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1. 发明申请

US20090114596A1 NANOFILM AND MEMBRANE COMPOSITIONS 有权
标题翻译：纳米和薄膜组合物
公开(公告)号：US20090114596A1
公开(公告)日：2009-05-07
申请号：US12183469
申请日：2008-07-31
申请人： Joshua W. KRIESEL , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas , Mark Micklatcher , Serena Joshi
发明人： Joshua W. KRIESEL , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas , Mark Micklatcher , Serena Joshi
IPC分类号： B01D61/14 , B01D53/22
CPC分类号： B82Y30/00 , C07D259/00
摘要： Nanofilms useful for filtration are prepared from oriented amphiphilic molecules and oriented macrocyclic modules. The amphiphilic species may be oriented on an interface or surface. The nanofilm may be prepared by depositing or attaching an oriented layer to a substrate. A nanofilm may also be prepared by coupling the oriented macrocyclic modules to provide a membrane.
摘要翻译：用于过滤的纳米薄膜由取向的两亲分子和取向的大环模块制备。两亲物种可以在界面或表面上取向。可以通过将定向层沉积或附着到基底来制备纳米薄膜。还可以通过将定向的大环模块偶联以提供膜来制备纳米薄膜。

2. 发明授权

US07432371B2 Nanofilm and membrane compositions 失效
标题翻译：纳米薄膜和膜组成
公开(公告)号：US07432371B2
公开(公告)日：2008-10-07
申请号：US10359894
申请日：2003-02-07
申请人： Joshua W. Kriesel , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas , Mark Micklatcher , Serena Joshi
发明人： Joshua W. Kriesel , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas , Mark Micklatcher , Serena Joshi
IPC分类号： C07D291/00
CPC分类号： B82Y30/00 , C07D259/00
摘要： Nanofilms useful for filtration are prepared from oriented amphiphilic molecules and oriented macrocyclic modules. The amphiphilic species may be oriented on an interface or surface. The nanofilm may be prepared by depositing or attaching an oriented layer to a substrate. A nanofilm may also be prepared by coupling the oriented macrocyclic modules to provide a membrane.
摘要翻译：用于过滤的纳米薄膜由取向的两亲分子和取向的大环模块制备。两亲物种可以在界面或表面上取向。可以通过将定向层沉积或附着到基底来制备纳米薄膜。还可以通过将定向的大环模块偶联以提供膜来制备纳米薄膜。

3. 发明授权

US08110679B2 Nanofilm and membrane compositions 有权
标题翻译：纳米薄膜和膜组成
公开(公告)号：US08110679B2
公开(公告)日：2012-02-07
申请号：US12183469
申请日：2008-07-31
申请人： Joshua W. Kriesel , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas , Mark Micklatcher , Serena Joshi
发明人： Joshua W. Kriesel , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas , Mark Micklatcher , Serena Joshi
IPC分类号： C07D291/00
CPC分类号： B82Y30/00 , C07D259/00
摘要： Nanofilms useful for filtration are prepared from oriented amphiphilic molecules and oriented macrocyclic modules. The amphiphilic species may be oriented on an interface or surface. The nanofilm may be prepared by depositing or attaching an oriented layer to a substrate. A nanofilm may also be prepared by coupling the oriented macrocyclic modules to provide a membrane.
摘要翻译：用于过滤的纳米薄膜由取向的两亲分子和取向的大环模块制备。两亲物种可以在界面或表面上取向。可以通过将定向层沉积或附着到基底来制备纳米薄膜。还可以通过将定向的大环模块偶联以提供膜来制备纳米薄膜。

4. 发明授权

US07767810B2 Macrocyclic modules comprising linked cyclic synthon units for use in the formation of selectively permeable membranes 有权
标题翻译：包含连接的环状合成单元的大环模块用于形成选择性渗透膜
公开(公告)号：US07767810B2
公开(公告)日：2010-08-03
申请号：US11199913
申请日：2005-08-08
申请人： Joshua W. Kriesel , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas
发明人： Joshua W. Kriesel , Timothy B. Karpishin , Donald B. Bivin , Grant Merrill , Martin S. Edelstein , Thomas H. Smith , Jeffery A. Whiteford , Robert T. Jonas
IPC分类号： C07D487/00
CPC分类号： C07D259/00
摘要： Certain macrocyclic modules comprising 3-24 synthons are provided herein. Each synthon is independently selected from cyclic substituents, wherein each synthon selected is bonded to the next through a linker to form a closed ring that defines a pore. One or more lipophilic moieties and one or more hydrophilic moieties are bonded to one or more of the synthons, resulting in the formation of the desired macrocyclic modules. Those modules may be subsequently linked to one another to form selectively-permeable membranes. Membranes comprising macrocyclic modules may be useful in filtering certain molecular species from a solution. Selective passage of particular species is determined, in part, by the size of the module's pore and the nature of the lipophilic/hydrophobic species attached thereto. Also provided are methods of making and using macrocyclic modules and membranes.
摘要翻译：本文提供了包含3-24个合成子的某些大环模块。每个合成子独立地选自环状取代基，其中所选择的每个合成子通过接头键合到下一个，以形成限定孔的封闭环。一个或多个亲脂部分和一个或多个亲水部分键合到一个或多个合成子上，导致所需的大环模块的形成。这些模块可以随后彼此连接以形成选择性渗透的膜。包含大环模块的膜可用于从溶液中过滤某些分子物质。特定物种的选择性通过部分地由模块的孔的尺寸和附着于其上的亲油/疏水物质的性质决定。还提供了制备和使用大环模块和膜的方法。

5. 发明申请

US20100152438A1 AMPHIPHILIC MOLECULAR MODULES AND CONSTRUCTS BASED THEREON 审中-公开
标题翻译：基于其的分子模块和构建体
公开(公告)号：US20100152438A1
公开(公告)日：2010-06-17
申请号：US12504610
申请日：2009-07-16
申请人： Timothy B. Karpishin , Josh kriesel , Grant Merrill , Donald B. Bivin , Thomas H. Smith , Martin Stuart Edelstein
发明人： Timothy B. Karpishin , Josh kriesel , Grant Merrill , Donald B. Bivin , Thomas H. Smith , Martin Stuart Edelstein
IPC分类号： C07D259/00
CPC分类号： C07D259/00
摘要： The present invention relates to the preparation of synthons that are used to form modules that, in turn, are used to form two-dimensional close-packed planar arrays, referred to as nanomembranes. In a presently preferred embodiment, a nanomembrane herein constitutes a filter.
摘要翻译：本发明涉及用于形成模块的合成子的制备，所述模块又被用于形成被称为纳米膜的二维密堆积平面阵列。在目前优选的实施方式中，本文中的纳米膜构成过滤器。

6. 发明授权

US07563890B2 Amphiphilic molecular modules and constructs based thereon 失效
标题翻译：两亲分子模块和基于此的构建体
公开(公告)号：US07563890B2
公开(公告)日：2009-07-21
申请号：US11207383
申请日：2005-08-18
申请人： Timothy B. Karpishin , Josh Kriesel , Grant Merrill , Donald B. Bivin , Thomas H. Smith , Martin Stuart Edelstein
发明人： Timothy B. Karpishin , Josh Kriesel , Grant Merrill , Donald B. Bivin , Thomas H. Smith , Martin Stuart Edelstein
IPC分类号： C07D487/00 , C07D491/00 , C07D513/00
CPC分类号： C07D259/00
摘要： Certain amphiphilic modules comprising 3-24 synthons are provided herein. Each synthon is independently selected from aryl, heteroaryl, alicyclic, and heteroalicyclic substituents, wherein each synthon selected is bonded to the next through a linker to form a closed ring that defines a nanopore. One or more lipophilic moieties and one or more hydrophilic moieties are bonded to one or more of the synthons, resulting in the formation of the desired amphiphilic modules. Those modules may be subsequently linked to one another to form two-dimensional close-packed planar arrays, referred to as nanomembranes. Nanomembranes may be useful in filtering certain ionic species from a solution. Selective passage of particular species is determined, in part, by the size of the module's nanopore and the nature of the lipophilic/hydrophobic species attached thereto. Also provided are methods of making and using amphiphilic modules and nanomembranes.
摘要翻译：本文提供了包含3-24个合成子的某些两亲模块。每个合成子独立地选自芳基，杂芳基，脂环族和杂脂环取代基，其中所选择的每个合成子通过接头键合到下一个，以形成限定纳米孔的封闭环。将一个或多个亲脂部分和一个或多个亲水部分键合到一个或多个合成子上，导致所需的两亲性模块的形成。这些模块可以随后彼此连接以形成称为纳米膜的二维密堆积平面阵列。纳米膜可用于从溶液中过滤某些离子物质。特定物种的选择性通过部分地由模块的纳米孔的尺寸和附着于其上的亲脂/疏水物质的性质决定。还提供了制造和使用两亲模块和纳米膜的方法。

7. 发明授权

US06391648B1 Photoluminescent metal-(Bis) ligand complexes having different ligands 失效
标题翻译：具有不同配体的发光金属 - （双）配体配合物
公开(公告)号：US06391648B1
公开(公告)日：2002-05-21
申请号：US09510887
申请日：2000-02-23
申请人： Timothy B. Karpishin , Mark T. Miller
发明人： Timothy B. Karpishin , Mark T. Miller
IPC分类号： G01N2176
CPC分类号： C09K11/06 , C07F1/005
摘要： Photoluminescent complexes of copper, silver, zinc, lithium or similar metals are described, being (bis)ligand, with two different ligands. A variety of ligands may be used, the larger ligand being of a size or shape such that a pair of such ligand are prevented by steric properties from forming a (bis)ligand complex with the metal. Preferred substituents may be alkyl, aryl or alkaryl hydrocarbons, or halogen, chalcogen, nitrogen or phosphorus moieties, or included heteroatoms. Formation of the (bis)ligand complex is accomplished by maintaining the molar ratios of reactants at that which is equivalent to the (bis)ligand complex composition. The complexes are useful as optical sensors for O2, NH3 and NOx, in dye sensitization for photovoltaic devices/solar cells, in producing visible TiO2 photosensitization and in H2 production from the photochemically splitting water. These heteroleptic complexes exhibit photoluminescence equal to or better than ruthenium homoleptic complexes.
摘要翻译：铜，银，锌，锂或类似金属的光致发光复合物被描述为具有两个不同配体的（双）配体。可以使用多种配体，较大的配体具有尺寸或形状，使得一对这样的配体通过空间性质防止与金属形成（双）配体络合物。优选的取代基可以是烷基，芳基或烷芳基烃，或卤素，硫族元素，氮或磷部分或包括的杂原子。（双）配体络合物的形成通过保持反应物的摩尔比在等于（双）配体络合物组合物的摩尔比来完成。该复合物可用作O 2，NH 3和NO x的光学传感器，用于光伏器件/太阳能电池的染料敏化，用于产生可见的TiO 2光敏化和在光化学裂解水中产生H2。这些杂光配合物表现出等于或优于钌均质复合物的光致发光。

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