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    • 7. 发明专利
    • DE1904857A1
    • 1969-09-11
    • DE1904857
    • 1969-01-31
    • KUREHA CHEMICAL IND CO LTD
    • SUZUKI SHIGEYUKIKANEDA ISAMUTAKAHASHI MASAAKINAGAI HIROSHI
    • C08G73/10C08G20/32
    • 1,204,086. Soluble copolyimides. KUREHA KAGAKU KOGYO K.K. 29 Jan., 1969 [1 Feb., 1968], No. 4974/69. Heading C3R. Soluble copolyimides are prepared from an aromatic diamine and a mixture of a major proportion of 1,2,3,4- and a minor proportion of 1,2,4,5-benzene tetracarboxylic acid dianhydrides. Specified diamines are 3,3 1 -diamino diphenyl ether, methane, sulphide and ketone. Polycondensation may be effected at -60‹ to 50‹ C. in a polar organic solvent e.g. N,N 1 - dimethyl acetamide or formamide, N - methyl pyrrolidone, dimethyl sulphoxide or pyridine to give a polyamide acid which may be treated with an imidizing agent, e.g. a molecular sieve or a mixture of pyridine, acetic anhydride and optionally benzene, to give a solution of the polyimide. The polyimide solutions may be used as a coating or adhesive for electric wire, for casting films or forming fibres by spinning into a non-solvent. The polyimide may be purified by precipitation in water-free benzene and redissolved in an organic polar solvent or sulphuric acid.