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    • 2. 发明申请
    • HERBICIDAL CYCLOHEXANE-1,3-DIONE DERIVATIVES AND THEIR PREPARATION PROCESS
    • 除草环己烷-1,3-二酮衍生物及其制备方法
    • WO1994003443A1
    • 1994-02-17
    • PCT/KR1993000069
    • 1993-08-06
    • KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYRYU, Eung, KulKIM, Kyoung, MahnKIM, Hyoung, RaeSONG, Jong, HwanKIM, Jae, NyoungKIM, Jin, Seog
    • KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
    • C07D307/81
    • C07D307/79A01N43/12
    • The present invention relates to novel cyclohexane-1,3-dione derivatives of formula (I) useful as herbicides and plant-growth regulants, wherein, X is selected from the group consisting of hydrogen, C1-C6 alkyl, C2-C6 alkoxy, halogen, C1-C6 haloalkyl, nitro, cyano, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, sulfamoyl, N-(C1-C6 alkyl)sulfamoyl and N,N-di(C1-C6 alkyl)sulfamoyl group; (X)n represents number of X substituents which may be the same or different on benzene ring, where n is 1, 2 or 3. Also, cyclohexyl moiety, one of the substituents on benzofuran ring, is substituted at 4, 5, 6 or 7 position. The (X)n cannot be filled only with hydrogens and the (X)n can substitute position where cyclohexyl moiety is not substituted; R1 is selected from hydrogen and C1-C4 alkyl group; R2 is selected from C1-C6 alkyl, C2-C6 alkenyl and C2-C6 alkynyl group; R3 is selected from hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkoxyalkyl, C2-C6 alkylthioalkyl, benzyl and C2-C6 haloalkanoyl group; R4 is selected from hydrogen, alkali metal cation, alkaline earth metal cation, C1-C4 alkanoyl, C1-C4 haloalkanoyl and benzoyl group.
    • 本发明涉及可用作除草剂和植物生长调节剂的式(I)的新型环己烷-1,3-二酮衍生物,其中X选自氢,C 1 -C 6烷基,C 2 -C 6烷氧基, 卤素,C 1 -C 6卤代烷基,硝基,氰基,C 1 -C 6烷硫基,C 1 -C 6烷基亚磺酰基,C 1 -C 6烷基磺酰基,氨磺酰基,N-(C 1 -C 6烷基)氨磺酰基和N,N-二(C 1 -C 6烷基) 组; (X)n表示在苯环上可以相同或不同的X取代基的数目,其中n为1,2或3.此外,苯并呋喃环上的取代基之一的环己基部分在4,5,6 或7位。 (X)n不能仅用氢气填充,(X)n可以替代环己基部分未被取代的位置; R1选自氢和C1-C4烷基; R2选自C1-C6烷基,C2-C6烯基和C2-C6炔基; R 3选自氢,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 2 -C 6烯基,C 2 -C 6卤代烯基,C 2 -C 6烷氧基烷基,C 2 -C 6烷硫基烷基,苄基和C 2 -C 6卤代烷酰基; R4选自氢,碱金属阳离子,碱土金属阳离子,C1-C4烷酰基,C1-C4卤代烷酰基和苯甲酰基。
    • 5. 发明申请
    • BENZENESULFONYLUREA DERIVATIVES
    • 苯并呋喃衍生物
    • WO1992015568A1
    • 1992-09-17
    • PCT/KR1992000007
    • 1992-03-09
    • KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYKIM, Dae-WhangKO, Young, KwanKIM, Jin-SeogKU, Dong, Whan
    • KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
    • C07D239/42
    • C07D521/00A01N47/36C07C311/29
    • The present invention relates to novel benzenesulfonylurea derivatives, having a herbicidal activity, which is described in the structure of general formula (I), wherein R is H, C1-C3 alkyl, C1-C3 haloalkyl, halogen, CN, NO2, C1-C3 alkoxy, C1-C3 haloalkoxy, SO2NR R , C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, SCH2F, NH2, NHCH3, N(Me)2, C1-C2 alkyl substituted with C1-C2 alkoxy, C1-C2 haloalkoxy, SH, SCH3, CN or OH, or CO2R ; and then R is H, C1-C4 alkyl, C2-C3 cyanoalkyl, methoxy or ethoxy; R is H, C1-C4 alkyl, C3-C4 alkenyl, or when taken together connecting R and R , -(CH2)3-, -(CH2)4-, -(CH2)5- or CH2CH2OCH2CH2-, may be formed; R is C1-C4 alkyl, C3-C4 alkenyl, C3-C4 alkynyl, C1-C4 alkyl substituted with 1 SIMILAR 3 halogens or cyano groups, C5-C6 cycloalkyl, C3-C7 cycloalkylalkyl or C2-C4 alkoxyalkyl; R is C1-C6 alkyl substituted with 1 SIMILAR 3 halogens; R is H or CH3; W is O or S; A is a heterocyclic ring defined in the specification; and these may be an agriculturally suitable salt.
    • 本发明涉及具有除草活性的新型苯磺酰脲衍生物,其在通式(I)的结构中描述,其中R 1是H,C 1 -C 3烷基,C 1 -C 3卤代烷基,卤素,CN,NO 2 ,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基,SO 2 NR R 1,C 1 -C 3烷硫基,C 1 -C 3烷基亚磺酰基,C 1 -C 3烷基磺酰基,SCH 2 F,NH 2,NHCH 3,N(Me) 被C 1 -C 2烷氧基,C 1 -C 2卤代烷氧基,SH,SCH 3,CN或OH或CO 2 R III取代的烷基; 然后R 1是H,C 1 -C 4烷基,C 2 -C 3氰基烷基,甲氧基或乙氧基; 或者当R 1和R 2连接在一起时, - (CH 2)3 - , - (CH 2)4 - , - (CH 2) 5-或CH 2 CH 2 OCH 2 CH 2 - 可以形成; R III是C 1 -C 4烷基,C 3 -C 4烯基,C 3 -C 4炔基,被1个3个卤素或氰基取代的C 1 -C 4烷基,C 5 -C 6环烷基,C 3 -C 7环烷基烷基或C 2 -C 4烷氧基烷基; R 2是被1个3个卤素取代的C 1 -C 6烷基; R 3是H或CH 3; W为O或S; A是说明书中定义的杂环; 这些可以是农业上合适的盐。