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1. 发明授权

US4342698A Olefin oxidation process 失效
标题翻译：烯烃氧化工艺
公开(公告)号：US4342698A
公开(公告)日：1982-08-03
申请号：US53607
申请日：1979-06-29
申请人： Joseph P. Bartek , Robert K. Grasselli , Rimvydas L. Cepulis
发明人： Joseph P. Bartek , Robert K. Grasselli , Rimvydas L. Cepulis
IPC分类号： B01J23/00 , B01J23/16 , B01J23/18 , B01J23/68 , B01J23/76 , B01J23/89 , B01J27/00 , B01J27/057 , B01J27/18 , B01J27/186 , C07B61/00 , C07D307/36 , C07D307/46 , C07D307/48 , C07D307/54
CPC分类号： B01J27/186 , B01J23/18 , B01J23/68 , B01J23/76 , B01J23/8933 , B01J27/0573 , B01J27/0576 , C07D307/36
摘要： Oxole compounds, e.g. furan, are produced by contacting alkenes and/or alkadienes with molecular oxygen in the presence of an antimony catalyst.
摘要翻译：氧化物化合物，例如呋喃通过在锑催化剂存在下使烯烃和/或链烯二烯与分子氧接触来制备。

2. 发明授权

US5068215A Catalyst for upgrading low molecular weight hydrocarbons 失效
标题翻译：用于升级低分子量烃的催化剂
公开(公告)号：US5068215A
公开(公告)日：1991-11-26
申请号：US448705
申请日：1989-12-11
申请人： Joseph P. Bartek , James F. Brazdil, Jr. , John M. Hupp , Robert K. Grasselli
发明人： Joseph P. Bartek , James F. Brazdil, Jr. , John M. Hupp , Robert K. Grasselli
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/06 , C07C2527/224
摘要： A multi-component oxide catalyst comprising zinc and an alkali metal is described which is useful particularly for converting methane and/or natural gas to higher molecular weight hydrocarbon products such as ethane and ethylene. The catalyst is characterized by the formulaZn.sub.a A.sub.b M.sub.c M'.sub.d O.sub.xwhereinA is Li, Na, K, or mixtures thereof;M is Al, Ga, Cr, La, Y, Sc, V, Nb, Ta, Cu or mixtures thereof;M' is Cs, Rb, Mg, Ca, Sr, Ba, Sm, Pb, Mn, Sb, P, Sn, Bi, Ti, Zr, Hf, or mixtures thereof;a is from about 1 to about 20;b is from about 0.1 to about 20;c is from about 0 to about 5;d is from about 0 to about 20; andx is a number needed to fulfill the valence requirements of the other elements; provided that(i) at least one of c and d is at least 0.1; and(ii) when M' is Sn, c must be at least 0.1.The process of the present invention involves contacting low molecular weight alkanes at elevated temperatures with oxygen and the catalyst of the invention for a period of time sufficient to provide the desired conversion.
摘要翻译：描述了包含锌和碱金属的多组分氧化物催化剂，其特别用于将甲烷和/或天然气转化为较高分子量烃产物如乙烷和乙烯。催化剂的特征在于式ZnaAbMcM'dOx，其中A为Li，Na，K或其混合物; M是Al，Ga，Cr，La，Y，Sc，V，Nb，Ta，Cu或其混合物; M'是Cs，Rb，Mg，Ca，Sr，Ba，Sm，Pb，Mn，Sb，P，Sn，Bi，Ti，Zr，Hf或它们的混合物; a为约1至约20; b为约0.1至约20; c为约0至约5; d为约0至约20; x是满足其他要素价格要求的数字; 条件是（i）c和d中的至少一个至少为0.1; 和（ii）当M'为Sn时，c必须至少为0.1。本发明的方法包括使低分子量烷烃在升高的温度下与氧和本发明的催化剂接触足以提供所需转化的时间。

3. 发明授权

US4094922A Alkylation of aromatics using amphora shaped catalysts 失效
标题翻译：使用二孢子形催化剂烷基化芳烃
公开(公告)号：US4094922A
公开(公告)日：1978-06-13
申请号：US771482
申请日：1977-02-24
申请人： Joseph P. Bartek , Robert K. Grasselli
发明人： Joseph P. Bartek , Robert K. Grasselli
IPC分类号： B01J35/08 , C07C2/66 , C07C2/68 , C07C2/70 , C07C3/52
CPC分类号： C07C2/68 , B01J35/08 , C07C2/66 , C07C2/70 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/02 , C07C2527/167 , C07C2527/173
摘要： Catalysts having a substantially spherical shape, a void center and a hole in the external surface communicating to the void center have been found to be especially effective in the alkylation of aromatic hydrocarbons.
摘要翻译：已经发现，具有基本上球形的催化剂，空心中心和与空隙中心连通的外表面中的孔在芳烃的烷基化方面特别有效。

4. 发明授权

US4292455A Multi-stage dehydrogenation process for preparing indene 失效
标题翻译：用于制备茚的多级脱氢方法
公开(公告)号：US4292455A
公开(公告)日：1981-09-29
申请号：US108328
申请日：1979-12-28
申请人： Joseph P. Bartek , Rimoydas L. Cepulis , Robert K. Grasselli
发明人： Joseph P. Bartek , Rimoydas L. Cepulis , Robert K. Grasselli
IPC分类号： C07C5/48 , C07C13/465 , C07C5/42 , C07C4/12 , C07C5/367
CPC分类号： C07C13/465 , C07C5/48
摘要： A multi-stage dehydrogenation process for preparing indene and substituted indenes from indene precursors more saturated than indene is described. The process comprises the steps of(a) contacting said indene precursor in a first dehydrogenation zone with a dehydrogenation catalyst at an elevated temperature to form an intermediate product,(b) advancing the product of the first dehydrogenation zone to a second dehydrogenation zone,(c) contacting said product in the second dehydrogenation zone with a second dehydrogenation catalyst at an elevated temperature, and(d) recovering indene or a substituted indene from said second zone.The process of the invention results in yields of indene which are enhanced when compared to single stage, essentially isothermal processes using a single catalyst.
摘要翻译：描述了从茚更饱和的茚前体制备茚和取代的茚的多级脱氢方法。该方法包括以下步骤：（a）在升高的温度下将第一脱氢区中的所述茚初始物与脱氢催化剂接触以形成中间产物，（b）使第一脱氢区的产物进入第二脱氢区（ c）在升高的温度下将第二脱氢区中的所述产物与第二脱氢催化剂接触，和（d）从所述第二区回收茚或取代的茚。与使用单一催化剂的单级，基本等温过程相比，本发明的方法导致茚的产率增强。

5. 发明授权

US4886931A Upgrading low molecular weight hydrocarbons 失效
标题翻译：升级低分子量碳氢化合物
公开(公告)号：US4886931A
公开(公告)日：1989-12-12
申请号：US58016
申请日：1987-06-04
申请人： Joseph P. Bartek , James F. Brazdil, Jr. , John M. Hupp , Robert K. Grasselli
发明人： Joseph P. Bartek , James F. Brazdil, Jr. , John M. Hupp , Robert K. Grasselli
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/06 , C07C2527/224 , Y10S585/943
摘要： A multi-component oxide catalyst comprising zinc and an alkali metal is described which is useful particularly for converting methane and/or natural gas to higher molecular weight hydrocarbon products such as ethane and ethylene. The catalyst is characterized by the formulaZn.sub.a A.sub.b M.sub.c M'.sub.d O.sub.xwhereinA is Li, Na, K, or mixtures thereof;M is Al, Ga, Cr, La, Y, Sc, V, Nb, Ta, Cu or mixtures thereof;M' is Cs, Rb, Mg, Ca, Sr, Ba, Sm, Pb, Mn, Sb, P, Sn, Bi, Ti, Zr, Hf, or mixtures thereof;a is from about 1 to about 20;b is from about 0.1 to about 20;c is from about 0 to about 5;d is from about 0 to about 20; andx is a number needed to fulfill the valence requirements of the other elements; provided that(i) at least one of c and d is at least 0.1; and(ii) when M' is Sn, c must be at least 0.1. The process of the present invention involves contacting low molecular weight alkanes at elevated temperatures with oxygen and the catalyst of the invention for a period of time sufficient to provide the desired conversion.
摘要翻译：描述了包含锌和碱金属的多组分氧化物催化剂，其特别用于将甲烷和/或天然气转化为较高分子量烃产物如乙烷和乙烯。催化剂的特征在于式ZnaAbMcM'dOx，其中A为Li，Na，K或其混合物; M是Al，Ga，Cr，La，Y，Sc，V，Nb，Ta，Cu或其混合物; M'是Cs，Rb，Mg，Ca，Sr，Ba，Sm，Pb，Mn，Sb，P，Sn，Bi，Ti，Zr，Hf或它们的混合物; a为约1至约20; b为约0.1至约20; c为约0至约5; d为约0至约20; x是满足其他要素价格要求的数字; 条件是（i）c和d中的至少一个至少为0.1; 和（ii）当M'为Sn时，c必须至少为0.1。本发明的方法包括使低分子量烷烃在升高的温度下与氧和本发明的催化剂接触足以提供所需转化的时间。

6. 发明授权

US4246421A Oxydehydrogenation process for alkylaromatics 失效
标题翻译：烷基芳烃的氧化脱氢方法
公开(公告)号：US4246421A
公开(公告)日：1981-01-20
申请号：US942576
申请日：1978-09-15
申请人： Joseph P. Bartek , Robert K. Grasselli
发明人： Joseph P. Bartek , Robert K. Grasselli
IPC分类号： B01J27/18 , C07C5/48 , C07D213/06 , C07D213/133 , C07C5/333 , C07C15/46 , C07D215/04
CPC分类号： C07D213/06 , B01J27/18 , C07C5/48
摘要： This invention relates to an improved process for the dehydrogenation of alkyl-substituted aromatic compounds to the corresponding alkenyl-substituted aromatics in the presence of oxygen and in the presence of an improved metal phosphate catalyst composition.
摘要翻译：本发明涉及在氧的存在下和在改进的金属磷酸盐催化剂组合物的存在下将烷基取代的芳族化合物脱氢为相应的烯基取代的芳族化合物的改进方法。

7. 发明授权

US4115464A Process for preparing diarylethylenes 失效
标题翻译：二烯基乙烯的制备方法
公开(公告)号：US4115464A
公开(公告)日：1978-09-19
申请号：US792638
申请日：1977-05-02
申请人： Joseph P. Bartek , Serge R. Dolhyj , Louis J. Velenyi , Robert K. Grasselli
发明人： Joseph P. Bartek , Serge R. Dolhyj , Louis J. Velenyi , Robert K. Grasselli
IPC分类号： B01J27/186 , C07C5/48 , C07C5/42
CPC分类号： B01J27/186 , C07C5/48
摘要： This invention relates to an improved process for the dehydrogenation of diarylethanes to the corresponding diarylethylenes in the presence of oxygen and in the presence of a metal phosphate catalyst.
摘要翻译：本发明涉及在氧的存在下和在金属磷酸盐催化剂的存在下将二芳基乙烷脱氢成相应的二元乙烯的改进方法。

8. 发明授权

US4665259A Methane conversion process using phosphate-containing catalysts 失效
标题翻译：使用含磷酸盐催化剂的甲烷转化方法
公开(公告)号：US4665259A
公开(公告)日：1987-05-12
申请号：US770666
申请日：1985-08-28
申请人： James F. Brazdil , Raymond G. Teller , Joseph P. Bartek , Robert K. Grasselli
发明人： James F. Brazdil , Raymond G. Teller , Joseph P. Bartek , Robert K. Grasselli
IPC分类号： C07C2/76 , C07C2/00
CPC分类号： C07C2/76 , C07C2527/167 , C07C2527/18 , Y10S585/943
摘要： A process is disclosed for converting methane to a higher order hydrocarbon comprising contacting a gaseous reactant comprising methane with a phosphate-containing catalyst for a sufficient period of time and at an effective temperature to provide said higher order hydrocarbon, said catalyst being represented by the formulaM.sub.x PO.sub.ywhereinM is selected from the group consisting of Pb, Bi, Sb, Sn, Tl, In, Mn, Cd, Ge or a mixture of two or more thereof,x is from about 0.1 to about 10, andy is the number of oxygens needed to fulfill the valence requirements of the other elements.
摘要翻译：公开了一种将甲烷转化为高级烃的方法，包括使包含甲烷的气态反应物与含磷酸盐的催化剂接触足够的时间和在有效温度下提供所述高级烃，所述催化剂由式 MxPOy，其中M选自Pb，Bi，Sb，Sn，Tl，In，Mn，Cd，Ge或其两种或更多种的混合物，x为约0.1至约10，y为的氧气需要满足其他要素的价格要求。

9. 发明授权

US4255283A Oxydehydrogenation process for alkylaromatics and catalyst therefor 失效
标题翻译：烷基芳烃的氧化脱氢方法及其催化剂
公开(公告)号：US4255283A
公开(公告)日：1981-03-10
申请号：US889177
申请日：1978-03-23
申请人： Joseph P. Bartek , Robert K. Grasselli
发明人： Joseph P. Bartek , Robert K. Grasselli
IPC分类号： B01J27/18 , C07C5/48 , C07D213/06 , C07D213/127 , B01J21/02 , B01J27/14
CPC分类号： C07D213/06 , B01J27/1802 , C07C5/48
摘要： This invention relates to an improved process for the dehydrogenation of alkyl-substituted aromatic compounds to the corresponding alkenyl-substituted aromatics in the presence of oxygen and in the presence of an improved metal phosphate catalyst composition.
摘要翻译：本发明涉及在氧的存在下和在改进的金属磷酸盐催化剂组合物的存在下将烷基取代的芳族化合物脱氢为相应的烯基取代的芳族化合物的改进方法。

10. 发明授权

US4143082A Method for making indene 失效
标题翻译：制造印花的方法
公开(公告)号：US4143082A
公开(公告)日：1979-03-06
申请号：US816638
申请日：1977-07-18
申请人： Joseph P. Bartek , Robert K. Grasselli
发明人： Joseph P. Bartek , Robert K. Grasselli
IPC分类号： B01J27/00 , B01J27/18 , C07B61/00 , C07C1/00 , C07C5/48 , C07C13/45 , C07C13/465 , C07C67/00 , C07C5/38 , C07C15/22
CPC分类号： B01J27/18 , C07C5/48
摘要： Unsubstituted and substituted bicyclic indene precursors more saturated than indene are converted to indene by a dehydrogenation process in which the indene precursor in the presence of an oxygen donor is contacted with a phosphate catalyst.
摘要翻译：找到一种简单，经济和直接的生产茚单体的方法存在问题。这个问题是通过用脱氢方法制备茚单体和取代的茚单体来解决的，其中比茚更饱和的茚前体与磷供体与磷酸酯催化剂接触。氧供体是O2。该过程进行温度高于100℃。磷酸盐催化剂由式MaPxOy表示，其中M是一种或多种选自Mg，Sr，Ca，Ba，La，Ce，其他稀土元素，Cr，Mn ，Fe，Co，Ni，Cu，Zn，Sn，Pb，Bi，Te，B，Al，Rh，Sb，As，Ge，U，Th和Ru。在代表性实施例中，将茚二酮，约五份空气和三份氮气用于每一份二氢化茚蒸气的混合物进料至含有磷酸盐催化剂的反应器中并保持在550℃的温度。

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