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1. 发明授权

US07018710B2 Heat sealable polyethylene film and method for its preparation 有权
标题翻译：可热封聚乙烯薄膜及其制备方法
公开(公告)号：US07018710B2
公开(公告)日：2006-03-28
申请号：US10312713
申请日：2001-06-29
申请人： Kalle Kallio , Jari Äärilä , Merete Skar , Arja Lehtinen
发明人： Kalle Kallio , Jari Äärilä , Merete Skar , Arja Lehtinen
IPC分类号： B32B27/08 , B32B27/32
CPC分类号： B32B27/08 , B32B27/32 , B32B27/327 , B32B2250/242 , B32B2307/31 , B32B2307/412 , B32B2307/558 , B32B2307/72 , B32B2439/70 , B32B2439/80 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2314/06 , Y10T428/2817 , Y10T428/2878 , Y10T428/31855 , Y10T428/31913 , Y10T428/31938 , C08L2666/06
摘要： A process for the preparation of a heat sealable film comprising a core layer and a sealing layer, said process comprising attaching said core layer to said sealing layer, said sealing layer comprising an ethylene copolymer composition in which: (1) there are two distinct maxima in the TREF fractogram of the ethylene copolymer composition; (2) at lest 10%, of the ethylene copolymer composition elutes in TREF at a temperature of less than 50° C.; (3) at least 25%, of the ethylene copolymer composition elutes in TREF at a temperature of higher than 75° C.; (4) none of the ethylene copolymer composition elutes in TREF at a temperature of higher than 100° C.; (5) the ethylene copolymer composition comprises two components, one of which is of relatively high comonomer content and high molecular weight, the other of which is of relatively low comonomer content and low molecular weight, both components being prepared by polymerisation of ethylene with a C3-20 alpha-olefin in the present of a single site catalyst; (6) the ethylene copolymer composition has a density of between 905 and 930 kg/m3, and an MFR2 between 0.3 and 4.0 g/10 min.
摘要翻译：一种制备可热封膜的方法，包括芯层和密封层，所述方法包括将所述芯层附着到所述密封层，所述密封层包含乙烯共聚物组合物，其中：（1）存在两个不同的最大值在乙烯共聚物组成的TREF分解图中; （2）至少10％的乙烯共聚物组合物在低于50℃的温度下在TREF中洗脱; （3）至少25％的乙烯共聚物组合物在高于75℃的温度下在TREF中洗脱; （4）乙烯共聚物组合物中没有一种在高于100℃的温度下在TREF中洗脱。（5）乙烯共聚物组合物包含两种组分，其中一种组分具有相对高的共聚单体含量和高分子量，另一种组分的共聚单体含量相对较低，分子量低，两种组分均通过乙烯与单一位点催化剂存在下的3-30-α-烯烃; （6）所述乙烯共聚物组合物的密度在905至930kg / m 3的范围内，MFR 2之间的密度在0.3至4.0g / 10min之间。

2. 发明授权

US06632884B1 Polymer composition, a process for the production thereof and films prepared thereof 有权
标题翻译：聚合物组合物，其制备方法和其制备的膜
公开(公告)号：US06632884B1
公开(公告)日：2003-10-14
申请号：US09857901
申请日：2001-10-01
申请人： Merete Skar , Ole Jan Myhre , Arja Lehtinen , Harri Hokkanen , Hilkka Knuuttila , Kalle Kallio , Esa Kinnunen , Eija Lappi
发明人： Merete Skar , Ole Jan Myhre , Arja Lehtinen , Harri Hokkanen , Hilkka Knuuttila , Kalle Kallio , Esa Kinnunen , Eija Lappi
IPC分类号： C08F2002
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F2/001 , C08F4/65927 , C08F2500/12 , C08F2500/07 , C08F2500/26 , C08F210/08
摘要： This invention concerns process for producing polyethylene compositions, films prepared thereof and process for the preparation of the films. The process comprises subjecting ethylene, optionally hydrogen and comonomers to polymerization or copolymerization reactions in a multistage polymerization. At least one polymerization stage is conducted essentially in the absence of hydrogen. The polymerization reactions are carried out in the presence of a single-site catalyst capable of forming a composition comprising a low molecular weight component with MFR2 of at least 10 g/10 min and a density higher than the density of the composition and a high molecular weight component. The melt flow rate of the composition is in the range MFR2=0.1-5.0 g/10 min and the density of the composition is 915-960 kg/m3. The invention makes it possible to produce polyethylene compositions for manufacturing films with a good balance between optical and mechanical properties.
摘要翻译：本发明涉及生产聚乙烯组合物的方法，其制备的薄膜及其制备方法。该方法包括使乙烯，任选的氢和共聚单体在多级聚合中进行聚合或共聚反应。基本上在不存在氢的情况下进行至少一个聚合阶段。聚合反应在能够形成包含至少10g / 10分钟的MFR低于2分子量组分的组合物的单中心催化剂的存在下进行并且密度高于组合物的密度和高分子量组分。组合物的熔体流动速率在MFR 2 = 0.1-5.0g / 10min的范围内，组合物的密度为915-960kg / m 2 <3 。本发明使得可以生产用于制造具有光学和机械性能之间良好平衡的膜的聚乙烯组合物

3. 发明申请

US20080139749A1 Copolymer 审中-公开
标题翻译：共聚物
公开(公告)号：US20080139749A1
公开(公告)日：2008-06-12
申请号：US11792877
申请日：2005-12-22
申请人： Arja Lehtinen , Merete Skar , Jarmo Lindroos , Janne Maaranen , Markku Vahteri , Hans Eklind , Holger Poehler , Alexander Krajete
发明人： Arja Lehtinen , Merete Skar , Jarmo Lindroos , Janne Maaranen , Markku Vahteri , Hans Eklind , Holger Poehler , Alexander Krajete
IPC分类号： C08L23/08
CPC分类号： C08L23/0815 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08J5/18 , C08J7/04 , C08J2323/08 , C08J2423/08 , C08L2205/02 , C08L2308/00 , C08L2666/06 , C08F4/65925 , C08F210/08 , C08F2500/08 , C08F2500/02 , C08F2500/12 , C08F2500/17 , C08F210/14 , C08F2500/26
摘要： A multimodal copolymer of ethylene comprising at least (i) a lower molecular weight fraction of a copolymer of ethylene and at least one alpha-olefin comonomer and (ii) a higher molecular weight fraction of a copolymer of ethylene and at least one alpha-olefin comonomer, wherein said copolymer has a density below 920 kg/m3.
摘要翻译：一种乙烯的多峰共聚物，其至少包含（i）乙烯与至少一种α-烯烃共聚单体的共聚物的较低分子量馏分和（ii）乙烯与至少一种α-烯烃的共聚物的较高分子量馏分共聚单体，其中所述共聚物的密度低于920kg / m 3。

4. 发明授权

US07504141B2 Shrink film 有权
标题翻译：收缩膜
公开(公告)号：US07504141B2
公开(公告)日：2009-03-17
申请号：US10523359
申请日：2003-07-29
申请人： Ole Jan Myhre , Merete Skar , Hans Georg Daviknes , Kjetil Larsen Brove , Geir Morten Johansen
发明人： Ole Jan Myhre , Merete Skar , Hans Georg Daviknes , Kjetil Larsen Brove , Geir Morten Johansen
IPC分类号： B65B53/00 , B65B53/02 , C08F210/00 , C08F210/02
CPC分类号： C08J5/18 , C08F210/16 , C08F297/083 , C08J2323/08 , C08L23/0815 , C08L2205/02 , Y10T428/13 , Y10T428/1303 , Y10T428/1328 , Y10T428/1352 , Y10T428/1359 , C08F2/001 , C08L2666/06 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/26
摘要： A shrink film comprising a polyethylene film, characterized in that said polyethylene is an ethylene copolymer mixture having a molecular weight distribution in the range 10 to 35, a density of 915 to 940 kg/m3, a weight average molecular weight of at least 100000 D and an MFR2.16 (190° C.) of 0.1 to 0.9 kg/m3, which copolymer mixture is produced by a two or more stage copolymerization of ethylene and 2 to 10% mole (relative to ethylene) of a C3-12 alpha-olefin comonomer in a series of reactors including at least one slurry loop reactor and at least one gas phase reactor using a heterogeneous Ziegler-Natta catalyst.
摘要翻译：一种包含聚乙烯膜的收缩膜，其特征在于所述聚乙烯是分子量分布在10至35，密度为915至940kg / m 3，重均分子量至少为100000D的乙烯共聚物混合物并且MFR2.16（190℃）为0.1至0.9kg / m 3，该共聚物混合物通过乙烯和2-10％摩尔（相对于乙烯）的C3-12α的两个或多个阶段共聚制备烯烃共聚单体在一系列反应器中，包括至少一个淤浆环流反应器和至少一个使用异质齐格勒 - 纳塔催化剂的气相反应器。

5. 发明申请

US20100099824A1 MULTIMODAL MEDIUM DENSITY POLYETHYLENE POLYMER COMPOSITION 有权
标题翻译：多中心密度聚乙烯聚合物组合物
公开(公告)号：US20100099824A1
公开(公告)日：2010-04-22
申请号：US12449090
申请日：2008-01-24
申请人： Irene Helland , Merete Skar
发明人： Irene Helland , Merete Skar
IPC分类号： C08L23/06
CPC分类号： C08L23/06 , C08J5/18 , C08J2323/04 , C08L23/0815 , Y10T428/31855 , Y10T428/31938 , C08L2666/06
摘要： A multimodal medium density polyethylene polymer obtainable using single site catalysis which comprises at least: (A) a lower molecular weight (LMW) polyethylene homopolymer component; and (B) a higher molecular weight (HMW) polyethylene copolymer component which is a copolymer of ethylene and at least one C3-12-alpha olefin; wherein said multimodal medium density polyethylene polymer has a density of 925 to 945 kg/m3 and a comonomer content of less than 2.5 mol %.
摘要翻译：使用单位点催化可获得的多峰中密度聚乙烯聚合物，其至少包括：（A）低分子量（LMW）聚乙烯均聚物组分; 和（B）较高分子量（HMW）聚乙烯共聚物组分，其是乙烯和至少一种C3-12-α-烯烃的共聚物; 其中所述多峰中密度聚乙烯聚合物的密度为925至945kg / m 3，共聚单体含量小于2.5mol％。

6. 发明授权

US08314187B2 Multimodal medium density polyethylene polymer composition 有权
标题翻译：多峰中密度聚乙烯聚合物组合物
公开(公告)号：US08314187B2
公开(公告)日：2012-11-20
申请号：US12449090
申请日：2008-01-24
申请人： Irene Helland , Merete Skar
发明人： Irene Helland , Merete Skar
IPC分类号： C08L23/06 , C08L23/08 , C08J5/18
CPC分类号： C08L23/06 , C08J5/18 , C08J2323/04 , C08L23/0815 , Y10T428/31855 , Y10T428/31938 , C08L2666/06
摘要： A multimodal medium density polyethylene polymer obtainable using single site catalysis which comprises at least: (A) a lower molecular weight (LMW) polyethylene homopolymer component; and (B) a higher molecular weight (HMW) polyethylene copolymer component which is a copolymer of ethylene and at least one C3-12-alpha olefin; wherein said multimodal medium density polyethylene polymer has a density of 925 to 945 kg/m3 and a comonomer content of less than 2.5 mol %.
摘要翻译：使用单位点催化可获得的多峰中密度聚乙烯聚合物，其至少包括：（A）低分子量（LMW）聚乙烯均聚物组分; 和（B）较高分子量（HMW）聚乙烯共聚物组分，其是乙烯和至少一种C3-12-α-烯烃的共聚物; 其中所述多峰中密度聚乙烯聚合物的密度为925至945kg / m 3，共聚单体含量小于2.5mol％。

7. 发明授权

US07256239B2 Polymer film 有权
标题翻译：聚合物膜
公开(公告)号：US07256239B2
公开(公告)日：2007-08-14
申请号：US10501625
申请日：2003-02-04
申请人： Irene Helland , Merete Skar , Jani Äärilä , Marja Ora , Markku Vahteri
发明人： Irene Helland , Merete Skar , Jani Äärilä , Marja Ora , Markku Vahteri
IPC分类号： C08F210/16
CPC分类号： C08J5/18 , C08F110/02 , C08F210/16 , C08F297/08 , C08J2323/08 , Y10T428/31855 , Y10T428/31909 , C08F2/001 , C08F210/08 , C08F210/14 , C08F2500/01 , C08F2500/05 , C08F2500/26 , C08F2500/02 , C08F2500/12
摘要： A film of a polyethylene produced by polymerization catalysed by a single site catalyst and comprising as comonomers to ethylene at least two C4-12 alpha olefins, preferably but-1-ene and hex-1-ene.
摘要翻译：通过由单中心催化剂催化并通过共聚单体包含至少两种C 4-12α-烯烃，优选丁-1-烯和己-1-烯的乙烯生产的聚乙烯膜。

8. 发明申请

US20060106182A1 Schrink film 有权
标题翻译： Schrink电影
公开(公告)号：US20060106182A1
公开(公告)日：2006-05-18
申请号：US10523424
申请日：2003-07-29
申请人： Ole Myhre , Merete Skar , Hans Daviknes , Kjetil Borve , Geir JOhansen
发明人： Ole Myhre , Merete Skar , Hans Daviknes , Kjetil Borve , Geir JOhansen
IPC分类号： C08F10/00
CPC分类号： C08L23/06 , C08F297/083 , C08L23/0815 , Y10T428/31855 , C08L2666/06
摘要： A shrink film comprising a polyethylene film of thickness 5 to 500 μm, wherein the polyethylene comprises an ethylene homopolymer-copolymer mixture having a molecular weight distribution in the range of 5 to 40, and a weight average molecular weight of at least 100 kD.
摘要翻译：一种包含厚度为5-500μm的聚乙烯薄膜的收缩薄膜，其中所述聚乙烯包括分子量分布在5至40范围内且重均分子量至少为100kD的乙烯均聚物 - 共聚物混合物。

9. 发明申请

US20050131187A1 Polymer film 有权
标题翻译：聚合物膜
公开(公告)号：US20050131187A1
公开(公告)日：2005-06-16
申请号：US10501625
申请日：2003-02-04
申请人： Irene Helland , Merete Skar , Jani Aarila , Marja Ora , Markku Vahteri
发明人： Irene Helland , Merete Skar , Jani Aarila , Marja Ora , Markku Vahteri
IPC分类号： C08L23/04 , C08F110/02 , C08F210/02 , C08F210/16 , C08F297/08 , C08J5/18 , C08F4/44
CPC分类号： C08J5/18 , C08F110/02 , C08F210/16 , C08F297/08 , C08J2323/08 , Y10T428/31855 , Y10T428/31909 , C08F2/001 , C08F210/08 , C08F210/14 , C08F2500/01 , C08F2500/05 , C08F2500/26 , C08F2500/02 , C08F2500/12
摘要： A film of a polyethylene produced by polymerization catalysed by a single site catalyst and comprising as comonomers to ethylene at least two C4-12 alpha olefins, preferably but-1-ene and hex-1-ene.
摘要翻译：通过由单中心催化剂催化并通过共聚单体包含至少两种C 4-12α-烯烃，优选丁-1-烯和己-1-烯的乙烯生产的聚乙烯膜。

10. 发明授权

US07517941B2 Shrink film 有权
标题翻译：收缩膜
公开(公告)号：US07517941B2
公开(公告)日：2009-04-14
申请号：US10523424
申请日：2003-07-29
申请人： Ole Jan Myhre , Merete Skar , Hans Georg Daviknes , Kjetil Larsen Borve , Geir Morten Johansen
发明人： Ole Jan Myhre , Merete Skar , Hans Georg Daviknes , Kjetil Larsen Borve , Geir Morten Johansen
IPC分类号： B65B53/02 , C08L23/08 , B32B27/32
CPC分类号： C08L23/06 , C08F297/083 , C08L23/0815 , Y10T428/31855 , C08L2666/06
摘要： A shrink film comprising a polyethylene film of thickness 5 to 500 μm, wherein the polyethylene comprises an ethylene homopolymer-copolymer mixture having a molecular weight distribution in the range of 5 to 40, and a weight average molecular weight of at least 100 kD.
摘要翻译：一种包含厚度为5-500μm的聚乙烯薄膜的收缩薄膜，其中所述聚乙烯包括分子量分布在5至40范围内且重均分子量至少为100kD的乙烯均聚物 - 共聚物混合物。

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