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    • 2. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4436808A
    • 1984-03-13
    • US469660
    • 1983-02-25
    • Morio YagiharaTsumoru HiranoKeiji Mihayashi
    • Morio YagiharaTsumoru HiranoKeiji Mihayashi
    • G03C7/38C08F20/00C08F20/34C08F20/38G03C7/327G03C7/384G03C7/16G03C5/24
    • G03C7/3275
    • A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a homopolymer or copolymer having a repeating unit derived from a monomer coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents hydrogen, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; R.sub.2 and R.sub.3, which may be the same or different, each represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain, an unsubstituted or substituted arylene group or an unsubstituted or substituted aralkylene group; X represents --CONH-- or --COO--; Y represents --O--, --S--, --SO--, --SO.sub.2 --, --CONH-- or --COO--; Ar represents an unsubstituted or substituted phenyl group; R.sub.4 represents an unsubstituted or substituted anilino group, an unsubstituted or substituted acylamino group or an unsubstituted or substituted ureido group; l represents 0 or 1; m represents 0 or 1; and n represents 0 or 1.The magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs, and the silver halide color photographic light-sensitive material containing the magenta color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a stable magenta image having improved graininess and sharpness and a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
    • 一种卤化银彩色照相感光材料,其包括其上具有卤化银乳剂层的载体,所述卤化银乳剂层含有品红色图像形成聚合物偶联剂胶乳,其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料, 是具有源自由以下通式(I)表示的单体成色剂的重复单元的均聚物或共聚物:其中R 1表示氢,含有1至4个碳原子的低级烷基或氯原子 ; R 2和R 3可以相同或不同,表示可以是直链或支链的未取代或取代的亚烷基,未取代或取代的亚芳基或未取代或取代的芳亚烷基; X表示-CONH-或-COO-; Y表示-O - , - S - , - SO-,-SO 2 - , - CONH-或-COO-; Ar表示未取代或取代的苯基; R4表示未取代或取代的苯胺基,未取代或取代的酰氨基或未取代或取代的脲基; l表示0或1; m表示0或1; 并且n表示0或1.品红色成像聚合物成色剂胶乳具有良好的成色性能,能够以高产率形成染料并且不形成不期望的污渍和雾,并且卤化银彩色照相感光 含有品红色成像聚合物偶联剂胶乳的材料具有良好的膜强度和降低的层厚度,并且提供了具有改善的颗粒度和清晰度以及对光,热和湿度的良好牢度的稳定的品红色图像。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 3. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4409320A
    • 1983-10-11
    • US377271
    • 1982-05-10
    • Morio YagiharaTsumoru HiranoKeiji MihayashiTakashi Ozawa
    • Morio YagiharaTsumoru HiranoKeiji MihayashiTakashi Ozawa
    • G03C7/38C07D231/52C08F20/00C08F20/34C08F20/52C08F20/58C08F20/60C09B26/02G03C7/327G03C7/00G03C1/40
    • G03C7/327C07D231/52C08F20/60
    • A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by the following general formula (I) ##STR1## wherein R represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; and X represents a halogen atom, an acylamino group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a cyano group or an alkoxycarbonyl group and which is present at the 4-position or 5-position of the phenyl group. The magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs, and the silver halide color photographic light-sensitive material containing the magenta color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a stable magenta image having an improved sharpness and a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
    • 一种卤化银彩色照相感光材料,其包括其上具有卤化银乳剂层的载体,所述卤化银乳剂层含有品红色图像形成聚合物偶联剂胶乳,其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料, 是具有衍生自由下列通式(I)表示的单体的重复单元的聚合物或共聚物其中R表示氢原子,含有1至4个碳原子的低级烷基或氯原子 ; X表示卤素原子,酰氨基,氨基甲酰基,亚磺酰氨基,氨磺酰基,氰基或烷氧基羰基,其存在于苯基的4-位或5-位上。 品红色成像聚合物成色剂胶乳具有良好的成色性能,能够以高产率形成染料并且不形成不期望的污渍和雾,并且含有品红色图像形成的卤化银彩色照相感光材料 聚合物成色剂胶乳具有良好的膜强度和降低的层厚度,并提供稳定的品红色图像,其具有改善的清晰度和对光,热和湿度的良好牢度。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 4. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4367282A
    • 1983-01-04
    • US328151
    • 1981-12-07
    • Morio YagiharaTsumoru HiranoKeiji Mihayashi
    • Morio YagiharaTsumoru HiranoKeiji Mihayashi
    • G03C7/38C07D231/52C07D521/00C08F20/36C08F20/60C09B26/02G03C7/327G03C7/00G03C1/40
    • C07D231/12C07D231/52C07D233/56C07D249/08C08F20/36C08F20/60G03C7/3275
    • A silver halide color photographic light-sensitive material is described comprising a support having thereon a silver halide emulsion layer containing a 2-equivalent magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by formula (I) ##STR1## wherein R represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; X represents --CONH--, --NH--, --NHCONH-- or --NHCOO--; Y represents --CONH-- or --COO--; A represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain or an unsubstituted or substituted phenylene group; Ar represents an unsubstituted or substituted phenyl group; Za, Zb, Zc and Zd can each represent a methine group, a substituted methine group or -N.dbd.; m represents 0 or 1; and n represents 0 or 1.The 2-equivalent magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs and provides a stable magenta image having a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
    • 描述了一种卤化银彩色照相感光材料,其包括其上具有含有2-当量的品红色成像聚合物成色剂胶乳的卤化银乳剂层的载体,其能够在与芳族原料的氧化产物偶联时形成染料 胺显影剂,其是具有衍生自由式(I)表示的单体的重复单元的聚合物或共聚物其中R表示氢原子,含有1至4个碳原子的低级烷基或 氯原子 X表示-CONH-,-NH-,-NHCONH-或-NHCOO-; Y表示-CONH-或-COO-; A表示未取代或取代的亚烷基,其可以是直链或支链或未取代或取代的亚苯基; Ar表示未取代或取代的苯基; Za,Zb,Zc和Zd各自表示次甲基,取代的次甲基或-N =; m表示0或1; 并且n表示0或1. 2-等价的品红色成像聚合物成色胶乳具有良好的成色性能,能够以高产率形成染料,并且不形成不期望的污渍和雾,并提供稳定的品红色图像,其具有 耐光,耐热,耐湿性好。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 5. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4444870A
    • 1984-04-24
    • US415295
    • 1982-09-07
    • Tsumoru HiranoKeiji MihayashiMorio Yagihara
    • Tsumoru HiranoKeiji MihayashiMorio Yagihara
    • G03C7/26G03C7/32G03C7/327G03C7/16
    • G03C7/3275Y10S525/902
    • A silver halide color photographic light-sensitive material comprising a support having thereon a layer containing at least one copolymer coupler latex having a layered structure capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent. The polymer coupler latex having a layered structure has an exceptionally good color forming property and is capable of forming a dye with a high yield and without the formation of undesired stains and fogs. The silver halide color photographic light-sensitive material containing the polymer coupler latex has good film strength and a reduced layer thickness and provides a color image having an improved sharpness. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.
    • 一种卤化银彩色摄影感光材料,其包括其上具有包含至少一种具有能与芳族伯胺显影剂的氧化产物偶合形成染料的层状结构的共聚物成色胶乳的层的载体。 具有层状结构的聚合物成色剂胶乳具有非常好的成色性,能够以高产率形成染料,并且不形成不期望的污渍和雾。 含有聚合物偶联胶乳的卤化银彩色照相感光材料具有良好的膜强度和降低的层厚度,并提供了具有改善的清晰度的彩色图像。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 9. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5541050A
    • 1996-07-30
    • US288877
    • 1994-08-10
    • Keiji MihayashiMikio Ihama
    • Keiji MihayashiMikio Ihama
    • G03C1/09G03C7/30G03C7/305G03C7/388G03C1/08G03C1/06G03C7/26G03C7/32
    • G03C7/3003G03C7/3022Y10S430/156Y10S430/158
    • A silver halide color photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer formed on a support containing light-sensitive silver halide grains which have been chemically sensitized by at least one of a selenium sensitizer, a gold sensitizer and a sulfur sensitizer and at least one of the layers of the material contains a compound represented by the following formula (I) and/or a compound represented by the following formula (II) in which A is a coupler residue or a redox group, L.sub.1 and L.sub.3 are divalent timing groups, L.sub.2 is a timing group with a valency of 3 or more, PUG is a photographically useful group, j and n are integers, each of 0 to 2, m is 1 or 2, s is 2 or a greater integer obtained by subtracting 1 from the valence of L.sub.2, L.sub.4 is --OCO-- group, and L.sub.5 is a group which releases PUG by electron transfer along a conjugated system.Formula (I)A'--(L.sub.1).sub.j --(L.sub.2).sub.m --[(L.sub.3).sub.n --PUG].sub.8Formula (II)A--L.sub.4 --L.sub.5 --PUG
    • 一种卤化银彩色照相感光材料,其具有形成在含有感光卤化银颗粒的载体上的至少一种感光卤化银乳剂层,该感光卤化银颗粒已通过硒增感剂,金增感剂和 硫化物增感剂和材料的至少一层包含由下式(I)表示的化合物和/或下式(II)表示的化合物,其中A是成色剂残基或氧化还原基团,L1和 L3是二价定时基团,L2是3价以上的定时基团,PUG是摄影有用的基团,j和n是整数,各自为0〜2,m为1或2,s为2以上 通过从L2的价数减去1得到的整数,L4是-OCO-基,L5是沿着共轭体系通过电子转移释放PUG的基团。 式(I)A' - (L1)j-(L2)m - [(L3)n-PUG] 8式(II)A-L4-L5-PUG