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C305/14 , C07C323/12 , C07C323/14 , C07F9/09 , C07F9/6574 , C08G18/32 , C08G18/38 , C08G18/67 , C08G18/73 , C08G18/75 , C09K3/18 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16 , C07C305/16
CPC分类号： C07C43/178 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C323/12 , C07F9/65742 , C08G18/3275 , C08G18/3812 , C08G18/6775 , C08G18/73 , C08G18/751 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16
摘要： Di-, tri- and poly-perfluoroalkyl-substituted alcohols and acids and derivatives thereof are described which are prepared from perfluoroalkyl iodides and di-, tri- or polyallyl alcohols or acids. These compounds contain two or more perfluoroalkyl-iodoalkyl or perfluoroalkyl-alkenyl groups and one or two alcohol or acid groups or derivatized alcohol or acid functions. They can be reacted with isocyanates, epoxy compounds, anhydrides, acids or acid derivatives to prepare a great variety of oil- and water-repellent compositions which are useful for oil- and water-repellent treatment of textiles, glass, paper, leather and other substrates.

3. 发明授权

US5491261A Poly-perfluoroalkyl-substituted alcohols and acids, and derivatives thereof 失效
标题翻译：聚全氟烷基取代的醇和酸及其衍生物
公开(公告)号：US5491261A
公开(公告)日：1996-02-13
申请号：US270083
申请日：1994-07-01
申请人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
发明人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
IPC分类号： C07D211/06 , C07B61/00 , C07C43/12 , C07C43/17 , C07C43/178 , C07C43/23 , C07C217/08 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C305/14 , C07C323/12 , C07C323/14 , C07F9/09 , C07F9/6574 , C08G18/32 , C08G18/38 , C08G18/67 , C08G18/73 , C08G18/75 , C09K3/18 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16 , C07C43/15 , C07C43/10 , C07C53/02 , C07C53/126 , C07C55/22 , C07C55/32
CPC分类号： C07C43/178 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C323/12 , C07F9/65742 , C08G18/3275 , C08G18/3812 , C08G18/6775 , C08G18/73 , C08G18/751 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16
摘要： Di-, tri- and poly-perfluoroalkyl-substituted alcohols and acids and derivatives thereof are described which are prepared from perfluoroalkyl iodides and di-, tri- or polyallyl alcohols or acids. These compounds contain two or more perfluoroalkyl-iodoalkyl or perfluoroalkyl-alkenyl groups and one or two alcohol or acid groups or derivatized alcohol or acid functions. They can be reacted with isocyanates, epoxy compounds, anhydrides, acids or acid derivatives to prepare a great variety of oil- and water-repellent compositions which are useful for oil- and water-repellent treatment of textiles, glass, paper, leather and other substrates.
摘要翻译：描述了由全氟烷基碘化物和二 - ，三 - 或多烯丙醇或酸制备的二 - ，三 - 和多 - 全氟烷基取代的醇及其酸及其衍生物。这些化合物含有两个或更多个全氟烷基 - 碘代烷基或全氟烷基 - 烯基和一个或两个醇或酸基团或衍生的醇或酸官能团。它们可以与异氰酸酯，环氧化合物，酸酐，酸或酸衍生物反应，以制备各种防憎水组合物，它们可用于纺织，玻璃，纸，皮革等的防水和防水处理底物。

4. 发明授权

US5663273A Polyurethanes derived from oligoperfluoroalkyl alcohols 失效
标题翻译：衍生自寡氟烷基醇的聚氨酯
公开(公告)号：US5663273A
公开(公告)日：1997-09-02
申请号：US456217
申请日：1995-05-31
申请人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
发明人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
IPC分类号： C07D211/06 , C07B61/00 , C07C43/12 , C07C43/17 , C07C43/178 , C07C43/23 , C07C217/08 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C305/14 , C07C323/12 , C07C323/14 , C07F9/09 , C07F9/6574 , C08G18/32 , C08G18/38 , C08G18/67 , C08G18/73 , C08G18/75 , C09K3/18 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16 , C08G18/50 , D06M13/398
CPC分类号： C07C43/178 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C323/12 , C07F9/65742 , C08G18/3275 , C08G18/3812 , C08G18/6775 , C08G18/73 , C08G18/751 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16
摘要： Di-, tri- and poly-perfluoroalkyl-substituted alcohols and acids and derivatives thereof are described which are prepared from perfluoroalkyl iodides and di-, tri- or polyallyl alcohols or acids. These compounds contain two or more perfluoroalkyl-iodoalkyl or perfluoroalkyl-alkenyl groups and one or two alcohol or acid groups or derivatized alcohol or acid functions. They can be reacted with isocyanates, epoxy compounds, anhydrides, acids or acid derivatives to prepare a great variety of oil- and water-repellent compositions which are useful for oil- and water-repellent treatment of textiles, glass, paper, leather and other substrates.
摘要翻译：描述了由全氟烷基碘化物和二 - ，三 - 或多烯丙醇或酸制备的二 - ，三 - 和多 - 全氟烷基取代的醇及其酸及其衍生物。这些化合物含有两个或更多个全氟烷基 - 碘代烷基或全氟烷基 - 烯基和一个或两个醇或酸基团或衍生的醇或酸官能团。它们可以与异氰酸酯，环氧化合物，酸酐，酸或酸衍生物反应，以制备各种防憎水组合物，它们可用于纺织，玻璃，纸，皮革等的防水和防水处理底物。

5. 发明授权

US08320585B2 Radio with dual sided audio 有权
标题翻译：收音机带双面音频
公开(公告)号：US08320585B2
公开(公告)日：2012-11-27
申请号：US11672630
申请日：2007-02-08
申请人： Deborah A. Gruenhagen , Javier Alfaro , Karl F. Mueller , David M. Yeager
发明人： Deborah A. Gruenhagen , Javier Alfaro , Karl F. Mueller , David M. Yeager
IPC分类号： H03G5/00
CPC分类号： H04R1/225 , H04R2430/01
摘要： A dual-sided radio (100) for enhancing a user's experience is provided. The radio includes a primary transducer (110) on an audio-side of the radio that projects a primary sound, a secondary transducer (120) on a data-side of the radio that projects a mid-high frequency sound, a processor (160) that equalizes (200) audio to the primary transducer and the secondary transducer, and a communication module (130) that receives and transmits communication signals containing the audio. The secondary transducer supplements the primary sound with a mid-high frequency sound (404) to compensate for mid-high frequency loss of the primary sound due to diffraction (300).
摘要翻译：提供了用于增强用户体验的双面无线电（100）。无线电装置包括在无线电的音频侧投影主声音的主要换能器（110），投射中高频声音的无线电台的数据侧的次级换能器（120），处理器（160）），其将（200）音频与所述主换能器和所述次级换能器相等，以及通信模块（130），其接收并发送包含所述音频的通信信号。辅助传感器用中高频声音（124）补充主声，以补偿由于衍射（300）导致的主要声音的中高频率损失。

6. 发明授权

US5426158A Crosslinked siloxane-urethane polymer contact lens 失效
标题翻译：交联硅氧烷 - 聚氨酯聚合物隐形眼镜
公开(公告)号：US5426158A
公开(公告)日：1995-06-20
申请号：US227481
申请日：1994-04-14
申请人： Karl F. Mueller , Paul Harisiades
发明人： Karl F. Mueller , Paul Harisiades
IPC分类号： G02C7/04 , C08G18/61 , C08L75/04 , G02B1/04 , C08F283/04
CPC分类号： C08G18/61 , G02B1/043 , C08G2270/00 , Y10S525/903
摘要： A contact lens is described which is synthesized by reaction in a mold of a isocyanate capped poly(dialkylsiloxane) prepolymer with a poly(dialkylsiloxane) di- or polyalkanol. The clear polyurethane rubber contact lens is readily made completely wettable by a transfer-grafting process or post-treatment and has a high oxygen permeability.
摘要翻译：描述了通过在异氰酸酯封端的聚（二烷基硅氧烷）预聚物的模具中与聚（二烷基硅氧烷）二 - 或聚链烷醇反应合成的隐形眼镜。透明聚氨酯橡胶隐形眼镜易于通过转移接枝方法或后处理完全润湿，并且具有高的透氧性。

7. 发明授权

US5104954A Thermostropic biphilic hydrogels and hydroplastics 失效
标题翻译：恒温双相水凝胶和水塑料
公开(公告)号：US5104954A
公开(公告)日：1992-04-14
申请号：US620223
申请日：1990-11-29
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： C08F220/18 , C08F220/54 , C09K9/02
CPC分类号： C08F220/54 , C08F220/18 , C09K9/02
摘要： Novel hydrogels and hydroplastics are described which exhibit temperature dependent, reversible phase separations and clear-opaque transitions between 1.degree. and 100.degree. C. These materials consist of linear or crosslinked random copolymers of N,N-dimethylacrylamide with alkyl- and alkoxyalkyl acrylates. The water solubility and water swelling of these polymers is extremely temperature dependent; they show sharply defined clear to opaque transitions in their water swollen state and as soluble polymers shown Lower Critical Solution Temperatures (LCST). They are useful in drug delivery systems, absorption and extraction processes and as qualitative thermometers, thermosensors and self-activating sunscreens, for example in greenhouses.
摘要翻译：描述了新的水凝胶和水塑料，其显示温度依赖性，可逆相分离和在1℃和100℃之间的透明不透明转变。这些材料由N，N-二甲基丙烯酰胺与丙烯酸烷基酯和烷氧基烷基酯的线性或交联的无规共聚物组成。这些聚合物的水溶性和水溶胀是非常温度的; 它们在其水溶胀状态下显示出清晰明确的不透明转变，并且可溶性聚合物显示出较低的临界溶液温度（LCST）。它们在药物递送系统，吸收和提取过程以及定性温度计，热敏机和自激活防晒剂中是有用的，例如在温室中。

8. 发明授权

US4954587A Dimethylacrylamide-copolymer hydrogels with high oxygen permeability 失效
标题翻译：具有高透氧性的二甲基丙烯酰胺共聚物水凝胶
公开(公告)号：US4954587A
公开(公告)日：1990-09-04
申请号：US356801
申请日：1989-05-23
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： A61L26/00 , A61L27/16 , A61L27/52 , C08F220/22 , C08F220/54 , G02B1/04
CPC分类号： C08F220/54 , A61L26/0014 , A61L26/008 , A61L27/16 , A61L27/52 , C08F220/22 , G02B1/043
摘要： This invention describes polymers which are obtained by copolymerization of 15-85 wt % N,N-dimethylacrylamide with about 15-85% of a fluorinated monomer such as perfluoroalkyl-alkylene acrylate or methacrylate with from 3 to 25 fluorine atoms and optionally, 0-50 wt % other acrylates or methacrylates and 0-20 wt %, but not more than 5 mol % of a polyvinyl functional crosslinking agent. These polymers are machinable in the dry state and form clear hydrogels with about 25-75 wt % water content and which possess oxygen-permeabilities 3-7 times higher than conventional hydrogels of similar water content. In the absence of crosslinking, the novel polymers are plasticized by water, forming clear hydroplastics with 30-70 wt % water content. The crosslinked polymers are especially useful for fabricating contact lenses for extended wear by either cutting and polishing a xerogel button, or by spin casting or direct molding in bulk or in solution.
摘要翻译：本发明描述了通过使15-85重量％的N，N-二甲基丙烯酰胺与约15-85重量％的含氟单体如全氟烷基 - 亚烷基丙烯酸酯或甲基丙烯酸酯与3-25个氟原子和任选的0- 50重量％的其它丙烯酸酯或甲基丙烯酸酯和0-20重量％，但不超过5摩尔％的聚乙烯基官能交联剂。这些聚合物可在干燥状态下加工，并形成具有约25-75％（重量）水含量的透明水凝胶，并具有相似水含量的常规水凝胶的3-7倍的透氧性。在没有交联的情况下，新型聚合物被水塑化，形成具有30-70重量％含水量的透明水塑料。交联聚合物特别适用于通过切割和抛光干凝胶按钮来制造用于延长磨损的隐形眼镜，或通过旋转浇铸或大量或溶液中的直接模塑来制造。

9. 发明授权

US4171282A Fluorinated nonionic surfactants 失效
标题翻译：氟化非离子表面活性剂
公开(公告)号：US4171282A
公开(公告)日：1979-10-16
申请号：US858218
申请日：1977-12-07
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： B01F17/38 , B23K35/36 , C08G63/688 , C08G65/332 , C08G65/334 , C08G65/338 , C08G77/382 , B01F17/36 , C07C69/40
CPC分类号： B23K35/3612 , C08G63/6884 , C08G65/332 , C08G65/3342 , C08G65/338 , C08G77/382
摘要： The perfluoroalkylthio-substituted half esters and amides of succinic acid having the formula ##STR1## wherein R.sub.f is a perfluoroalkyl, R.sup.1 alkylene optionally interrupted with oxygen, sulfur or nitrogen atom, X is oxygen or NH, y is zero or 1, Q is a polyether or polyester diradical moiety having a molecular weight of 300 to 5000 or a polysiloxane having 5 to 80 repeating units and A is hydrogen, hydroxyl, amino, alkoxy of 1 to 21 carbons, phenoxy, alkylphenoxy of 7 to 20 carbons, dialkylamino where each alkyl has 1 to 18 carbons or the group ##STR2## said compounds being prepared by first reacting maleic anhydride with a polyether, polyester, diamine or a polysiloxane derivative of an alcohol or a primary amine and then reacting the product with a perfluoroalkyl alkylene thiol. The novel compounds are useful as surfactants with specific applications as wetting agents in coatings, waxes, emulsions, paints and resins.
摘要翻译：具有式“IMAGE”的琥珀酸的全氟烷硫基取代的半酯和酰胺，其中Rf是全氟烷基，任选被氧，硫或氮原子间隔的R 1亚烷基，X是氧或NH，y是0或1，Q是分子量为300〜5000的聚醚或聚酯二元部分或具有5〜80个重复单元的聚硅氧烷，A为氢，羟基，氨基，1〜21个碳的烷氧基，苯氧基，7〜20个碳的烷基苯氧基，烷基具有1至18个碳或“IMAGE”组，所述化合物通过首先使马来酸酐与醇或伯胺的聚醚，聚酯，二胺或聚硅氧烷衍生物反应制备，然后使产物与全氟烷基亚烷基硫醇反应。新型化合物可用作具有特殊用途的表面活性剂，作为涂料，蜡，乳液，油漆和树脂中的润湿剂。

10. 发明申请

US20070297629A1 METHOD AND SYSTEM FOR EQUAL ACOUSTICS PORTING 有权
标题翻译：用于平等声学分析的方法和系统
公开(公告)号：US20070297629A1
公开(公告)日：2007-12-27
申请号：US11426780
申请日：2006-06-27
申请人： Shlomo Gelbart , Deborah A. Gruenhagen , Karl F. Mueller
发明人： Shlomo Gelbart , Deborah A. Gruenhagen , Karl F. Mueller
IPC分类号： H04R1/02 , H04R1/20
CPC分类号： H04R1/345 , H04R1/403 , H04R2499/11
摘要： A device (300) and method (600) for equal audio porting is provided. The device can include a first side with at least one first audio port (182) providing a data communication aspect, a second side with at least one second audio port (184) providing an audio communication aspect, and a transducer (110) positioned between the first side and the second side. The transducer projects sound out of the at least one first audio port and the at least one second audio port such that a quality of the sound through the at least one first audio port and the at least one second audio port are substantially the same.
摘要翻译：提供了用于相同音频端口的设备（300）和方法（600）。设备可以包括具有提供数据通信方面的至少一个第一音频端口（182）的第一侧，具有提供音频通信方面的至少一个第二音频端口（184）的第二侧和位于第一面和第二面。所述传感器从所述至少一个第一音频端口和所述至少一个第二音频端口发出声音，使得通过所述至少一个第一音频端口和所述至少一个第二音频端口的声音的质量基本相同。

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