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1. 发明申请

US20110021849A1 Process For The Preparation of Fluorinated Compounds 有权
标题翻译：氟化合物的制备方法
公开(公告)号：US20110021849A1
公开(公告)日：2011-01-27
申请号：US12842737
申请日：2010-07-23
申请人： Karine Avril , Bertrand Collier
发明人： Karine Avril , Bertrand Collier
IPC分类号： C07C21/18 , C07C17/38 , C07C17/383
CPC分类号： C07C21/18 , C07C17/25 , C07C17/354 , C07C17/383 , C07C19/08
摘要： A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene comprising the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; (iv) purification of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage; and (v) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene; and (vi) purification of the 2,3,3,3-tetrafluoro-1-propene of the preceding stage.
摘要翻译：本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法，包括以下步骤：（i）六氟丙烯的氢化，得到1,1,1,2,3， 3-六氟丙烷; （ii）前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢，得到1,2,3,3,3-五氟-1-丙烯; （iii）在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化，得到1,1,1,2,3-五氟丙烷; （iv）前一阶段获得的1,1,1,2,3-五氟丙烷的纯化; 和（v）前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢，得到2,3,3,3-四氟-1-丙烯; 和（vi）前一阶段的2,3,3,3-四氟-1-丙烯的纯化。

2. 发明授权

US08389779B2 Process for the preparation of fluorinated compounds 有权
标题翻译：氟化合物的制备方法
公开(公告)号：US08389779B2
公开(公告)日：2013-03-05
申请号：US12842737
申请日：2010-07-23
申请人： Karine Avril , Bertrand Collier
发明人： Karine Avril , Bertrand Collier
IPC分类号： C07C17/25
CPC分类号： C07C21/18 , C07C17/25 , C07C17/354 , C07C17/383 , C07C19/08
摘要： A subject-matter of the invention is a process for the preparation of 2,3,3,3-tetrafluoro-1-propene comprising the following stages: (i) hydrogenation of hexafluoropropylene to give 1,1,1,2,3,3-hexafluoropropane; (ii) dehydrofluorination of the 1,1,1,2,3,3-hexafluoropropane obtained in the preceding stage to give 1,2,3,3,3-pentafluoro-1-propene; (iii) hydrogenation of the 1,2,3,3,3-pentafluoro-1-propene obtained in the preceding stage to give 1,1,1,2,3-pentafluoropropane; (iv) purification of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage; and (v) dehydrofluorination of the 1,1,1,2,3-pentafluoropropane obtained in the preceding stage to give 2,3,3,3-tetrafluoro-1-propene; and (vi) purification of the 2,3,3,3-tetrafluoro-1-propene of the preceding stage.
摘要翻译：本发明的主题是制备2,3,3,3-四氟-1-丙烯的方法，包括以下步骤：（i）六氟丙烯的氢化，得到1,1,1,2,3， 3-六氟丙烷; （ii）前段得到的1,1,1,2,3,3-六氟丙烷的脱氟化氢，得到1,2,3,3,3-五氟-1-丙烯; （iii）在前一阶段获得的1,2,3,3,3-五氟-1-丙烯的氢化，得到1,1,1,2,3-五氟丙烷; （iv）前一阶段获得的1,1,1,2,3-五氟丙烷的纯化; 和（v）前一阶段获得的1,1,1,2,3-五氟丙烷的脱氟化氢，得到2,3,3,3-四氟-1-丙烯; 和（vi）前一阶段的2,3,3,3-四氟-1-丙烯的纯化。

3. 发明申请

US20120136183A1 METHOD FOR PREPARING FLUORINE COMPOUNDS 有权
标题翻译：氟化合物的制备方法
公开(公告)号：US20120136183A1
公开(公告)日：2012-05-31
申请号：US13382574
申请日：2010-05-21
申请人： Michel Devic , Nicolas Doucet , Laurent Wendlinger , Geraldine Cavallini , Pierre-Marie Sedat , Karine Avril
发明人： Michel Devic , Nicolas Doucet , Laurent Wendlinger , Geraldine Cavallini , Pierre-Marie Sedat , Karine Avril
IPC分类号： C07C17/25 , C07C17/383
CPC分类号： C07C17/25 , C07C17/354 , C07C21/18 , C07C19/08
摘要： The invention relates to a method for preparing fluoropropenes of formula (I) CF3CF═CHR, where R is a hydrogen or a fluorine atom from at least one compound of formula (Ia) CF3CF═CFR, where R has the same meaning as in formula (I), said method including the following steps: (i) hydrogenating at least one compound of formula (Ia) in an adiabatic reactor in the presence of a catalyst with a superstoichiometric amount of hydrogen so as to produce a hydrofluoropropane; (ii) partially condensing the flow from the adiabatic reactor of step (i) so as to produce a gaseous phase fraction, including unreacted hydrogen and a portion of the formed hydrofluoropropane, which is recirculated to step (i), and a liquid phase fraction including the residue of the hydrofluoropropane; (iii) dehydrofluorinating hydrofluoropropane from the liquid fraction of step (ii) using potassium hydroxide in an aqueous reaction medium contained in an agitated reactor so as to produce the fluoropropene of formula (I); and (iv) purifying the fluoropropene obtained in step (iii).
摘要翻译：本发明涉及一种制备式（I）CF 3 CF = CHR的氟丙烯的方法，其中R是至少一种式（Ia）CF 3 CF = CFR的化合物的氢或氟原子，其中R的定义与式（I），所述方法包括以下步骤：（i）在具有超化学计量的氢的催化剂存在下，在绝热反应器中氢化至少一种式（Ia）化合物以产生氢氟丙烷; （ii）部分冷凝来自步骤（i）的绝热反应器的流，以便产生气相馏分，包括未反应的氢气和一部分所形成的氢氟丙烷，其循环至步骤（i），以及液相馏分包括氢氟丙烷的残留物; （iii）使用氢氧化钾在搅拌反应器中的含水反应介质中，从步骤（ii）的液体馏分中脱氢氟化氢氟丙烷，以制备式（I）的氟丙烯; 和（iv）纯化步骤（iii）中获得的氟丙烯。

4. 发明授权

US08779217B2 Method for preparing fluorine compounds 有权
标题翻译：氟化合物的制备方法
公开(公告)号：US08779217B2
公开(公告)日：2014-07-15
申请号：US13382574
申请日：2010-05-21
申请人： Michel Devic , Nicolas Doucet , Laurent Wendlinger , Geraldine Cavallini , Pierre-Marie Sedat , Karine Avril
发明人： Michel Devic , Nicolas Doucet , Laurent Wendlinger , Geraldine Cavallini , Pierre-Marie Sedat , Karine Avril
IPC分类号： C07C17/25 , C07C17/354
CPC分类号： C07C17/25 , C07C17/354 , C07C21/18 , C07C19/08
摘要： The invention relates to a method for preparing fluoropropenes of formula (I) CF3CF═CHR, where R is a hydrogen or a fluorine atom from at least one compound of formula (Ia) CF3CF═CFR, where R has the same meaning as in formula (I), said method including the following steps: (i) hydrogenating at least one compound of formula (Ia) in an adiabatic reactor in the presence of a catalyst with a superstoichiometric amount of hydrogen so as to produce a hydrofluoropropane; (ii) partially condensing the flow from the adiabatic reactor of step (i) so as to produce a gaseous phase fraction, including unreacted hydrogen and a portion of the formed hydrofluoropropane, which is recirculated to step (i), and a liquid phase fraction including the residue of the hydrofluoropropane; (iii) dehydrofluorinating hydrofluoropropane from the liquid fraction of step (ii) using potassium hydroxide in an aqueous reaction medium contained in an agitated reactor so as to produce the fluoropropene of formula (I); and (iv) purifying the fluoropropene obtained in step (iii).
摘要翻译：本发明涉及一种制备式（I）CF 3 CF = CHR的氟丙烯的方法，其中R是至少一种式（Ia）CF 3 CF = CFR的化合物的氢或氟原子，其中R的定义与式（I），所述方法包括以下步骤：（i）在具有超化学计量的氢的催化剂存在下，在绝热反应器中氢化至少一种式（Ia）化合物以产生氢氟丙烷; （ii）部分地冷凝来自步骤（i）的绝热反应器的流，以便产生气相馏分，包括未反应的氢气和一部分所形成的氢氟丙烷，其循环至步骤（i），以及液相馏分包括氢氟丙烷的残留物; （iii）使用氢氧化钾在搅拌反应器中的含水反应介质中，从步骤（ii）的液体馏分中脱氢氟化氢氟丙烷，以制备式（I）的氟丙烯; 和（iv）纯化步骤（iii）中获得的氟丙烯。

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