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    • 7. 发明专利
    • INSULATING FILM FOR GRAIN ORIENTED SILICON STEEL SHEET, AND ITS FORMATION
    • JPH10152780A
    • 1998-06-09
    • JP31038496
    • 1996-11-21
    • KAWASAKI STEEL CO
    • WATANABE MAKOTOKAMI TSUTOMUSATO KEIJI
    • C23C22/00C21D9/46
    • PROBLEM TO BE SOLVED: To obtain a superior film without deteriorating magnetic properties by partially infiltrating a film into the inner part of ferrite to form anchor parts and regulating the area ratio of the remaining parts of the film, at the time when the film is peeled off at the bending test of a steel sheet, to a value in a specific range. SOLUTION: This film 1 partially infiltrates into the inner part of ferrite 2 and forms anchor parts 3, and the area ratio of remaining parts 4 of the above film is 8-53%. A steel, containing 2-4wt.% Si, is hot-rolled and cold-rolled and finished to final sheet thickness and then subjected to primary recrystallization annealing, and, after the application of an MgO-type separation agent at annealing, final finish annealing is performed, by which an insulating film is formed on the surface of ferrite of the steel sheet. At this time, the thickness of a lamellar silica-enriched layer in the internally oxidized layer formed at primary recrystallization annealing is regulated to 0.2-3.6μm, and an MgO in which the amount of moisture introduced as the result of being formed into slurry state becomes 1.0-3.9% is used as a separation agent at annealing, and further, atmospheric oxidizing property P(H2 O)/P(H2 ) at 700- to 2.0×10 .