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    • 6. 发明专利
    • POLYTHIAZYL FILM
    • JPS59232902A
    • 1984-12-27
    • JP10496283
    • 1983-06-14
    • KOGYO GIJUTSUIN
    • IKEDA YUKIHIROOZAKI MASARUARAKAWA TATSUMI
    • H01B5/14C01B21/086C08J5/18C23C14/04
    • PURPOSE:To obtain a polythiazyl film consisting of polythiazyl crystals whose fibrillation direction coincides with the direction of the film thickness and having electric conductivity and electric anisotropy by vapor-depositing S2N2 on a substrate in high vacuum to form a thin film, and subjecting the film to solid phase polymn. in vacuum. CONSTITUTION:S2N2 is vapor-deposited on a flat substrate cooled to a low temp. in high vacuum to form a thin film, and this film is subjected to solid phase polymn. in vacuum at room temp. or under heating to obtain a polythiazyl film consisting of fibrils grown in a direction perpendicular to the substrate on the whole surface of the substrate. The whole surface of the polythiazyl film is made of an aggregate of fibrillar fine crystals having high orientability and crystallizability, and the fibrillation direction of the fine crystals coincides with the direction of the film thickness. The polythiazyl film has electric conductivity and electric anisotropy in the direction of the film thickness, and it is useful to form a device, an element or the like as an electrically conductive anisotropic film of a large area.