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    • 2. 发明授权
    • Ethylidene norbornyl group-containing polysiloxane
    • 含亚乙基降冰片基的聚硅氧烷
    • US4640968A
    • 1987-02-03
    • US787232
    • 1985-10-15
    • Junichiro WatanabeYuichi FunahashiKazuo SugiuraHironori Matsumoto
    • Junichiro WatanabeYuichi FunahashiKazuo SugiuraHironori Matsumoto
    • C08G77/00C08G77/04C08G77/20C08G77/22C08G77/38
    • C08G77/20C08G77/04C08G77/38
    • A polysiloxane containing an ethylidene norbornyl group possesses a terminal group represented by the formula: ##STR1## wherein R.sup.1 stands for a monovalent hydrocarbon group, a hydroxyl group, an alkoxy group, or at least one of the hydrocarbon groups represented by Y, and each R.sup.2 stands for the same or different groups selected from the class consisting of hydrogen, monovalent hydrocarbon groups, and a group represented by R.sup.1 wherein R.sup.1 has the same meaning as defined above, and being substantially in the form of a straight chain, 0 to 100 mol %, providing that 100 mol % is excluded where neither of the R.sup.1 's in the terminal groups is a hydrocarbon group represented by Y of the component units being represented by the formula: ##STR2## wherein each R.sup.3 's stand for the same or different groups selected from the class consisting of hydrogen and monovalent hydrocarbon groups and 100 to 0 mol %, providing that 0 mol % is excluded where neither of the R.sup.1 's in the terminal groups is a hydrocarbon group represented by Y of the component units being represented by the formula: ##STR3## wherein R.sup.4 stands for a monovalent hydrocarbon group of 1 to 8 carbon atoms and Y stands for ##STR4## so as to bond a silicon atom to the neighboring silicon atom through an oxygen atom.
    • 含有亚乙基降冰片基的聚硅氧烷具有由下式表示的末端基团:其中R1表示一价烃基,羟基,烷氧基或由Y表示的至少一个烃基, R2表示选自氢,一价烃基和由R1表示的基团的相同或不同的基团,其中R1具有与上述相同的含义,并且基本上为直链的形式,0至100 mol%,条件是排除了100mol%,其中末端基团中的R1都不是由下式表示的组分单元的Y表示的烃基:其中每个R3代表相同或不同的基团选择 从由氢和一价烃基组成的类和100至0mol%的范围内,假定不包括末端基团中的R 1不是氢键的0mol% 由以下式表示的组分单元的Y表示的n基团:其中R4表示1至8个碳原子的一价烃基,Y表示“IMAGE”或“IMAGE”,以键合硅原子 通过氧原子与相邻的硅原子反应。