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    • 10. 发明授权
    • Method of recovering tall-oil soap from kraft black liquor
    • 从牛皮纸黑液中回收妥尔油皂的方法
    • US4085000A
    • 1978-04-18
    • US759070
    • 1977-01-13
    • Joseph V. OtrhalekGilbert Stephen GomesGunther Hans Elfers
    • Joseph V. OtrhalekGilbert Stephen GomesGunther Hans Elfers
    • C11B13/02C11D15/04D21C11/00
    • D21C11/0007C11B13/02C11D15/04Y02W30/74
    • As a tall-oil-soap skimming aid, there is added to black liquor resulting from the pulping of coniferous trees a terpolymer of (a) an alpha-beta-unsaturated acid, (2) an alkylate of an alpha-beta-unsaturated acid, and (3) allyl alcohol. The acid contains 3 to 4 carbon atoms and comprises about 60 to about 88 percent by weight of the terpolymer. The alkylate comprises about 6 to 28 parts by weight of the terpolymer, being an ester of the abovementioned acids, the ester having an alkyl portion containing 1 to 18 carbon atoms. Allyl-alcohol units are present in the terpolymer to an extent of 4.5 to 20 weight percent. The terpolymer can be produced by free-radical polymerization in accordance with the customary procedures. With the use of such a copolymer, the proportion of tall oil recovered from black liquor is very substantially increased.
    • 作为高油皂撇渣助剂,添加了由针叶树制浆造成的(a)α-β-不饱和酸的三元共聚物,(2)α-β-不饱和酸的烷基化物 ,和(3)烯丙醇。 该酸含有3至4个碳原子,并且占三元共聚物的约60至约88重量%。 烷基化物包含约6至28重量份的三元共聚物,即上述酸的酯,所述酯具有含有1至18个碳原子的烷基部分。 烯丙醇单元在三元共聚物中的存在量为4.5至20重量%。 三元共聚物可以根据常规方法通过自由基聚合制备。 通过使用这种共聚物,从黑液中回收的妥尔油的比例大大增加。