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    • 3. 发明公开
    • ULTRAVIOLET-SCREENING COMPOSITE PARTICULATE AND PROCESS FOR THE PRODUCTION THEREOF
    • 粒状保护组合免受紫外线和方法及其
    • EP0882673A4
    • 2000-03-15
    • EP97902710
    • 1997-02-17
    • KAO CORP
    • OSHIMA KENTAROKOZAKI SHUNJIIMAIZUMI YOSHINOBUMIYAKE TOSHIOTSUTO KEIICHI
    • A61K8/04A61K8/11A61K8/19A61K8/25A61K8/26A61K8/27A61Q17/04C01B33/18A61K7/00A61K7/42C01B33/12C01F7/02
    • A61K8/26A61K8/0283A61K8/11A61K8/19A61K8/25A61K8/27A61K2800/413A61Q17/04
    • An ultraviolet-screening composite particulate transparent in the visible region, characterized in that it is constituted of a matrix particle formed by the agglomeration of primary particles having sizes of 0.001 to 0.3 νm and retaining their shapes as such and daughter particles having a mean diameter of 0.001 to 0.1 νm and dispersed and immobilized in the matrix particle, the daughter particles having a smaller band gap energy than that of the primary particles constituting the matrix particle and exhibiting an ultraviolet-absorbing power, that it has a structure wherein the surface is coated with at least one silicone selected from the group consisting of modified silicones, reactive silicones and silicone-modified copolymers, and that it is substantially free from catalytic activity. Thus, the composite particulate contains ultrafine particles having an ultraviolet-screening power and is surface-coated with a silicone, so that it is substantially free from catalytic activity and can efficiently screen ultraviolet rays while having a high transparency in the visible region.
    • 紫外线屏蔽在可见光区域具有透明度复合微粒,其特征在于,其具有:从0.001〜0.3微米的平均粒径的一次颗粒的聚集体的基质颗粒,而初级颗粒保持其形状的聚集体形成; 和具有上的0.001至0.1微米的平均粒径子粒子,分散的子粒子在和支承在基体颗粒,worin子颗粒具有比构成母粒的微粒小的带隙能量,并且能够 吸收紫外光,并worin复合微粒的表面涂覆有选自改性聚硅氧烷,反应性聚硅氧烷和聚硅氧烷改性共聚物中的一种或多种硅酮,和worin紫外线遮蔽性复合微粒实质上不具有催化 活动。 通过形成复合微粒包含具有紫外线遮蔽能力的超微粒,本发明的复合微粒实质上不具有催化活性,高的透明度,在可见光区域,并在紫外光区的高遮蔽性。
    • 7. 发明专利
    • DE4228487A1
    • 1993-03-04
    • DE4228487
    • 1992-08-27
    • KAO CORP
    • KIMURA HIROSHITSUTO KEIICHI
    • B01J23/54B01J23/63B01J23/644C07C45/38C07C45/39C07C51/245
    • A compound having a carbonyl group and/or a carboxyl group is produced by catalytically oxidizing a polyhydric alcohol having at least one primary hydroxyl group and at least one secondary hydroxyl group in the presence of a supported catalyst comprising at least one catalytic component selected from among the following components (I) to (IV) loaded on a support: (I) A first catalytic component chosen from at least one element selected from group A consisting of platinum, palladium, rhodium, ruthenium, rhenium, gold, silver and copper, (II) a combination of the first catalytic component with a second catalytic component chosen from at least one element selected from group B consisting of tin, lead, antimony, bismuth, selenium and tellurium, (III) a combination of the first catalytic component with a third catalytic component chosen from at least one element selected from group C consisting of rare earth elements, and (IV) a combination of the first catalytic component with the second catalytic component and the third catalytic component.