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1. 发明申请

US20090155689A1 Lithium iron phosphate cathode materials with enhanced energy density and power performance 审中-公开
标题翻译：磷酸铁锂正极材料具有增强的能量密度和功率性能
公开(公告)号：US20090155689A1
公开(公告)日：2009-06-18
申请号：US12000625
申请日：2007-12-14
申请人： Karim Zaghib , Patrick Charest , Abdelbast Guerfi , Guoxian Liang
发明人： Karim Zaghib , Patrick Charest , Abdelbast Guerfi , Guoxian Liang
IPC分类号： H01M4/40 , H01M4/48 , C01B25/30
CPC分类号： H01M4/5825 , H01M4/364 , H01M4/366 , H01M4/625 , H01M10/0525
摘要： The invention is related to a cathode material comprising particles having a lithium metal phosphate core and a pyrolytic carbon deposit, said particles having a synthetic multimodal particle size distribution comprising at least one fraction of micron size particles and one fraction of submicron size particles, said lithium metal phosphate having formula LiMPO4 wherein M is at least Fe or Mn.Said material is prepared by method comprising the steps of providing starting micron sized particles and starting submicron sized particles of at least one lithium metal phosphate or of precursors of a lithium metal phosphate; mixing by mechanical means said starting particles; making a pyrolytic carbon deposit on the lithium metal phosphate starting particles before or after the mixing step, and on their metal precursor before or after mixing the particles; optionally adding carbon black, graphite powder or fibers to the said lithium metal phosphate particles before the mechanical mixing.
摘要翻译：本发明涉及包含具有锂金属磷酸盐芯和热解碳沉积物的颗粒的阴极材料，所述颗粒具有合成多峰粒度分布，其包含至少一部分微米级颗粒和一部分亚微米级颗粒，所述锂具有式LiMPO 4的金属磷酸盐，其中M至少为Fe或Mn。所述材料通过包括以下步骤的方法制备：包括提供起始微米尺寸的颗粒和开始至少一种锂金属磷酸盐或锂金属磷酸盐前体的亚微米尺寸的颗粒; 通过机械装置混合所述起始颗粒; 在混合步骤之前或之后在锂金属磷酸盐起始颗粒上制备热解碳沉积物，以及在混合颗粒之前或之后对其金属前体; 在机械混合之前，任选地将碳黑，石墨粉或纤维加入到所述锂金属磷酸盐颗粒中。

2. 发明授权

US08435671B2 Multilayer material, method for making same and use as electrode 有权
标题翻译：多层材料，制作方法和电极用途
公开(公告)号：US08435671B2
公开(公告)日：2013-05-07
申请号：US12162933
申请日：2007-01-31
申请人： Karim Zaghib , Michel Petitclerc , Patrick Charest , Abdelbast Guerfi , Martin Dontigny
发明人： Karim Zaghib , Michel Petitclerc , Patrick Charest , Abdelbast Guerfi , Martin Dontigny
IPC分类号： B23H3/04 , B05D5/12 , C25B9/00
CPC分类号： H01M4/485 , H01M4/0404 , H01M4/0421 , H01M4/0426 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/136 , H01M4/1391 , H01M4/1393 , H01M4/1395 , H01M4/1397 , H01M4/366 , H01M4/5805 , H01M4/5825 , H01M4/621 , H01M10/0525 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2300/0085 , H01M2300/0091 , Y02E60/122 , Y02P70/54
摘要： A multilayer material includes a solid substrate and at least two superimposed solid layers containing particles of an electrochemically active material, the first solid layer adhering to the solid substrate and the second solid layer adhering to the first solid layer. The multilayer material has a constant thickness of upper layer not less than 95% and a depth of penetration of the second layer into the first layer which is less than 10% of the thickness of the first layer, and enables as electrode constituent, generators having a low risk of overload degradation to be prepared.
摘要翻译：多层材料包括固体基质和包含电化学活性材料的颗粒的至少两个叠加的固体层，第一固体层粘附到固体基底和粘附到第一固体层的第二固体层。多层材料具有上层的恒定厚度不小于95％，第二层进入第一层的深度小于第一层的厚度的10％，并且能够作为电极组分，具有低准备过载降解的风险。

3. 发明授权

US07588826B2 Particle containing a graphite based nucleus with at least one continuous or discontinuous layer, processes for preparing the same and their uses 有权
标题翻译：含有至少一个连续或不连续层的基于石墨的核的颗粒，其制备方法及其用途
公开(公告)号：US07588826B2
公开(公告)日：2009-09-15
申请号：US10532793
申请日：2003-10-23
申请人： Karim Zaghib , Patrick Charest , Abdelbast Guerfi , Michel Perrier , Kimio Kinoshita
发明人： Karim Zaghib , Patrick Charest , Abdelbast Guerfi , Michel Perrier , Kimio Kinoshita
IPC分类号： B32B5/66
CPC分类号： H01M4/90 , C01P2004/03 , C01P2006/40 , C08K3/04 , C08K9/04 , C09C1/46 , C09C1/56 , C09D5/24 , C09D7/62 , H01M4/362 , H01M4/587 , H01M4/625 , H01M4/96 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2996 , Y10T428/2998
摘要： Process for preparing by crushing, a homogenous mixture of particles containing a conductive nucleus including at least one graphite and continuously or discontinuously coated with at least one material that is different from the one constituting the nucleus, the size of the particles of the nucleus being larger than the particles used for coating the nuclei by crushing the particles together. The mixtures of particles obtained show electrochemical and mechanical properties that enable them to be advantageously used in electrochemical batteries and in paints.
摘要翻译：通过粉碎制备包含至少一种石墨的导电核的颗粒的均匀混合物的方法，并连续地或不连续地涂覆有至少一种与构成核的材料不同的材料，核的颗粒尺寸更大比用于通过将颗粒粉碎在一起来涂覆核的颗粒。获得的颗粒的混合物显示出电化学和机械性能，使得它们有利地用于电化学电池和涂料中。

4. 发明申请

US20090123845A1 Electrolyte purification method, electrolytes and generators thus obtained and use of same 审中-公开
标题翻译：电解液净化方法，电解液和发电机因此得到并使用相同
公开(公告)号：US20090123845A1
公开(公告)日：2009-05-14
申请号：US11991270
申请日：2006-07-28
申请人： Karim Zaghib , Jocelyn Jalbert , Abdelbast Guerfi , Christophe Michot , Michel Gauthier , Martin Dontigny , Patrick Charest
发明人： Karim Zaghib , Jocelyn Jalbert , Abdelbast Guerfi , Christophe Michot , Michel Gauthier , Martin Dontigny , Patrick Charest
IPC分类号： B01D15/00 , H01M10/26 , H01M4/36 , B01J20/04 , C01D15/00 , H01M4/40
CPC分类号： H01M10/4242 , B01D15/00 , H01M10/0565 , H01M10/0566 , H01M2300/0085
摘要： Process for the purification of an ionic electrolyte comprising at least one alkali metal salt, the process having at least one stage in which particles of at least one calcium salt are brought into contact. The process makes it possible to obtain electrolytes characterized in particular by a particularly low water content. The corresponding electrochemical generators which incorporate the electrolyte as constituent component are characterized by a noteworthy stability and are particularly safe.
摘要翻译：用于纯化包含至少一种碱金属盐的离子电解质的方法，该方法具有至少一个阶段，其中使至少一种钙盐的颗粒接触。该方法可以获得特别特别是特别低含水量的电解质。结合电解质作为组成成分的相应的电化学发生器的特征在于值得注意的稳定性并且特别安全。

5. 发明申请

US20050234177A1 Highly-stable polymeric electrolyte and use thereof in electrochemical systems 有权
标题翻译：高度稳定的聚合物电解质及其在电化学系统中的应用
公开(公告)号：US20050234177A1
公开(公告)日：2005-10-20
申请号：US10501844
申请日：2003-01-15
申请人： Karim Zaghib , Michel Perrier , Abdelbast Guerfi , Elisabeth Dupuis , Patrick Charest , Francois Allaire , Michel Armand
发明人： Karim Zaghib , Michel Perrier , Abdelbast Guerfi , Elisabeth Dupuis , Patrick Charest , Francois Allaire , Michel Armand
IPC分类号： C08J3/24 , C08K3/00 , C08L33/12 , C08L33/20 , C08L101/02 , H01G11/32 , H01G11/56 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/36 , C08L1/00
CPC分类号： H01G9/038 , C08F283/00 , C08F290/062 , C08G65/2609 , C08G65/33348 , C08L33/12 , C08L71/02 , C09D133/12 , H01G11/56 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2300/0091 , Y02E60/13 , C08L2666/04
摘要： Polymer electrolyte for an electrochemical generator based on at least a four branched polymer, at least a poly(vinylyldienefluoride), a poly(vinyldiene fluoro-co-hexafluoropropene copolymer), a poly(tetrafluoroethylene), a poly(ethylene-co-propylene-co-5-methylene-2-norbornene) or an ethylene propylene-diene copolymer, a polyol, a poly(methylmethacrylate, a poly(acrylonitrile), SiO2Al2O3, or nano TiO2 non coated or coated with an organic material. This electrolyte allows to prepare electrolytic compositions that can be used in high performance electrochemical devices.
摘要翻译：至少四种支链聚合物，至少一种聚（乙烯基二氟化物），聚（乙烯基二烯氟 - 共 - 六氟丙烯共聚物），聚（四氟乙烯），聚（乙烯 - 共 - 丙烯 - 共 - 5-亚甲基-2-降冰片烯）或乙烯丙烯 - 二烯共聚物，多元醇，聚甲基丙烯酸甲酯，聚（丙烯腈），SiO 2 Al 2 O 2， O 3或非有机材料的纳米TiO 2，该电解质允许制备可用于高性能电化学装置的电解质组合物。

6. 发明授权

US10147978B2 Electrolyte purification method using calcium carbide, and electrolytes thus obtained 有权
公开(公告)号：US10147978B2
公开(公告)日：2018-12-04
申请号：US11991270
申请日：2006-07-28
申请人： Karim Zaghib , Jocelyn Jalbert , Abdelbast Guerfi , Christophe Michot , Michel Gauthier , Martin Dontigny , Patrick Charest
发明人： Karim Zaghib , Jocelyn Jalbert , Abdelbast Guerfi , Christophe Michot , Michel Gauthier , Martin Dontigny , Patrick Charest
IPC分类号： H01M10/42 , H01M10/0566 , B01D15/00 , H01M10/0565
摘要： Process for the purification of an ionic electrolyte comprising at least one alkali metal salt, the process having at least one stage in which particles of at least one calcium salt are brought into contact. The process makes it possible to obtain electrolytes characterized in particular by a particularly low water content. The corresponding electrochemical generators which incorporate the electrolyte as constituent component are characterized by a noteworthy stability and are particularly safe.

7. 发明授权

US08048561B2 Process for the preparation of an electrode from a porous material, electrode thus obtained and corresponding electrochemical system 有权
标题翻译：从多孔材料制备电极的方法，由此获得的电极和相应的电化学系统
公开(公告)号：US08048561B2
公开(公告)日：2011-11-01
申请号：US10561845
申请日：2004-06-25
申请人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
发明人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
IPC分类号： H01M4/02 , H01M4/00 , H01M4/50 , H01M4/58
CPC分类号： H01M4/0438 , C01B33/02 , H01M4/044 , H01M4/0461 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/505 , H01M4/525 , H01M4/624 , H01M4/625 , H01M10/052 , Y10T29/49108
摘要： Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mAh/gram, a high capacity in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
摘要翻译：用于从多孔材料制备电极的方法，使得可以获得可用于电化学系统并且具有以下特性中的至少一个的电极：以mAh /克的高容量，以mAh /升的高容量，a 良好的自行车能力，自放电率低，环境友好性好。

8. 发明申请

US20070154805A1 Process for the preparation of an electrode from a porous material, electrode thus obtained and corresponding electrochemical system 有权
标题翻译：从多孔材料制备电极的方法，由此获得的电极和相应的电化学系统
公开(公告)号：US20070154805A1
公开(公告)日：2007-07-05
申请号：US10561845
申请日：2004-06-25
申请人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
发明人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
IPC分类号： H01M4/04 , H01M4/58 , H01M4/50 , H01M4/52 , B05D5/12
CPC分类号： H01M4/0438 , C01B33/02 , H01M4/044 , H01M4/0461 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/505 , H01M4/525 , H01M4/624 , H01M4/625 , H01M10/052 , Y10T29/49108
摘要： Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mnAh/gram, a high capaciaty in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
摘要翻译：用于从多孔材料制备电极的方法，使得可以获得可用于电化学系统并具有以下特性中的至少一个的电极：以mnAh /克的高容量，mAh /升的高电容，良好的自行车能力，自放电率低，环境友好性好。

9. 发明授权

US09431675B2 Material consisting of composite oxide particles, method for preparing same, and use thereof as electrode active material 有权
标题翻译：由复合氧化物颗粒组成的材料，其制备方法及其作为电极活性材料的用途
公开(公告)号：US09431675B2
公开(公告)日：2016-08-30
申请号：US13394665
申请日：2010-09-15
申请人： Abdelbast Guerfi , Jean-François Labrecque , Martin Dontigny , Patrick Charest , Karim Zaghib
发明人： Abdelbast Guerfi , Jean-François Labrecque , Martin Dontigny , Patrick Charest , Karim Zaghib
IPC分类号： H01M6/14 , H01M10/052 , H01M4/36 , H01M4/58 , H01M4/62
CPC分类号： H01M10/052 , H01M4/366 , H01M4/5825 , H01M4/625 , Y02E60/122 , Y02P70/54
摘要： A positive electrode material, having particles having a complex oxide OC1 core, an at least partial complex oxide OC2 coating, and an adhesive carbon surface deposit. The material is characterized in that the complex oxide OC1 is an oxide having a high energy density and in that the oxide OC2 is an oxide of a metal having a catalytic effect on the reaction of the carbon deposit, the oxide having good electronic conductivity. The presence of the OC2 layer facilitates the deposit of a carbon adhesive layer at the surface of the oxide particles, and improves the conductivity of the material when the latter is used as an electrode material. The electrode material can particularly be used in the manufacture of a lithium battery.
摘要翻译：具有具有复合氧化物OC1芯，至少部分复合氧化物OC2涂层和粘合剂碳表面沉积物的颗粒的正极材料。该材料的特征在于复合氧化物OC1是具有高能量密度的氧化物，并且氧化物OC2是具有对碳沉积物的反应具有催化作用的金属的氧化物，氧化物具有良好的电子导电性。 OC2层的存在有助于在氧化物颗粒的表面上沉积碳粘合剂层，并且当材料用作电极材料时，材料的导电性提高。电极材料可以特别用于制造锂电池。

10. 发明授权

US08828103B2 Process for the preparation of an electrode from a porous material, electrode thus obtained and corresponding electrochemical system 有权
标题翻译：从多孔材料制备电极的方法，由此获得的电极和相应的电化学系统
公开(公告)号：US08828103B2
公开(公告)日：2014-09-09
申请号：US13243448
申请日：2011-09-23
申请人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
发明人： Karim Zaghib , Abdelbast Guerfi , Patrick Charest , Robert Kostecki , Kimio Kinoshita , Michel Armand
IPC分类号： H01M6/00 , H01M4/02 , H01M4/13
CPC分类号： H01M4/0438 , C01B33/02 , H01M4/044 , H01M4/0461 , H01M4/0495 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/387 , H01M4/405 , H01M4/505 , H01M4/525 , H01M4/624 , H01M4/625 , H01M10/052 , Y10T29/49108
摘要： Process for the preparation of electrodes from a porous material making it possible to obtain electrodes that are useful in electrochemical systems and that have at least one of the following properties: a high capacity in mAh/gram, a high capacity in mAh/liter, a good capacity for cycling, a low rate of self discharge, and a good environmental tolerance.
摘要翻译：用于从多孔材料制备电极的方法，使得可以获得可用于电化学系统并且具有以下特性中的至少一个的电极：以mAh /克的高容量，以mAh /升的高容量，a 良好的自行车能力，自放电率低，环境友好性好。

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