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    • 1. 发明申请
    • METHOD FOR FORMING MULTILAYER COATING FILM
    • 形成多层涂膜的方法
    • US20100129662A1
    • 2010-05-27
    • US12452808
    • 2008-07-18
    • Junya OgawaKoji KanagawaShuichi NakaharaTadashi IidaHiroyuki NaganoYoshizumi MatsunoYasushi Nakao
    • Junya OgawaKoji KanagawaShuichi NakaharaTadashi IidaHiroyuki NaganoYoshizumi MatsunoYasushi Nakao
    • B05D3/02B32B27/38
    • B05D7/574B05D3/0254B05D7/572B05D2202/10Y10T428/31511
    • This invention provides a method for forming multilayer coating film excelling in smoothness and distinctness of image, by 3-coat-1-bake system in which a step of applying onto a coating object a water-based intermediate paint (X) to form an intermediate coating film; a step of adjusting the solid content of the intermediate coating film to 70-100 mass %; a step of applying onto the intermediate coating film a water-based base coating paint (Y) containing 30-55 mass parts of alcoholic solvent having a boiling point of 170-250° C., to form a base coating film; a step of adjusting the solid content of the base coating film to 70-100 mass %; a step of applying a clear paint (Z) comprising 40-60 mass parts of carboxyl-containing compound and 60-40 mass parts of polyepoxide onto the base coating film to form a clear coating film; and heating the intermediate coating film, base coating film and clear coating film at 100-120° C. for 3-10 minutes and thereafter further heating them at 130-160° C. for 10-30 minutes; are successively carried out.
    • 本发明提供了一种形成多层涂膜的方法,其通过3-涂层1烘烤系统的平滑度和清晰度,其中涂布在涂料上的步骤为水性中间涂料(X)以形成中间体 涂膜; 将中间涂膜的固体成分调整为70〜100质量%的工序; 向中间涂膜施加含有30-55质量份沸点为170-250℃的醇溶剂的水性底涂层(Y)的步骤,以形成基底涂膜; 调整基底涂膜的固体成分为70〜100质量%的工序。 将包含40-60质量份含羧基化合物和60-40质量份聚环氧化物的透明涂料(Z)施加到基底涂膜上以形成透明涂膜的步骤; 并在100-120℃下加热中间涂膜,底涂层和透明涂膜3-10分钟,然后在130-160℃下进一步加热10-30分钟; 相继进行。
    • 2. 发明授权
    • Method for forming multilayer coating film
    • 多层涂膜形成方法
    • US08906465B2
    • 2014-12-09
    • US12452808
    • 2008-07-18
    • Junya OgawaKoji KanagawaShuichi NakaharaTadashi IidaHiroyuki NaganoYoshizumi MatsunoYasushi Nakao
    • Junya OgawaKoji KanagawaShuichi NakaharaTadashi IidaHiroyuki NaganoYoshizumi MatsunoYasushi Nakao
    • B05D5/00B05D3/02B05D7/00B05D1/02
    • B05D7/574B05D3/0254B05D7/572B05D2202/10Y10T428/31511
    • This invention provides a method for forming multilayer coating film excelling in smoothness and distinctness of image, by 3-coat-1-bake system in which a step of applying onto a coating object a water-based intermediate paint (X) to form an intermediate coating film; a step of adjusting the solid content of the intermediate coating film to 70-100 mass %; a step of applying onto the intermediate coating film a water-based base coating paint (Y) containing 30-55 mass parts of alcoholic solvent having a boiling point of 170-250° C., to form a base coating film; a step of adjusting the solid content of the base coating film to 70-100 mass %; a step of applying a clear paint (Z) comprising 40-60 mass parts of carboxyl-containing compound and 60-40 mass parts of polyepoxide onto the base coating film to form a clear coating film; and heating the intermediate coating film, base coating film and clear coating film at 100-120° C. for 3-10 minutes and thereafter further heating them at 130-160° C. for 10-30 minutes; are successively carried out.
    • 本发明提供了一种形成多层涂膜的方法,其通过3-涂层1烘烤系统的平滑度和清晰度,其中涂布在涂料上的步骤为水性中间涂料(X)以形成中间体 涂膜; 将中间涂膜的固体成分调整为70〜100质量%的工序; 向中间涂膜施加含有30-55质量份沸点为170-250℃的醇溶剂的水性底涂层(Y)的步骤,以形成基底涂膜; 调整基底涂膜的固体成分为70〜100质量%的工序。 将包含40-60质量份含羧基化合物和60-40质量份聚环氧化物的透明涂料(Z)施加到基底涂膜上以形成透明涂膜的步骤; 并在100-120℃下加热中间涂膜,底涂层和透明涂膜3-10分钟,然后在130-160℃下进一步加热10-30分钟; 相继进行。
    • 7. 发明授权
    • Method for forming coating film on plastic substrate
    • 在塑料基材上形成涂膜的方法
    • US07150899B2
    • 2006-12-19
    • US10694057
    • 2003-10-28
    • Hiroyuki OnoyamaYasuyuki KataokaShuichi NakaharaYoshizumi Matsuno
    • Hiroyuki OnoyamaYasuyuki KataokaShuichi NakaharaYoshizumi Matsuno
    • B05D1/04B05D1/38
    • B05D7/572B05D1/045B05D2201/02Y02P20/582
    • The present invention provides a method for forming a coating film on a plastic substrate which comprises: (1) coating the plastic substrate with an aqueous white primer (A) having a water content of 15 to 48 wt. % to form a coating film having an L* value of 80 or more, (2) heating the coating film of the primer (A) to adjust the water content of the film to 1 to 10 wt. % and the surface electrical resistivity value of the film to less than 109 Ω/square, (3) electrostatically coating the coating film of the primer (A) with a thermosetting clear colored coating composition (B), (4) electrostatically coating the uncured coating film of the coating composition (B) with a thermosetting clear coating composition (C), and (5) baking the three-layer coating film to obtain a cured multilayer coating film having an N value of 8.5 or more.
    • 本发明提供一种在塑料基材上形成涂膜的方法,该方法包括:(1)用水含量为15〜48重量%的水性白底漆(A)涂布塑料基材。 %以形成L *值为80以上的涂膜,(2)加热底漆(A)的涂膜以将膜的水分调节至1〜10重量%。 %,膜的表面电阻率值小于10欧/平方,(3)用热固性透明有色涂料组合物(B)静电涂布底漆(A)的涂膜, ,(4)用热固性透明涂料组合物(C)将涂料组合物(B)的未固化涂膜静电涂覆,(5)烘烤三层涂膜,得到N值为 8.5以上。
    • 10. 发明授权
    • Pigment dispersing resins
    • 颜料分散树脂
    • US06743848B2
    • 2004-06-01
    • US10223626
    • 2002-08-20
    • Shuichi NakaharaYoshiyuki Yukawa
    • Shuichi NakaharaYoshiyuki Yukawa
    • C08L5100
    • C08L51/003C08F265/04C08F290/04C08F290/046C09B67/009C09D7/45C09D17/002C09D151/003Y10T428/31511Y10T428/31938C08L2666/02
    • This invention provides a pigment dispersing resin having a weight-average molecular weight within a range of 1,000-150,000, which is obtained by copolymerizing a monomeric mixture comprising (a) a macromonomer obtained by polymerizing at least one ethylenically unsaturated monomer in the presence of a metal complex as a catalytic chain transfer agent, or an addition cleavage-type chain transfer agent and if necessary a radical polymerization initiator, which macromonomer having a resin acid value less than 50 mgKOH/g, and (b) at least one copolymerizable unsaturated monomer, wherein at least one monomer among the ethylenically unsaturated monomer(s) constituting said macromonomer (a) and the copolymerizable unsaturated monomer(s) (b) has a functional group selected from substituted or unsubstituted amino group, quaternary ammonium salt group, sulfonic group, phosphoric group and carboxyl group.
    • 本发明提供一种颜料分散树脂,其重均分子量在1,000-150,000范围内,该颜料分散树脂通过共聚单体混合物获得,所述单体混合物包含(a)通过在至少一种烯键式不饱和单体的存在下聚合至少一种烯属不饱和单体获得的大分子单体 金属络合物作为催化链转移剂,或加成裂解型链转移剂,如果需要,具有树脂酸值小于50mgKOH / g的大分子单体的自由基聚合引发剂,和(b)至少一种可共聚的不饱和单体 其中构成所述大分子单体(a)的烯键式不饱和单体和所述可共聚不饱和单体(b)中的至少一种单体具有选自取代或未取代的氨基,季铵盐基,磺酸基的官能团 ,磷酸基和羧基。