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    • 3. 发明申请
    • METHOD OF RECOVERING NUCLEAR FUEL MATERIAL
    • 回收核燃料材料的方法
    • US20160225473A1
    • 2016-08-04
    • US13899978
    • 2013-05-22
    • Kabushiki Kaisha Toshiba
    • Yuya TAKAHASHIKoji MizuguchiReiko FujitaHitoshi NakamuraShohei KanamuraNaoki KishimotoYoshikazu MatsubayashiTakashi Oomori
    • G21C19/48C25C7/00C25C3/34
    • C25C7/005C25C3/34G21C19/46Y02W30/883
    • According to an embodiment, a nuclear fuel material recovery method of recovering a nuclear fuel material containing thorium metal by reprocessing an oxide of a nuclear fuel material containing thorium oxide in a spent fuel is provided. The method has: a first electrolytic reduction step of electrolytically reducing thorium oxide in a first molten salt of alkaline-earth metal halide; a first reduction product washing step of washing a reduction product; and a main electrolytic separation step of separating the reduction product. The first molten salt further contains alkali metal halide, and contains at least one out of a group consisting of calcium chloride, magnesium chloride, calcium fluoride and magnesium fluoride. The method may further has a second electrolytic reduction step of electrolytically reducing uranium oxide, plutonium oxide, and minor actinoid oxide in a second molten salt of alkali metal halide.
    • 根据一个实施方案,提供了一种通过在废燃料中再处理含有氧化钍的核燃料材料的氧化物来回收含有钍金属的核燃料材料的核燃料材料回收方法。 该方法具有:在碱土金属卤化物的第一熔盐中电解还原氧化钍的第一电解还原步骤; 洗涤还原产物的第一还原产物洗涤步骤; 以及分离还原产物的主要电解分离步骤。 第一熔融盐还含有碱金属卤化物,并含有氯化钙,氯化镁,氟化钙和氟化镁中的至少一种。 该方法还可以具有在碱金属卤化物的第二熔融盐中电解还原铀氧化物,钚氧化物和次要锕系氧化物的第二电解还原步骤。
    • 7. 发明授权
    • Method of separating and recovering metals and system for separating and recovering metals
    • 分离回收金属的方法和金属分离回收系统
    • US09353452B2
    • 2016-05-31
    • US14323066
    • 2014-07-03
    • Kabushiki Kaisha Toshiba
    • Yuya TakahashiHitoshi NakamuraShohei KanamuraAkira YamadaKoji MizuguchiTakashi Oomori
    • C25C3/00C25C3/26C25C3/34C25C7/06
    • C25C7/06C25C3/26C25C3/34
    • According to one embodiment, a method of separating and recovering metals whereby a mixture containing at least a first metal and a second metal, the second metal having a higher standard electrode potential than that of the first metal, is connected to an anode in a molten salt, and the first metal and the second metal are precipitated on a cathode in the molten salt by electrolysis, the method of separating and recovering metals comprising: a detection step of detecting a concentration change in each of a first metal ion and a second metal ion in the molten salt by a concentration change detection unit; a first electrolysis step of electrolyzing the first metal; a first recovery step of recovering a precipitated substance according to a detection in which a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step; a second electrolysis step of electrolyzing the second metal; and a second recovery step of recovering a precipitated substance subsequent to the first recovery step.
    • 根据一个实施方案,一种分离和回收金属的方法,其中包含至少第一金属和第二金属的混合物,具有比第一金属的标准电极电位更高的标准电极电位的第二金属与熔融的 盐,第一金属和第二金属通过电解沉淀在熔融盐中的阴极上,金属的分离和回收方法包括:检测第一金属离子和第二金属中的每一种的浓度变化的检测步骤 通过浓度变化检测单元在熔融盐中离子; 电解第一金属的第一电解步骤; 在检测步骤中检测出根据在浓度变化检测单元中预先确定的第一金属离子的浓度降低的检测来回收沉淀物质的第一回收步骤; 电解第二金属的第二电解步骤; 以及在第一回收步骤之后回收沉淀物质的第二回收步骤。
    • 9. 发明申请
    • METHOD OF SEPARATING AND RECOVERING METALS AND SYSTEM FOR SEPARATING AND RECOVERING METALS
    • 分离和回收金属的方法和用于分离和回收金属的系统
    • US20150008136A1
    • 2015-01-08
    • US14323066
    • 2014-07-03
    • Kabushiki Kaisha Toshiba
    • Yuya TAKAHASHIHitoshi NakamuraShohei KanamuraAkira YamadaKoji MizuguchiTakashi Oomori
    • C25C7/06C25C3/26
    • C25C7/06C25C3/26C25C3/34
    • According to one embodiment, a method of separating and recovering metals whereby a mixture containing at least a first metal and a second metal, the second metal having a higher standard electrode potential than that of the first metal, is connected to an anode in a molten salt, and the first metal and the second metal are precipitated on a cathode in the molten salt by electrolysis, the method of separating and recovering metals comprising: a detection step of detecting a concentration change in each of a first metal ion and a second metal ion in the molten salt by a concentration change detection unit; a first electrolysis step of electrolyzing the first metal; a first recovery step of recovering a precipitated substance according to a detection in which a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step; a second electrolysis step of electrolyzing the second metal; and a second recovery step of recovering a precipitated substance subsequent to the first recovery step.
    • 根据一个实施方案,一种分离和回收金属的方法,其中包含至少第一金属和第二金属的混合物,具有比第一金属的标准电极电位更高的标准电极电位的第二金属与熔融的 盐,第一金属和第二金属通过电解沉淀在熔融盐中的阴极上,金属的分离和回收方法包括:检测第一金属离子和第二金属中的每一种的浓度变化的检测步骤 通过浓度变化检测单元在熔融盐中离子; 电解第一金属的第一电解步骤; 在检测步骤中检测出根据在浓度变化检测单元中预先确定的第一金属离子的浓度降低的检测来回收沉淀物质的第一回收步骤; 电解第二金属的第二电解步骤; 以及在第一回收步骤之后回收沉淀物质的第二回收步骤。