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1. 发明专利

CA2285275C CARBONACEOUS ELECTRODE MATERIAL FOR NON-AQUEOUS SECONDARY BATTERY 未知
公开(公告)号：CA2285275C
公开(公告)日：2003-12-16
申请号：CA2285275
申请日：1998-04-03
申请人： SONY CORP , KUREHA CHEMICAL IND CO LTD
发明人： ISHIKAWA MINORU , IMOTO HIROSHI , AZUMA HIDETO , SENOO TADASHI , YAMADA SHINICHIRO , SONOBE NAOHIRO , MASUKO JIRO , SEKAI KOJI , NAGAMINE MASAYUKI , OMARU ATSUO
IPC分类号： C01B31/02 , H01M4/133 , H01M4/1393 , H01M4/587 , H01M4/96 , H01M10/05 , H01M4/58
摘要： A carbonaceous electrode having improved capacities for doping and dedoping of a cell active substance, such as lithium, and suitable for a non-aqueous solvent secondary battery, is constituted by a carbonaceous material having a true density as measured by a butanol substitution method of at most 1.46 g/cm3, a true density as measured by a helium substitution method of at leas t 1.7 g/cm3, a hydrogen-to-carbon atomic ratio H/C of at most 0.15 as measured according to elementary analysis, a BET specific surface area of at most 50 m2/g as measured by nitrogen adsorption BET method, and a carbon dioxide adsorption capacity of at least 10 ml/g. The carbonaceous material is advantageously produced by carbonizing an organic material originated from bamboo genera of family Gramineae, particularly genus Pleioblastus or Bambus a, at 1000 - 1400 ~C under a reduced pressure or under a flowing inert gas stre am to provide an appropriate porous structure.

2. 发明专利

CA2285275A1 CARBONACEOUS ELECTRODE MATERIAL FOR NON-AQUEOUS SECONDARY BATTERY 未知
公开(公告)号：CA2285275A1
公开(公告)日：1998-10-08
申请号：CA2285275
申请日：1998-04-03
申请人： KUREHA CHEMICAL IND CO LTD , SONY CORP
发明人： ISHIKAWA MINORU , YAMADA SHINICHIRO , AZUMA HIDETO , NAGAMINE MASAYUKI , SONOBE NAOHIRO , SENOO TADASHI , OMARU ATSUO , IMOTO HIROSHI , MASUKO JIRO , SEKAI KOJI
IPC分类号： C01B31/02 , H01M4/133 , H01M4/1393 , H01M4/587 , H01M4/96 , H01M10/05 , H01M4/58
摘要： A carbonaceous electrode having improved capacities for doping and dedoping of a cell active substance, such as lithium, and suitable for a non-aqueous solvent secondary battery, is constituted by a carbonaceous material having a true density as measured by a butanol substitution method of at most 1.46 g/cm3, a true density as measured by a helium substitution method of at least 1.7 g/cm3, a hydrogen-to-carbon atomic ratio H/C of at most 0.15 as measured according to elementary analysis, a BET specific surface area of at most 50 m2/g as measured by nitrogen adsorption BET method, and a carbon dioxide adsorption capacity of at least 10 ml/g. The carbonaceous material is advantageously produced by carbonizing an organic material originated from bamboo genera of family Gramineae, particularly genus Pleioblastus or Bambusa, at 1000 - 1400 ~C under a reduced pressure or under a flowing inert gas stream to provide an appropriate porous structure.

3. 发明专利

JPH10284089A CARBON MATERIAL FOR ELECTRODE OF NONAQUEOUS SOLVENT SECONDARY BATTERY, AND ITS MANUFACTURE, AND NONAQUEOUS SOLVENT SECONDARY BATTERY 失效
公开(公告)号：JPH10284089A
公开(公告)日：1998-10-23
申请号：JP9958097
申请日：1997-04-03
申请人： SONY CORP , KUREHA CHEMICAL IND CO LTD
发明人： YAMADA SHINICHIRO , IMOTO HIROSHI , AZUMA HIDETO , SENOO SUNAO , SEKAI KOUJI , NAGAMINE MASAYUKI , KOMARU TOKUO , SONOBE NAOHIRO , MASUKO JIRO , ISHIKAWA MINORU
IPC分类号： C01B31/02 , H01M4/133 , H01M4/1393 , H01M4/587 , H01M4/96 , H01M10/05 , H01M4/02 , H01M4/58 , H01M10/40
摘要： PROBLEM TO BE SOLVED: To provide carbon material for an electrode of a secondary battery, which can make a nonaqueous solvent secondary battery with high energy density, its manufacturing method and a nonaqueous solvent secondary battery with an negative electrode of the carbon material. SOLUTION: As to carbon material for an electrode of nonaqueous solvent tape secondary battery, its true density found by the butanol method is not more than 46 g/cm , its true value found by the helium method is not less than 1.7 g/cm , its atomic ratio of hydrogen atom to a carbon atom H/C found by elemental analysis is not more than 0.15, its specific surface found by the nitrogen apsorption BET method is not more than 50 m /g and its absorbed quantity of carbon dioxide gas is not less than 10 ml/g, and this carbon material has an appropriate micropore structure formed by carbonizing carbon precursor based on grameneous bamboo genus under a reduced pressure or under distribution of inactive gas at a temperature of 1,000-1,400 deg.C.

4. 发明专利

DE69630741T2 未知
公开(公告)号：DE69630741T2
公开(公告)日：2004-09-30
申请号：DE69630741
申请日：1996-03-06
申请人： SONY CORP
发明人： YAMADA SHINICHIRO , AKASHI HIROYUKI , IMOTO HIROSHI , AZUMA HIDETO , KITAMURA KENICHI , ADACHI MOMOE , SASAKI TERUE , TANAKA KOHICHI
IPC分类号： H01M4/133 , H01M4/587 , H01M4/58

5. 发明公开

EP0687022A4 MATERIAL FOR CATHODE AND METHOD OF ITS MANUFACTURE 失效
标题翻译：材料用于生产阴极和方法
公开(公告)号：EP0687022A4
公开(公告)日：1996-09-11
申请号：EP94903101
申请日：1993-12-28
申请人： SONY CORP
发明人： IMOTO HIROSHI , OMARU ATSUO , AZUMA HIDETO , NISHI YOSHIO , GONNO YOSHIHISA , NAGAMINE MASAYUKI
IPC分类号： H01M4/1393 , H01M4/48 , H01M4/485 , H01M4/58 , H01M4/587 , H01M10/0525 , H01M10/36
CPC分类号： H01M4/587 , H01M4/1393 , H01M4/485 , H01M4/583 , H01M10/0525
摘要： A material for a cathode is made of a carbon material hard to turn to graphite and obtainable by burning a carbon precursor. For this carbon material having the graphitization resistance, the weight % Ps of carbon in the material is smaller than 0.59 or the stacking index SI is smaller than 0.76. This carbon has a structure of stacked layers, which is determined by the diffraction peak due to the (002) plane of the crystal lattice, and the X-ray diffraction spectrum on the side of an angle lower than the diffraction peak among the X-ray diffraction spectrum. The average Nave of the number of stacked layers is smaller than 2.46. Alternatively, letting the burning temperature be T °C, and the half-width of a peak appearing near 1,340 cm-1 in the Raman spectrum be HW, the following condition is satisfied: HW > 138-0.06 T. This carbon material is manufactured by thermally treating a carbon precursor by burining it in an inert gas atmosphere flown at a flow rate of 0.1 ml per minute or more per one gram of the carbon precursor at a temperature of 600 °C or high, or in an atmosphere pressurized at 50 kPa or less at a temperature of 600 °C or high. In this case, the carbon precursor is placed in a layer so that the contact area of the precursor with the atmosphere is 10 cm2 or more.

6. 发明公开

EP0758801A4 NEGATIVE ELECTRODE MATERIAL FOR SECONDARY CELL FOR NONAQUEOUS ELECTROLYTIC SOLUTION, PROCESS FOR THE PRODUCTION THEREOF, AND SECONDARY CELL FOR NONAQUEOUS ELECTROLYTIC SOLUTION USING IT 失效
标题翻译：材料负极的二次电池非水电解质，方法与元件
公开(公告)号：EP0758801A4
公开(公告)日：1998-05-06
申请号：EP96905013
申请日：1996-03-06
申请人： SONY CORP
发明人： YAMADA SHINICHIRO , AKASHI HIROYUKI , IMOTO HIROSHI , AZUMA HIDETO , KITAMURA KENICHI , ADACHI MOMOE , SASAKI TERUE , TANAKA KOHICHI
IPC分类号： H01M4/133 , H01M4/587 , H01M4/58
CPC分类号： H01M4/583 , H01M10/0525
摘要： A negative electrode material for secondary cells for nonaqueous electrolytic solution realizing a high charge-and-discharge capacity and a high charge-and-discharge efficiency. The electrode material contains a product of carbonization of at least one member selected from among coffee bean, tea leaf, canes, corns, fruits, straws and chaffs; or contains a carbonaceous material resulting from a vegetable polymer and containing metal elements, phosphorus and/or sulfur in a total amount of 0.2 to 20 wt.% in terms of elements; or it contains a carbonaceous material having a diffraction peak at an angle of diffraction (i.e., 2υ) of 30 to 32 degrees in the pattern of X-ray powder diffraction (CuKα). Such a negative electrode material is produced by firing at least one member selected from among coffee bean, tea leaf, canes, corns, fruits, straws and chaffs or a mixture obtained by adding at least one member selected from among metal elements, phosphorus and sulfur to a crystalline or fibrous cellulose to effect carbonization. The obtained material is used in producing a secondary cell for a nonaqueous electrolytic solution fitted with a positive electrode made of a lithium double oxide and a negative electrode made of a carbonaceous negative electrode material capable of doping with lithium ions and dedoping as an active material of the negative electrode as the carbonaceous negative electrode material.
摘要翻译：用于实现高充电/放电容量和高的放电效率，其制造寻求材料和用人谋求材料的非水电解液二次电池的方法匿名-wässrige液体电解质的二次电池用负极材料。负电极材料含有选自咖啡豆，茶叶，甘蔗，玉米，水果，谷物秸秆和谷物壳，由植物来源的高分子材料含衍生的碳质材料中选择的至少一种碳质材料总和的金属元素，磷及硫的0.2〜20重量％计算值作为具有30°和32°的2个θ驱动的之间的衍射峰的元件或一个碳质材料; 在X射线（CuKα射线阿尔法）粉末衍射图的衍射角。为生产所说的负极材料，选自咖啡豆，茶叶，甘蔗，玉米，水果，谷物秸秆和谷物壳，或结晶或纤维状纤维素的具有至少一个混合选择的至少一种碳质材料金属元素，磷或硫，下烧结碳化。负极材料用于具有形成锂复合氧化物的正极以及形成能够掺杂和去掺杂锂离子的作为活性负电极材料的碳质负极材料构成的负极的非水电解液二次电池。

7. 发明专利

DE69809365D1 未知
公开(公告)号：DE69809365D1
公开(公告)日：2002-12-19
申请号：DE69809365
申请日：1998-09-28
申请人： SONY CORP
发明人： SENOO TADASHI , AKASHI HIROYUKI , AZUMA HIDETO , SHIBUYA MASHIO , NODA KAZUHIRO , YAMADA SHINICHIRO , YASUDA TOSHIKAZU , SEKAI KOJI
IPC分类号： H01M10/05 , C01B31/02 , C01B31/04 , H01M4/13 , H01M10/40 , H01M4/58
摘要： A gel electrolyte secondary cell in which discharge capacity loss can be suppressed even with the use of a graphitized carbonaceous material of a small particle size as a negative electrode material to assure low impedance, superior cell voltage and load characteristics and high charging/discharging efficiency. To this end, a graphitized carbonaceous material prepared by firing meso-carbon micro-beads is used as a material for a negative electrode 9.

8. 发明专利

CA2022191A1 CARBONACEOUS MATERIAL AND A NON-AQUEOUS ELECTROLYTE CELL USING THE SAME 未知
公开(公告)号：CA2022191A1
公开(公告)日：1991-01-30
申请号：CA2022191
申请日：1990-07-27
申请人： SONY CORP
发明人： AZUMA HIDETO , OMARU ATSUO , NISHI YOSHIO
IPC分类号： C04B35/528 , C10C3/04 , H01M4/02 , H01M4/04 , H01M4/58 , H01M4/587 , H01M10/0525 , H01M10/36

9. 发明专利

CA2591553C NEGATIVE ELECTRODE MATERIAL FOR NON-AQUEOUS LIQUID ELECTROLYTE SECONDARY CELL, METHOD FOR PRODUCING SAME AND NON-AQUEOUS LIQUID ELECTROLYTE SECONDARY CELL EMPLOYING SAME 未知
公开(公告)号：CA2591553C
公开(公告)日：2012-11-27
申请号：CA2591553
申请日：1996-03-06
申请人： SONY CORP
发明人： YAMADA SHINICHIRO , AKASHI HIROYUKI , IMOTO HIROSHI , AZUMA HIDETO , KITAMURA KENICHI , ADACHI MOMOE , SASAKI TERUE , TANAKA KOHICHI
IPC分类号： H01M4/133 , C08L1/00 , H01M4/1393 , H01M4/583
摘要： A negative electrode material for a secondary cell for anon--aqueous liquid electrolyte for realizing a high charging/discharging capacity and a high discharging efficiency, a method for producing such material and a non-aqueous liquid electrolyte secondary cell employing such material. The negative electrode material contains at least one carbonaceous material selected from the group consisting of coffee beans, tea leaves, cane sugar, corns, fruits, straws of cereals and husks of cereals, a carbonaceous material derived from a plant-origin high molecular material containing a sum total of 0.2 to 20 wt% of metal elements, phosphorus and sulphur calculated as elements or a carbonaceous material having a diffraction peak between 30° and 32° of the 2.theta. diffraction angle in the X-ray (CuK.alpha.) powder diffraction pattern. For producing the negative electrode material, at least one carbonaceous material selected from the group consisting of coffee beans, tea leaves, cane sugar, corns, fruits, straws of cereals and husks of cereals, or crystalline or fibrous cellulose admixed with at least one of metal elements, phosphorus or sulphur, is sintered for carbonization. The negative electrode material is used for a non-aqueous liquid electrolyte secondary cell having a positive electrode formed of a lithium compound oxide and a negative electrode formed of a carbonaceous negative electrode material capable of doping and dedoping lithium ions as an active negative electrode material.

10. 发明专利

CA2334386A1 METHOD FOR MANUFACTURING ACTIVE MATERIAL OF POSITIVE PLATE AND METHOD FOR MANUFACTURING NONAQUEOUS ELECTROLYTE SECONDARY CELL 未知
公开(公告)号：CA2334386A1
公开(公告)日：2000-10-12
申请号：CA2334386
申请日：2000-03-28
申请人： SONY CORP
发明人： LI GUOHUA , YAMADA ATSUO , AZUMA HIDETO
IPC分类号： C01B25/37 , H01M4/36 , H01M4/58 , H01M4/04 , H01M10/40
摘要： A method for manufacturing an active material of a positive plate which is doped/dedoped well reversely with/of lithium comprising a mixing step of mixing materials to be used as a synthetic material of a compound whose composition is expressed by a general formula LixMyPO4 (where 0~x

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