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1. 发明申请

US20080308455A1 Catalyst and a Method for Cracking Hydrocarbons 审中-公开
标题翻译：催化剂和烃类裂化方法
公开(公告)号：US20080308455A1
公开(公告)日：2008-12-18
申请号：US11813056
申请日：2005-12-28
申请人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
发明人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂化烃的方法。催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂， ⅦB族和2〜25wt％P添加剂，其中金属添加剂由金属氧化物计算，P添加剂通过P2O5计算。使用该催化剂裂化烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

2. 发明授权

US08658024B2 Catalyst and a method for cracking hydrocarbons 有权
标题翻译：催化剂和裂化烃的方法
公开(公告)号：US08658024B2
公开(公告)日：2014-02-25
申请号：US13565145
申请日：2012-08-02
申请人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
发明人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jiushun Zhang , Beiyan Chen , Haitao Song
IPC分类号： C10G11/05 , C10G11/18 , B01J29/46
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂化烃的方法。催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂， ⅦB族和2〜25wt％P添加剂，其中金属添加剂由金属氧化物计算，P添加剂通过P2O5计算。使用该催化剂裂化烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

3. 发明申请

US20100311569A1 CATALYST AND A METHOD FOR CRACKING HYDROCARBONS 审中-公开
标题翻译：催化剂和裂化烃的方法
公开(公告)号：US20100311569A1
公开(公告)日：2010-12-09
申请号：US12813110
申请日：2010-06-10
申请人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jishun Zhang , Beiyan Chen , Haitao Song
发明人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jishun Zhang , Beiyan Chen , Haitao Song
IPC分类号： B01J29/072
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive, is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂化烃的方法。该催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂，所述金属添加剂选自第VIIIB族和2-25重量％的P添加剂，其中金属添加剂由金属氧化物计算，P添加剂通过P2O5计算。使用该催化剂裂化烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

4. 发明申请

US20120292230A1 CATALYST AND A METHOD FOR CRACKING HYDROCARBONS 有权
标题翻译：催化剂和裂化烃的方法
公开(公告)号：US20120292230A1
公开(公告)日：2012-11-22
申请号：US13565145
申请日：2012-08-02
申请人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jishun Zhang , Beiyan Chen , Haitao Song
发明人： Jun Long , Wenbin Jiang , Mingde Xu , Huiping Tian , Yibin Luo , Xingtian Shu , Jishun Zhang , Beiyan Chen , Haitao Song
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , B01J27/1853 , B01J29/46 , B01J35/0006 , B01J35/002 , B01J2229/42 , C10G11/02 , C10G47/16 , C10G2300/4018 , C10G2400/02
摘要： The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.
摘要翻译：本发明公开了一种催化剂和一种裂化烃的方法。该催化剂包括以干基计，10〜65重量％的ZSM-5沸石，0〜60重量％的粘土，15〜60重量％的无机氧化物粘合剂，0.5〜15重量％的一种或多种金属添加剂，所述金属添加剂选自 VIIIB族和2〜25％（重量）P添加剂，其中金属添加剂由金属氧化物计算，P添加剂通过P2O5计算。使用该催化剂裂化烃的方法提高了FCC液化石油气（LPG）的产率和FCC汽油的辛烷值，并且显着提高了LPG中丙烯的浓度。

5. 发明授权

US07923399B2 Zeolite-containing hydrocarbon-converting catalyst, the preparation process thereof, and a process for converting hydrocarbon oils with the catalyst 有权
标题翻译：含沸石的烃转化催化剂，其制备方法以及用催化剂转化烃油的方法
公开(公告)号：US07923399B2
公开(公告)日：2011-04-12
申请号：US11547209
申请日：2005-03-31
申请人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
发明人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
IPC分类号： B01J29/42
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2 I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2 II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.
摘要翻译：用于转化烃的催化剂包括基于催化剂的重量，1-60重量％的沸石，0.1-10重量％的助催化组分，5-98重量％的耐热无机氧化物，和以氧化物换算0-70重量％的粘土。沸石是含有MFI结构的含沸石的磷光体和过渡金属或沸石与大孔沸石的混合物，其基于混合物的重量，包含所述MFI结构的75-100重量％含沸石的磷光体和过渡金属和0-25重量％的大孔沸石。就氧化物的质量而言，含有荧光粉和过渡金属的MFI结构的沸石具有以下无水化学式：（0-0.3）Na2O（0.3-5.5）Al2O3（1.0-10）P2O5。（0.7-15）M1xOy（0.01-5）M2mOn（0-10）RE2O3（70-97）SiO2 I或（0-0.3）Na2O（0.3-5）Al2O3（1.0-10）P2O5（ 0.7-15）MpOq。（0-10）RE2O3。（70-98）SiO2 II助催化剂组分是选自碱金属，ⅣB族金属，Ⅷ族非贵金属的一种或多种，元素周期表中的稀土金属。该催化剂具有较高的转化石油烃的能力和较高的丙烯，乙烯和轻质芳族化合物的产率。

6. 发明申请

US20090325786A1 HYDROCARBON CONVERSION CATALYST 有权
标题翻译：碳氢转化催化剂
公开(公告)号：US20090325786A1
公开(公告)日：2009-12-31
申请号：US12439315
申请日：2006-09-28
申请人： Yujian Liu , Huiping Tian , Xingtian Shu , Jun Long , Yibin Luo , Chaogang Xie , Zhenyu Chen , Liuzhou Zhao , Yuxia Zhu , Youbao Lu
发明人： Yujian Liu , Huiping Tian , Xingtian Shu , Jun Long , Yibin Luo , Chaogang Xie , Zhenyu Chen , Liuzhou Zhao , Yuxia Zhu , Youbao Lu
IPC分类号： B01J29/04 , B01J21/16 , B01J29/40 , B01J29/072 , B01J29/08 , B01J29/18
CPC分类号： B01J29/80 , B01J29/40 , B01J29/7007 , B01J29/7057 , B01J29/7615 , B01J29/7815 , B01J35/023 , B01J35/04 , B01J35/1076 , B01J35/1095 , B01J37/0045 , B01J37/0219 , B01J37/0234 , B01J2229/20 , B01J2229/42 , C04B35/18 , C04B2235/3201 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , C04B2235/3284 , C04B2235/3293 , C04B2235/447 , C10G2400/20
摘要： A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M. The catalysts provided in the present invention have higher ability to convert petroleum hydrocarbons and higher yields for light olefins, particularly for propylene. The catalysts can be used for the selectively producing light olefins.
摘要翻译：一种烃转化催化剂，其基于催化剂的总重量包含1-60重量％的沸石混合物，5-99重量％的耐热无机氧化物和0-70重量％的粘土，其中所述沸石混合物包括基于所述沸石混合物的总重量，1-75重量％的用磷和过渡金属M改性的沸石β，25-99重量％的具有MFI结构的沸石和0-74重量％的大孔沸石，其中用磷和过渡金属M改性的沸石β的无水化学式以氧化物的质量百分比表示为（0-0.3）Na 2 O（0.5-10）Al 2 O 3（1.3-10） P2O5（0.7-15）MxOy（64-97）SiO2，其中过渡金属M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种; x表示过渡金属M的原子数，y表示满足过渡金属M的氧化态所需的数。本发明提供的催化剂具有较高的转化石油烃的能力和较高的轻质烯烃产率，特别是用于丙烯。催化剂可用于选择性生产轻质烯烃。

7. 发明授权

US08716163B2 Hydrocarbon conversion catalyst 有权
标题翻译：烃转化催化剂
公开(公告)号：US08716163B2
公开(公告)日：2014-05-06
申请号：US12439315
申请日：2006-09-28
申请人： Yujian Liu , Huiping Tian , Xingtian Shu , Jun Long , Yibin Luo , Chaogang Xie , Zhenyu Chen , Liuzhou Zhao , Yuxia Zhu , Youbao Lu
发明人： Yujian Liu , Huiping Tian , Xingtian Shu , Jun Long , Yibin Luo , Chaogang Xie , Zhenyu Chen , Liuzhou Zhao , Yuxia Zhu , Youbao Lu
IPC分类号： B01J21/00 , B01J21/16 , B01J29/04 , B01J29/08 , B01J29/18
CPC分类号： B01J29/80 , B01J29/40 , B01J29/7007 , B01J29/7057 , B01J29/7615 , B01J29/7815 , B01J35/023 , B01J35/04 , B01J35/1076 , B01J35/1095 , B01J37/0045 , B01J37/0219 , B01J37/0234 , B01J2229/20 , B01J2229/42 , C04B35/18 , C04B2235/3201 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , C04B2235/3284 , C04B2235/3293 , C04B2235/447 , C10G2400/20
摘要： A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M.
摘要翻译：一种烃转化催化剂，其基于催化剂的总重量包含1-60重量％的沸石混合物，5-99重量％的耐热无机氧化物和0-70重量％的粘土，其中所述沸石混合物包括基于所述沸石混合物的总重量，1-75重量％的用磷和过渡金属M改性的沸石β，25-99重量％的具有MFI结构的沸石和0-74重量％的大孔沸石，其中用磷改性的沸石β和过渡金属M的无水化学式以氧化物的质量百分比表示为（0-0.3）Na 2 O（0.5-10）Al 2 O 3（1.3-10） P2O5（0.7-15）MxOy（64-97）SiO2，其中过渡金属M是选自Fe，Co，Ni，Cu，Mn，Zn和Sn中的一种或多种; x表示过渡金属M的原子数，y表示满足过渡金属M的氧化态所需的数。

8. 发明申请

US20140005032A1 CATALYST CONTAINING A MODIFIED Y-TYPE ZEOLITE AND A PREPARATON PROCESS THEREOF 有权
标题翻译：含有改性Y型沸石的催化剂及其制备方法
公开(公告)号：US20140005032A1
公开(公告)日：2014-01-02
申请号：US13929044
申请日：2013-06-27
申请人： Jun LONG , Fei Ren , Yuxia Zhu , Yibin Luo , Jiasong Yan , Xue Yang , Huiping Tian , Li Zhuang , Beiyan Chen , Minggang Li , Ying Ouyang , Xiangtian Shu
发明人： Jun LONG , Fei Ren , Yuxia Zhu , Yibin Luo , Jiasong Yan , Xue Yang , Huiping Tian , Li Zhuang , Beiyan Chen , Minggang Li , Ying Ouyang , Xiangtian Shu
IPC分类号： B01J29/80
CPC分类号： B01J29/80 , B01J29/088 , B01J37/28 , B01J37/30 , B01J2229/16 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C01B39/026
摘要： The present invention discloses a catalytic cracking catalyst and a preparation process therefor. The catalytic cracking catalyst comprises a cracking active component, 10 wt %-70 wt % of a clay on the dry basis, and 10 wt %-40 wt % of an inorganic oxide binder (as oxide), relative to the weight of the catalytic cracking catalyst, wherein said cracking active component contains, relative to the weight of the catalytic cracking catalyst, 10 wt %-50 wt % of a modified Y-type zeolite on the dry basis and 0-40 wt % of other zeolite on the dry basis, wherein said modified Y-type zeolite is characterized by having a unit cell size of 2.420-2.440 nm; as percent by weight of the modified Y-type zeolite, a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%; and a specific hydroxy nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g.
摘要翻译：本发明公开了一种催化裂化催化剂及其制备方法。催化裂化催化剂包含相对于催化剂重量的裂化活性组分，10重量％-70重量％的干基粘土和10重量％-40重量％的无机氧化物粘合剂（作为氧化物）裂化催化剂，其中所述裂化活性组分相对于催化裂化催化剂的重量含有10重量％-50重量％的基于干基的改性Y型沸石和0-40重量％干燥的其它沸石其中所述改性的Y型沸石的特征在于具有2.420-2.440nm的晶胞尺寸; 改性Y型沸石的重量百分比，磷含量为0.05-6％，RE2O3含量为0.03-10％，氧化铝含量小于22％; 特异性羟基巢浓度小于0.35mmol / g且大于0.05mmol / g。

9. 发明授权

US09630171B2 Catalyst containing a modified Y-type zeolite and a preparation process thereof 有权
公开(公告)号：US09630171B2
公开(公告)日：2017-04-25
申请号：US13929044
申请日：2013-06-27
申请人： Jun Long , Fei Ren , Yuxia Zhu , Yibin Luo , Jiasong Yan , Xue Yang , Huiping Tian , Li Zhuang , Beiyan Chen , Minggang Li , Ying Ouyang , Xiangtian Shu
发明人： Jun Long , Fei Ren , Yuxia Zhu , Yibin Luo , Jiasong Yan , Xue Yang , Huiping Tian , Li Zhuang , Beiyan Chen , Minggang Li , Ying Ouyang , Xiangtian Shu
IPC分类号： B01J29/06 , B01J29/80 , B01J29/08 , C01B39/02 , B01J37/30 , B01J37/28
CPC分类号： B01J29/80 , B01J29/088 , B01J37/28 , B01J37/30 , B01J2229/16 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C01B39/026
摘要： The present invention discloses a catalytic cracking catalyst and a preparation process therefor. The catalytic cracking catalyst comprises a cracking active component, 10 wt %-70 wt % of a clay on the dry basis, and 10 wt %-40 wt % of an inorganic oxide binder (as oxide), relative to the weight of the catalytic cracking catalyst, wherein said cracking active component contains, relative to the weight of the catalytic cracking catalyst, 10 wt %-50 wt % of a modified Y-type zeolite on the dry basis and 0-40 wt % of other zeolite on the dry basis, wherein said modified Y-type zeolite is characterized by having a unit cell size of 2.420-2.440 nm; as percent by weight of the modified Y-type zeolite, a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%; and a specific hydroxy nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g.

10. 发明申请

US20070293714A1 Zeolite-Containing Hydrocarbon-Converting Catalyst, the Preparation Process Thereof, and a Process for Converting Hydrocarbon Oils with the Catalyst 有权
公开(公告)号：US20070293714A1
公开(公告)日：2007-12-20
申请号：US11547209
申请日：2005-03-31
申请人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
发明人： Jun Long , Zhijian Da , Huiping Tian , Zhenyu Chen , Weilin Zhang , Xingtian Shu , Jiushun Zhang , Yuxia Zhu , Yujian Liu
IPC分类号： B01J29/42 , C10G11/05
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2 I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.(70-98)SiO2 II The assistant catalytic component is one or more selected from the group consisting of the alkali earth metals, Group IVB metals, non-noble metals of Group VIII, and rare earth metals of the Periodic Table of the Elements. This catalyst has a higher ability to convert petroleum hydrocarbons and higher yields for propylene, ethylene, and light aromatics.

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