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1. 再颁专利

USRE34640E Thermoplastic elastomers of isobutylene and process of preparation 失效
标题翻译：异丁烯的热塑性弹性体及其制备方法
公开(公告)号：USRE34640E
公开(公告)日：1994-06-14
申请号：US875082
申请日：1992-04-28
申请人： Joseph P. Kennedy , Judit E. Puskas , Gabor Kaszas , William G. Hager
发明人： Joseph P. Kennedy , Judit E. Puskas , Gabor Kaszas , William G. Hager
IPC分类号： C08F4/00 , C08F297/00 , C08F297/06 , C08F255/10
CPC分类号： C08F297/06 , C08F297/00
摘要： Block copolymers compose a polyisobutylene rubbery soft segment of M.sub.n of about 5,000 to above 500,000 and glassy hard segments of M.sub.n of about 5,000 or higher and usually about 10,000 to 35,000 or more, are made by preparing a living polymer block of the polyisobutylene and then polymerizing on said living polyisobutylene block the glassy hard segments by adding thereto an electron donor having a donor number of 15 to 50 and then adding and polymerizing the monomers for the glassy hard segments. The monomers for the glassy hard segments are styrene and its derivatives and indene and its derivatives and mixtures thereof.
摘要翻译：嵌段共聚物通过制备聚异丁烯的活性聚合物嵌段而制备约5,000至500,000以上的上链＆Mn的聚异丁烯橡胶状软链段和约5000或更高，通常约10,000-35,000或更高的玻璃状硬链段，然后在所述活性聚异丁烯上聚合，通过向其中加入供体数为15至50的电子给体，然后加入并聚合用于玻璃状硬链段的单体，阻断玻璃状硬链段。玻璃状硬链段的单体是苯乙烯及其衍生物和茚及其衍生物及其混合物。

2. 发明授权

US4946899A Thermoplastic elastomers of isobutylene and process of preparation 失效
标题翻译：异丁烯的热塑性弹性体及其制备方法
公开(公告)号：US4946899A
公开(公告)日：1990-08-07
申请号：US285207
申请日：1988-12-16
申请人： Joseph P. Kennedy , Judit E. Puskas , Gabor Kaszas , William G. Hager
发明人： Joseph P. Kennedy , Judit E. Puskas , Gabor Kaszas , William G. Hager
IPC分类号： C08F4/00 , C08F297/00 , C08F297/06
CPC分类号： C08F297/06 , C08F297/00
摘要： Block copolymers compose a polyisobutylene rubbery soft segment of M.sub.n of about 5,000 to above 500,000 and glassy hard segments of M.sub.n of about 5,000 or higher and usually about 10,000 to 35,000 or more, are made by preparing a living polymer block of the polyisobutylene and then polymerizing on said living polyisobutylene block the glassy hard segments by adding thereto an electron donor having a donor number of 15 to 50 and then adding and polymerizing the monomers for the glassy hard segments. The monomers for the glassy hard segments are styrene and its derivatives and indene and its derivatives and mixtures thereof.
摘要翻译：嵌段共聚物通过制备聚异丁烯的活性聚合物嵌段而制备约5,000至500,000以上的上链＆Mn的聚异丁烯橡胶状软链段和约5000或更高，通常约10,000-35,000或更高的玻璃状硬链段，然后在所述活性聚异丁烯上聚合，通过向其中加入供体数为15至50的电子给体，然后加入并聚合用于玻璃状硬链段的单体，阻断玻璃状硬链段。玻璃状硬链段的单体是苯乙烯及其衍生物和茚及其衍生物及其混合物。

3. 发明授权

US5171760A UV curable polymer formulation 失效
标题翻译：紫外线固化聚合物配方
公开(公告)号：US5171760A
公开(公告)日：1992-12-15
申请号：US632368
申请日：1990-12-21
申请人： Gabor Kaszas , Judit E. Puskas , Joseph P. Kennedy
发明人： Gabor Kaszas , Judit E. Puskas , Joseph P. Kennedy
IPC分类号： C08F2/48 , C08F255/08 , C08F290/04 , H05K3/28
CPC分类号： C08F290/044 , C08F255/08 , H05K3/287
摘要： A cross-linked composition produced by exposing a mixture including a telechelic polyisobutylene-containing base polymer which carries multiple terminal acrylate groups as a part thereof, a reactive diluent, and in some cases, a high-energy sensitizer, to high-energy radiation. The base polymer may also comprise a block copolymer which has polyisobutylene, and polydiene blocks as, for example, polyisoprene, and in which the polydiene blocks, advantageously partially cyclized, carry multiple acrylate groups as a part thereof. Among other things, the compositions have particular application in the formation of films useful in the electronic, biomedical, specialty adhesive, sealant, and other fields.
摘要翻译：将包含作为其一部分携带多个末端丙烯酸酯基的遥爪聚异丁烯的基础聚合物的混合物，反应性稀释剂和在一些情况下将高能量敏化剂暴露于高能量辐射而制备的交联组合物。基础聚合物还可以包含具有聚异丁烯的嵌段共聚物，聚二烯嵌段作为例如聚异戊二烯，其中聚二烯嵌段有利地部分环化，作为其一部分携带多个丙烯酸酯基团。除其他之外，组合物特别适用于形成用于电子，生物医学，特种粘合剂，密封剂等领域的膜。

4. 发明授权

US5169914A Uniform molecular weight polymers 失效
标题翻译：均匀的分子量聚合物
公开(公告)号：US5169914A
公开(公告)日：1992-12-08
申请号：US865826
申请日：1992-04-01
申请人： Gabor Kaszas , Judit E. Puskas , Joseph P. Kennedy
发明人： Gabor Kaszas , Judit E. Puskas , Joseph P. Kennedy
IPC分类号： C08F10/00 , C08F10/10 , C08F110/10 , C08F210/12
CPC分类号： C08F10/00 , C08F10/10 , C08F110/10 , C08F210/12
摘要： A method for producing polymers with narrow molecular weight distribution which involves combining (1) an initiator component of the formula ##STR1## in which R.sub.1, R.sub.2, and R.sub.3 are alkyl, aryl, or aralkyl groups, and can be the same or different, and X is an acetate, etherate, a hydroxyl group, or a halogen, and i is a positive whole number, (2) a Lewis acid of the formula MX.sub.n in which M is titanium, aluminum, boron, or tin, X is a halogen, and n is a positive whole number, (3) an electron donor component having an electron donor number of from at least about 25 to no more than about 50, (4) a solvent for the preceding and (5) a hydrocarbon monomer component.
摘要翻译：制备具有窄分子量分布的聚合物的方法，其涉及组合（1）式（I）的引发剂组分，其中R 1，R 2和R 3是烷基，芳基或芳烷基，并且可以相同或不同的，X为乙酸酯，醚合物，羟基或卤素，i为正整数，（2）式MXn的路易斯酸，其中M为钛，铝，硼或锡， X是卤素，n是正整数，（3）具有至少约25至不超过约50的电子给体数的电子给体组分，（4）前述和（5）的溶剂，烃单体组分。

5. 发明授权

US4910261A Thermoplastic elastomers having isobutylene block and cyclized diene blocks 失效
标题翻译：具有异丁烯嵌段和环化二烯嵌段的热塑性弹性体
公开(公告)号：US4910261A
公开(公告)日：1990-03-20
申请号：US208374
申请日：1988-06-17
申请人： Gabor Kaszas , Judit E. Puskas , Joseph P. Kennedy
发明人： Gabor Kaszas , Judit E. Puskas , Joseph P. Kennedy
IPC分类号： C08F297/00
CPC分类号： C08F297/00
摘要： A polymerization process for preparing triblock copolymers and multiblock copolymers. The process includes the polymerization of isobutylene below about -40.degree. C. in a reaction mixture which includes a titanium halide, a mixed solvent, and an initiator compound selected from the group consisting of cumyl ester and cumyl ether compounds. In at least some instances, the components are added in a particular order, sometimes together with a moisture scavenger. After formation of the polyisobutylene, a diene is added to the mixture containing the polyisobutylene and polymerized to form the desired copolymer. The diene portion of the copolymer may subsequently be cyclized to produce a copolymer exhibiting both thermoplastic and elastomeric properties. If desired the block copolymers can be subsequently modified to include functional side groups, or to provide photocuring capabilities.

6. 发明授权

US5194538A Preparation of butyl rubber with bimodal molecular weight distribution 失效
标题翻译：制备具有双峰分子量分布的丁基橡胶
公开(公告)号：US5194538A
公开(公告)日：1993-03-16
申请号：US914368
申请日：1992-07-15
申请人： Judit E. Puskas , Gabor Kaszas
发明人： Judit E. Puskas , Gabor Kaszas
IPC分类号： C08F4/00 , C08F2/38 , C08F210/10 , C08F210/12
CPC分类号： C08F210/10
摘要： A polymerization process is provided for producing a butyl rubber with a bimodal molecular weight distribution which comprises introducing isobutylene, a conjugated diolefin monomer having from 4 to 8 carbon atoms, from about 1.times.10.sup.-5 to about 1.times.10.sup.-3 moles of an initiator component per mole of isobutylene, said initiator component being selected from the group consisting of an initiator component having the formula: ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are selected from the group consisting of alkyl, aryl and aralkyl groups and can be the same or different and i is a positive whole number from 2 to 6, and an initiator component having an adamantyl nucleus bearing from 2 to 4 hydroxyl groups an inert organic solvent and from about 1.times.10.sup.-4 to about 1.times.10.sup.-3 moles of water per liter of inert organic solvent into a suitable reaction vessel at a temperature of from about -120.degree. C. to about -50.degree. C., adding a solution of from about 5.times.10.sup.-5 to about 1.times.10.sup.-2 moles of a Lewis acid per mole of isobutylene in an organic solvent and polymerizing the monomers to form said butyl rubber.

7. 发明授权

US5276094A Compositions of butyl elastomers and block copolymers of polyisobutylene 失效
标题翻译：丁基弹性体的组合物和聚异丁烯的嵌段共聚物
公开(公告)号：US5276094A
公开(公告)日：1994-01-04
申请号：US974552
申请日：1992-11-12
申请人： Gabor Kaszas , Judit E. Puskas
发明人： Gabor Kaszas , Judit E. Puskas
IPC分类号： C08F297/06 , C08L23/18 , C08L23/22 , C08L23/26 , C08L23/28 , C08L53/00 , C08F297/00
CPC分类号： C08L23/22 , C08F297/06 , C08L23/283
摘要： An elastomeric polymer composition that exhibits improved processability and green strength comprises: from about 95 to about 70 parts by weight of one rubbery polymer selected from the group consisting of butyl rubber, chlorinated butyl rubber and brominated butyl rubber and from about 5 to about 30 parts by weight of a block copolymer having an elastomeric polyisobutylene midblock and two plastomeric endblocks of polymerized monovinylidene aromatic monomers and star-shaped block copolymers having from three to six arms wherein the inner elastomeric blocks are polyisobutylene and the outer plastomeric blocs are polymerized monovinylidene aromatic monmers for a total of 100 parts by weight of the rubbery polymer and the block copolymer. Vulcanizates of the composition that exhibit reduced permeability to gases and improved tear strength are provided together with a process for their production.
摘要翻译：显示改善的加工性和生坯强度的弹性体聚合物组合物包括：约95至约70重量份的一种选自丁基橡胶，氯化丁基橡胶和溴化丁基橡胶的橡胶状聚合物和约5至约30重量份的具有弹性聚异丁烯中间嵌段的嵌段共聚物和聚合的单亚乙烯基芳族单体的两个塑性端嵌段和具有三至六个臂的星形嵌段共聚物，其中内部弹性体嵌段是聚异丁烯，外部塑性嵌段是聚合的单亚乙烯基芳族单体，用于共计100重量份的橡胶状聚合物和嵌段共聚物。提供显示出降低的气体渗透性和改进的撕裂强度的组合物的硫化橡胶与其生产方法一起提供。

8. 发明申请

US20100256305A1 METHOD OF PURIFYING BLOCK COPOLYMERS 审中-公开
公开(公告)号：US20100256305A1
公开(公告)日：2010-10-07
申请号：US12608792
申请日：2009-10-29
申请人： Gabor Kaszas
发明人： Gabor Kaszas
IPC分类号： C08L25/08
CPC分类号： C08F297/00 , C08F6/003 , C08F6/06 , C08L53/00
摘要： The invention relates to block polymers, for example, arborescent copolymer compounds, and to methods of making and purifying such compounds. In one embodiment, the invention relates to arborescent polymer compounds that contain one or more styrene polymeric blocks in combination with one or more isobutylene polymeric blocks. In another embodiment, the invention relates to methods for purifying arborescent polymer compounds that contain at least one styrene polymeric block in combination with at least one isobutylene polymeric block.

9. 发明申请

US20100059452A1 METHOD OF PURIFYING BLOCK COPOLYMERS 审中-公开
标题翻译：纯化嵌段共聚物的方法
公开(公告)号：US20100059452A1
公开(公告)日：2010-03-11
申请号：US12209103
申请日：2008-09-11
申请人： Gabor Kaszas
发明人： Gabor Kaszas
IPC分类号： B01D21/01 , C08L53/00
CPC分类号： C08F297/00 , C08F6/003 , C08F6/06 , C08L53/00
摘要： The invention relates to block polymers, for example, arborescent copolymer compounds, and to methods of making and purifying such compounds. In one embodiment, the invention relates to arborescent polymer compounds that contain one or more styrene polymeric blocks in combination with one or more isobutylene polymeric blocks. In another embodiment, the invention relates to methods for purifying arborescent polymer compounds that contain at least one styrene polymeric block in combination with at least one isobutylene polymeric block.
摘要翻译：本发明涉及嵌段聚合物，例如芳族聚合物化合物，以及制备和纯化这些化合物的方法。在一个实施方案中，本发明涉及含有一个或多个苯乙烯聚合物嵌段与一个或多个异丁烯聚合物嵌段组合的芳族聚合物化合物。在另一个实施方案中，本发明涉及用于纯化含有至少一个苯乙烯聚合物嵌段与至少一个异丁烯聚合物嵌段组合的芳族聚合物化合物的方法。

10. 发明申请

US20090030169A1 Process for production of high-isoprene butyl rubber 审中-公开
标题翻译：生产高异戊二烯丁基橡胶的方法
公开(公告)号：US20090030169A1
公开(公告)日：2009-01-29
申请号：US11825723
申请日：2007-07-09
申请人： R. Resendes , Rudolf Casper , Rotraud Casper , William E. App , Gerhard Langstein , Martin Bohnenpoll , Gabor Kaszas , Stephan Glander
发明人： R. Resendes , Rudolf Casper , Rotraud Casper , William E. App , Gerhard Langstein , Martin Bohnenpoll , Gabor Kaszas , Stephan Glander
IPC分类号： C08F4/52 , C08F36/00
CPC分类号： C08F210/12 , C08F4/00 , C08F4/12 , C08F236/06 , C08F2500/01 , C08F2500/21
摘要： The present invention relates to a process for producing polymers comprising repeating units derived from at least one isoolefin monomer, at least one multiolefin monomer and optionally further copolymerizable monomers in the presence of at least one organic nitro compound and AlCl3/water wherein the process is conducted in the absence of compounds selected from the group consisting of vanadium compounds, zirconium halogenid, hafnium halogenides.Preferably the polymers have a multiolefin content of greater than 2.5 mol %, and a molecular weight Mw of greater than 240 kg/mol.
摘要翻译：本发明涉及在至少一种有机硝基化合物和AlCl 3 /水的存在下，由至少一种异烯烃单体，至少一种多烯烃单体和任选的其它可共聚单体衍生的聚合物的方法，其中进行该方法在不存在选自钒化合物，卤化锆，卤化铪的化合物的化合物的情况下。优选地，聚合物的多烯烃含量大于2.5摩尔％，分子量Mw大于240千克/摩尔。

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