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    • 1. 发明申请
    • Electrode structure for solid polymer type fuel cell
    • 固体聚合物型燃料电池的电极结构
    • US20060068269A1
    • 2006-03-30
    • US10532963
    • 2003-10-21
    • Kaoru FukudaMasaki TaniHayato KajiShigeru InaiTakeshi MuroShinya Watanabe
    • Kaoru FukudaMasaki TaniHayato KajiShigeru InaiTakeshi MuroShinya Watanabe
    • H01M4/94H01M4/96H01M8/10H01M8/04
    • H01M8/1004H01M4/8605H01M4/8657H01M4/926
    • A water holding layer having a carbon-based material and a water holding material is arranged on an anode diffusion layer. The water holding material is contained at 5 to 20 wt % of total weight of the water holding material and an electron conductive material. Alternatively, carbon particles having water absorption amount at saturated water vapor pressure at 60° C. is not less than 150 cc/g are contained in the anode diffusion layer. Water absorption ratio of the anode diffusion layer at 60° C. is in a range of 40 to 85%, a differential pressure is in a range of 60 to 120 mmaq, and a ratio of quantity of electric charge of catalytic material of the cathode catalytic layer existing in proton conductive passage from the polymer electrolyte membrane is not less than 15% of the quantity of electric charge of all the catalytic material existing in the cathode catalytic layer. Furthermore, a layer including carbon particles having water absorption amount at saturated water vapor pressure at 60° C. of not less than 150 cc/g and fluorine resin, is arranged on a carbon-based material having a contact angle with water of not more than 90° by performing a hydrophilic treatment. The water absorption ratio at 60° C. is in a range of 40 to 85 wt %, and the penetration resistance is not more than 5 mΩ.
    • 具有碳基材料和保水材料的保水层设置在阳极扩散层上。 保水材料的含水量为水保持材料的总重量的5〜20重量%和电子传导性材料。 或者,阳极扩散层中含有在60℃的饱和水蒸气压下的吸水量为150cc / g以上的碳粒子。 阳极扩散层在60℃下的吸水率在40〜85%的范围内,差压在60〜120mm范围内,阴极的催化剂材料的电荷比例 存在于高分子电解质膜的质子传导路径中的催化剂层不低于存在于阴极催化剂层中的所有催化材料的电荷量的15%。 此外,将具有不低于150cc / g的饱和水蒸汽压在60℃以下的吸水量为150cc / g以上的碳粒子和氟树脂的层设置在与水不接触的接触角的碳系材料上 超过90°。 60℃下的吸水率为40〜85重量%,耐渗透性为5mOmega以下。