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1. 发明授权

US07514385B2 Rare earth y-zeolite catalyst for cracking hydrocarbons and a method for preparing same 有权
标题翻译：用于裂解烃的稀土y沸石催化剂及其制备方法
公开(公告)号：US07514385B2
公开(公告)日：2009-04-07
申请号：US10533488
申请日：2003-10-28
申请人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
发明人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
IPC分类号： B01J29/06
CPC分类号： C10G47/02 , B01J29/088 , B01J2229/16 , B01J2229/32 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G47/16 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2400/02 , C10L1/06
摘要： The invention discloses a rare-earth Y-zeolite-containing catalyst for cracking hydrocarbons and a method for preparing the same. The catalyst is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite, calculated in RE2O3, is from 4 to 15% by weight, the original unit cell size is from 2.440 nm to 2.465 nm and the equilibrium unit cell size after 100% steam-aging treatment at 800° C. for 17 hours is larger than 2.435 nm. The catalyst is obtained in the following steps: the rare-earth Y-zeolite is dried first till its water content less than 10% by weight, then in a weight ratio of SiCl4:Y-zeolite=0.1˜0.9:1, reacts with SiCl4 gas carried by dry air, further is purged by dry air and washed by decationized water to remove the soluble by-products; the resulted rare-earth Y-zeolite is mixed with a binder and a clay, pulped and formed by spary drying. The zeolite content of the catalyst disclosed in present invention decreases 5˜25% by weight compared to the catalyst prepared in prior art for cracking heavy oil and decreasing olefin content. The catalyst is characterized with good cracking activity, high hydrothermal stability, and high conversion of heavy oil as well as excellent selectivity of gasoline, dry gas and coke; moreover, the olefin content in the produced gasoline decreases effectively.
摘要翻译：本发明公开了一种用于裂化烃的稀土Y-沸石催化剂及其制备方法。催化剂的特征在于稀土Y-沸石的晶格中的稀土含量以RE 2 O 3计算，为4〜15重量％，原始晶胞尺寸为2.440nm〜2.465nm，在800℃下进行100％蒸汽老化处理17小时后的平衡晶胞尺寸大于2.435nm。催化剂按以下步骤得到：稀土Y-沸石首先被干燥，直到其含水量低于10重量％，然后以SiCl 4 :Y-沸石= 0.1〜0.9:1的重量比与由干燥空气携带的SiCl 4气体，进一步用干燥空气清洗，并用去离子水洗涤以除去可溶性副产物; 将所得到的稀土Y沸石与粘合剂和粘土混合，通过喷雾干燥制浆并形成。与现有技术中制备的催化剂相比，本发明公开的催化剂的沸石含量降低了5〜25重量％，用于裂化重油和降低烯烃含量。催化剂的特点是具有良好的开裂活性，高水稳定性，重油转化率高，以及汽油，干气和焦炭的优异选择性; 此外，生产汽油中的烯烃含量有效降低。

2. 发明申请

US20080261802A1 Cracking Catalyst and a Preparation Process for the Same 有权
标题翻译：裂化催化剂及其制备方法
公开(公告)号：US20080261802A1
公开(公告)日：2008-10-23
申请号：US11910252
申请日：2006-03-31
申请人： Jun Du , Zheng Li , Jun Long , Mingde Xu , Zhijian Da , Huiping Tian , Mingyuan He
发明人： Jun Du , Zheng Li , Jun Long , Mingde Xu , Zhijian Da , Huiping Tian , Mingyuan He
IPC分类号： B01J29/08
CPC分类号： B01J29/088 , B01J35/002 , B01J37/0045 , B01J2229/24 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C10G11/05 , C10G2400/02
摘要： The present invention provides a cracking catalyst, containing a rare-earth Y-zeolite and a support, which is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite is 4-15 wt % of RE2O3; the original unit cell size is 2.440-2.465 nm; the equilibrium unit cell size of the catalyst after 100% stream-aging at 800° C. for 17 hours is larger than 2.435 nm; the rare-earth atom content in the support is 1.0-8.0 wt % of the support. The present invention also relates to a preparation process for the same catalyst.
摘要翻译：本发明提供含有稀土Y型沸石和载体的裂化催化剂，其特征在于，稀土Y型沸石的晶格中的稀土含量为RE的4〜15重量％ SUB> 2 3

3. 发明授权

US06991774B2 Rare earth zeolite Y and the preparation process thereof 有权
标题翻译：稀土沸石Y及其制备方法
公开(公告)号：US06991774B2
公开(公告)日：2006-01-31
申请号：US10811865
申请日：2004-03-30
申请人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
发明人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
IPC分类号： B01J29/08
CPC分类号： C01B39/026 , B01J29/084 , B01J2229/16 , C01B39/24 , C10G11/05 , Y10S423/21
摘要： The present invention discloses a high stability rare earth zeolite Y with high rare earth and the preparation process thereof, which zeolite has a content of rare earth of 4–15 wt %, a unit cell constant of 2.450–2.458 nm, a differential thermal collapsed temperature of 1000–1056° C., a silica to alumina ratio of 8.3–8.8, and a content of sodium oxide less than 1.0 wt %. Said zeolite is prepared by drying a rare earth-containing zeolite Y, introducing gaseous silicon tetrachloride carried by dry air and reacting at a temperature of 150–600° C. for 10 min to 6 h, then purging with dry air and washing with de-cationized water to remove the soluble by-products. The rare earth zeolite Y possesses high activity and selectivity for cracking the heavy oils, high activity for hydrogen transfer, has good coke selectivity, can effectively increase the yield of light oils, and improve the quality of gasoline and thus can directly serve as an active component for preparing various hydrocarbon cracking catalysts.
摘要翻译：本发明公开了一种具有高稀土的高稳定性稀土沸石Y及其制备方法，该沸石的稀土含量为4-15重量％，单位晶胞常数为2.450-2.458纳米，差热分解温度为1000-1056℃，二氧化硅与氧化铝之比为8.3-8.8，氧化钠含量小于1.0重量％。所述沸石通过干燥含稀土的沸石Y，引入由干燥空气携带的四氯化硅并在150-600℃的温度下反应10分钟至6小时，然后用干燥空气吹扫并用de 电解水以除去可溶性副产物。稀土沸石Y具有高重力油裂解活性和选择性，氢转移活性高，焦炭选择性好，能有效提高轻油产率，提高汽油质量，可直接作为活性炭制备各种烃裂解催化剂的组分。

4. 发明授权

US06787123B2 Rare earth zeolite Y and the preparation process thereof 有权
公开(公告)号：US06787123B2
公开(公告)日：2004-09-07
申请号：US10132911
申请日：2002-04-26
申请人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
发明人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
IPC分类号： C01B3924
CPC分类号： C01B39/026 , B01J29/084 , B01J2229/16 , C01B39/24 , C10G11/05 , Y10S423/21
摘要： The present invention discloses a high stability rare earth zeolite Y with high rare earth and the preparation process thereof, which zeolite has a content of rare earth of 4-15 wt %, a unit cell constant of 2.450-2.458 nm, a differential thermal collapsed temperature of 1000-1056° C., a silica to alumina ratio of 8.3-8.8, and a content of sodium oxide less than 1.0 wt %. Said zeolite is prepared by drying a rare earth-containing zeolite Y, introducing gaseous silicon tetrachloride carried by dry air and reacting at a temperature of 150-600° C. for 10 min to 6 h, then purging with dry air and washing with de-cationized water to remove the soluble by-products. The rare earth zeolite Y possesses high activity and selectivity for cracking the heavy oils, high activity for hydrogen transfer, has good coke selectivity, can effectively increase the yield of light oils, and improve the quality of gasoline and thus can directly serve as an active component for preparing various hydrocarbon cracking catalysts.

5. 发明授权

US07776775B2 Cracking catalyst and a preparation process for the same 有权
标题翻译：裂化催化剂及其制备方法相同
公开(公告)号：US07776775B2
公开(公告)日：2010-08-17
申请号：US11910252
申请日：2006-03-31
申请人： Jun Du , Zheng Li , Jun Long , Mingde Xu , Zhijian Da , Huiping Tian , Mingyuan He
发明人： Jun Du , Zheng Li , Jun Long , Mingde Xu , Zhijian Da , Huiping Tian , Mingyuan He
IPC分类号： B01J29/06
CPC分类号： B01J29/088 , B01J35/002 , B01J37/0045 , B01J2229/24 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C10G11/05 , C10G2400/02
摘要： The present invention provides a cracking catalyst, containing a rare-earth Y-zeolite and a support, which is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite is 4-15 wt % of RE2O3; the original unit cell size is 2.440-2.465 nm; the equilibrium unit cell size of the catalyst after 100% steam-aging treatment at 800° C. for 17 hours is larger than 2.435 nm; the rare-earth atom content in the support is 1.0-8.0 wt % of the support. The present invention also relates to a preparation process for the same catalyst.
摘要翻译：本发明提供含有稀土Y型沸石和载体的裂化催化剂，其特征在于，稀土Y型沸石的晶格中的稀土含量为RE 2 O 3的4〜15重量％原单位尺寸为2.440-2.465nm; 在800℃下经过100％蒸汽老化处理17小时后的催化剂的平衡单元尺寸大于2.435nm; 载体中的稀土原子含量为载体的1.0-8.0wt％。本发明还涉及相同催化剂的制备方法。

6. 发明申请

US20060199725A1 Petroleum Hydrocarbon cracking catalyst that contains rare earth zeolitey and its preparation 有权
标题翻译：含有稀土沸石的石油烃裂解催化剂及其制备方法
公开(公告)号：US20060199725A1
公开(公告)日：2006-09-07
申请号：US10533488
申请日：2003-10-28
申请人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
发明人： Jun Du , Zheng Li , Zhijian Da , Mingyuan He
IPC分类号： B01J29/08 , B01J21/00
CPC分类号： C10G47/02 , B01J29/088 , B01J2229/16 , B01J2229/32 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G47/16 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2400/02 , C10L1/06
摘要： The invention discloses a rare-earth Y-zeolite-containing catalyst for cracking hydrocarbons and a method for preparing the same. The catalyst is characterized in that the rare-earth content in crystal lattice of the rare-earth Y-zeolite, calculated in RE2O3, is from 4 to 15% by weight, the original unit cell size is from 2.440 nm to 2.465 nm and the equilibrium unit cell size after 100% steam-aging treatment at 800° C. for 17 hours is larger than 2.435 nm. The catalyst is obtained in the following steps: the rare-earth Y-zeolite is dried first till its water content less than 10% by weight, then in a weight ratio of SiCl4:Y-zeolite=0.1˜0.9:1, reacts with SiCl4 gas carried by dry air, further is purged by dry air and washed by decationized water to remove the soluble by-products; the resulted rare-earth Y-zeolite is mixed with a binder and a clay, pulped and formed by spary drying. The zeolite content of the catalyst disclosed in present invention decreases 5˜25% by weight compared to the catalyst prepared in prior art for cracking heavy oil and decreasing olefin content. The catalyst is characterized with good cracking activity, high hydrothermal stability, and high conversion of heavy oil as well as excellent selectivity of gasoline, dry gas and coke; moreover, the olefin content in the produced gasoline decreases effectively.
摘要翻译：本发明公开了一种用于裂化烃的稀土Y-沸石催化剂及其制备方法。催化剂的特征在于，在RE 2 O 3 3中计算的稀土Y-沸石的晶格中的稀土含量为4〜15％，原始晶胞尺寸为2.440nm至2.465nm，并且在800℃下经100％蒸汽老化处理17小时后的平衡晶胞尺寸大于2.435nm。催化剂按以下步骤得到：首先将稀土Y-沸石干燥至其含水量低于10重量％，然后以SiCl 4重量比：Y-沸石= 0.1〜0.9：1，与干燥空气携带的SiCl 4气体反应，进一步用干燥空气清洗，用去离子水洗涤除去可溶性副产物; 将所得到的稀土Y沸石与粘合剂和粘土混合，通过喷雾干燥制浆并形成。与现有技术中制备的催化剂相比，本发明公开的催化剂的沸石含量降低了5〜25重量％，用于裂化重油和降低烯烃含量。催化剂的特点是具有良好的开裂活性，高水稳定性，重油转化率高，以及汽油，干气和焦炭的优异选择性; 此外，生产汽油中的烯烃含量有效降低。

7. 发明授权

US07485595B2 Molecular sieve-containing catalyst for cracking hydrocarbons and a method for preparing the same 有权
标题翻译：用于裂化烃的分子筛催化剂及其制备方法
公开(公告)号：US07485595B2
公开(公告)日：2009-02-03
申请号：US10855386
申请日：2004-05-28
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： B01J29/04 , B01J29/87 , B01J29/06 , B01J21/00 , B01J29/00 , B01J29/08 , B01J21/16 , B01J23/00 , B01J23/32 , B01J23/02 , B01J23/06 , B01J23/70
CPC分类号： B01J29/088 , B01J29/061 , B01J29/146 , B01J29/166 , B01J37/0045 , B01J37/16 , B01J2229/18 , B01J2229/20 , B01J2229/42 , C10G11/05
摘要： A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.
摘要翻译：一种分子筛催化剂，用于裂解烃，包括分子筛，耐火无机氧化物，粘土和金属组分，其中所述分子筛的量为1至90重量％，耐火无机氧化物为2至80重量％，粘土为2〜80重量％，金属成分为0.1〜30重量％，以所述金属的最高化合价的氧化物计，基于催化剂的总量计，其中，所述金属组分基本上以还原状态存在，并且是选自IIIA族金属（铝以外）中的一种或多种金属，以及IVA，VA，IB，IIB，VB，VIB和VIIB族的金属，以及周期表第Ⅷ族的非贵金属。该催化剂具有较高的裂解活性和较高的硫还原活性。

8. 发明授权

US07435332B2 Process for cracking hydrocarbon oils 有权
标题翻译：裂解烃油的工艺
公开(公告)号：US07435332B2
公开(公告)日：2008-10-14
申请号：US10949298
申请日：2004-09-27
申请人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Huiping Tian , Yujian Liu , Yuxia Zhu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00 , C10G9/00
CPC分类号： C10G11/05 , C10G11/04
摘要： This invention relates to a process for cracking hydrocarbon oils. The process comprises contacting a hydrocarbon oil with a catalyst that has been contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, and regenerating the catalyst. The catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component. The catalyst is contacted with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, and the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has enhanced capability for desulfurizing and cracking heavy oils.
摘要翻译：本发明涉及一种裂解烃油的方法。该方法包括使烃油与已经与含有还原气体的气氛接触的催化剂接触，分离裂化产物和催化剂，并再生催化剂。催化剂是含有金属组分的裂化催化剂，或含有金属组分的裂化催化剂和不含金属组分的裂化催化剂的催化剂混合物。催化剂与含有还原气体的气氛在100〜900℃的温度下接触1秒以上，含有还原气体的气氛量不低于0.03立方米/ 裂化催化剂在还原反应器中以0.1-0.5MPa的压力每分钟含有金属组分。该工艺提高脱硫和重油的能力。

9. 发明申请

US20080289997A1 PROCESS FOR CRACKING HYDROCARBON OILS 有权
标题翻译：破碎油气的方法
公开(公告)号：US20080289997A1
公开(公告)日：2008-11-27
申请号：US12027123
申请日：2008-02-06
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译：一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

10. 发明授权

US07347930B2 Process for cracking hydrocarbon oils 有权
标题翻译：裂解烃油的工艺
公开(公告)号：US07347930B2
公开(公告)日：2008-03-25
申请号：US10964644
申请日：2004-10-15
申请人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
发明人： Jun Long , Yuxia Zhu , Huiping Tian , Yujian Liu , Zhenyu Chen , Yaoqing Guo , Zhijian Da , Jiushun Zhang , Mingyuan He
IPC分类号： C10G11/00 , C10G29/04
CPC分类号： C10G11/14 , C10G11/05 , C10G11/16 , C10G11/182 , C10G2300/205 , C10G2300/4006 , C10G2300/4012 , C10G2300/701 , C10G2400/04
摘要： A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
摘要翻译：一种用于裂化烯烃的新方法，包括在裂化反应条件下具有多个反应区的提升管反应器中使烃油与催化剂接触; 分离反应产物和催化剂; 再生至少一部分所获得的废催化剂，使部分再生催化剂与第一反应区中的烃接触; 在第一反应区之后的至少一个反应区与先前反应区中获得的产物接触废催化剂和/或再生催化剂的另一部分。

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