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1. 发明申请

US20190031811A1 POLYISOBUTYLENE-BASED POLY(URETHANE-UREA)S 审中-公开
公开(公告)号：US20190031811A1
公开(公告)日：2019-01-31
申请号：US16072612
申请日：2017-01-24
申请人： Joseph KENNEDY , Kalman TOTH , Susan DOLLINGER , Nihan NUGAY
发明人： Joseph KENNEDY , Kalman TOTH , Susan DOLLINGER , Nihan NUGAY
IPC分类号： C08G18/10 , C08G18/62 , C08G18/76
摘要： In one or more embodiments, the present invention provide a polyisobutylene-based polyurethane-urea, and related method of preparation, wherein PIB-diols form the soft segment and a diisocyanate along with a well-defined combinations low molecular weight diol chain extenders and amino alcohol as co-chain extenders form the hard segments. In one or more embodiments, the present invention is directed to the use of judiciously chosen chain extender/co-chain extender combinations to enhance the strength of PUs by partially replacing urethane groups with urea groups by the use of amino alcohols to improve strength, while maintaining good processability. These thermoplastic PIB-PUU elastomers exhibit heretofore unattainable combinations of mechanical properties and processability.

2. 发明申请

US20200239620A1 GLYCEROL CONTAINING POLYURETHANES AND POLYURETHANE NANOCOMPOSITES 审中-公开
公开(公告)号：US20200239620A1
公开(公告)日：2020-07-30
申请号：US16751683
申请日：2020-01-24
申请人： Joseph KENNEDY , Turgut NUGAY , Nihan NUGAY
发明人： Joseph KENNEDY , Turgut NUGAY , Nihan NUGAY
IPC分类号： C08G18/62 , C08G18/76 , C08G18/32
摘要： The present invention generally relates to polyurethanes and polyurethane nanocomposites having improved mechanical, rheological, and thermal properties over ordinarily produced polyurethanes and polyurethane nanocomposites. Such polyurethanes and polyurethane nanocomposites include very small amounts of a small chain diol, such as glycerol, and more specifically, between 0.01 and 4 weight percent of the small chain diol, based on the total polymer composition.

3. 发明申请

US20200216597A1 STAR ISOBUTYLENE-BASED THERMOPLASTIC ELASTOMERS 审中-公开
公开(公告)号：US20200216597A1
公开(公告)日：2020-07-09
申请号：US16821357
申请日：2020-03-17
申请人： Joseph KENNEDY , Turgut NUGAY , Nihan NUGAY
发明人： Joseph KENNEDY , Turgut NUGAY , Nihan NUGAY
IPC分类号： C08F297/00 , C08F210/10 , C08L23/22 , C08L25/16 , C08F212/08
摘要： A star block copolymer and a thermoplastic elastomer including plurality of the star block copolymers and a method of making both is taught. The star block copolymers of the present invention include a core component having a styrene oligomer wherein arms emanate from the core component and the arms are poly(isobutylene-block-styrene) diblock copolymers.

4. 发明申请

US20200040121A1 STAR ISOBUTYLENE-BASED THERMOPLASTIC ELASTOMERS 审中-公开
公开(公告)号：US20200040121A1
公开(公告)日：2020-02-06
申请号：US16532800
申请日：2019-08-06
申请人： Joseph KENNEDY , Turgut Nugay , Nihan Nugay
发明人： Joseph KENNEDY , Turgut Nugay , Nihan Nugay
IPC分类号： C08F297/00 , C08F210/10 , C08L23/22 , C08F212/08 , C08L25/16
摘要： A star block copolymer and a thermoplastic elastomer including plurality of the star block copolymers and a method of making both is taught. The star block copolymers of the present invention include a core component having an -methylstyrene oligomer wherein arms emanate from the core component and the arms are poly(isobutylene-block-styrene) diblock copolymers.

5. 发明申请

US20160002373A1 PREPARATION OF POLYISOBUTYLENE-BASED POLYMER NETWORKS BY THIOL-ENE CHEMISTRY 有权
标题翻译：通过THIOL-ENE化学制备基于聚异丁烯的聚合物网络
公开(公告)号：US20160002373A1
公开(公告)日：2016-01-07
申请号：US14769709
申请日：2014-03-04
申请人： Joseph KENNEDY , Turgut NUGAY , Nihan NUGAY
发明人： Joseph KENNEDY , Turgut NUGAY , Nihan NUGAY
IPC分类号： C08F110/10
CPC分类号： C08F110/10 , C08F10/10 , C08F299/00 , C08G75/04 , C08G75/045 , C08K5/37 , C08F4/16 , C08F2/10
摘要： A PIB-based polymer network includes at least one sulfur containing segment and at least two PIB polymer segments. The at least two PIB polymer segments each include a core and at least two polyisobutylene polymer chains extending therefrom. The at least one sulfur containing segment includes at least one sulfur atom that is located between any two polyisobutylene polymer chains from two different PIB polymer segments, so that the sulfur containing segment connects those two different PIB polymer segments together. The PIB-based polymer network is produced by the thiol-ene reaction in the presence of light or heat. The reaction products include at least two polyisobutylene polymer precursor moieties, each polyisobutylene polymer precursor moiety having at least two end group selected from the end groups —CH2—CH(CH3)═CH2, —CH2═C(CH3)2, and —CH2—CH═CH2; and at least one multi-functional thiol.
摘要翻译：基于PIB的聚合物网络包括至少一个含硫段和至少两个PIB聚合物链段。所述至少两个PIB聚合物链段各自包含芯和从其延伸的至少两个聚异丁烯聚合物链。至少一个含硫部分包含位于来自两个不同PIB聚合物链段的任何两个聚异丁烯聚合物链之间的至少一个硫原子，使得含硫链段将那两个不同的PIB聚合物链段连接在一起。基于PIB的聚合物网络通过在光或热存在下的硫醇 - 烯反应制备。反应产物包括至少两个聚异丁烯聚合物前体部分，每个聚异丁烯聚合物前体部分具有至少两个选自端基-CH 2 -CH（CH 3）= CH 2，-CH 2 = C（CH 3）2和-CH 2 -CH = CH 2; 和至少一种多官能硫醇。

6. 发明申请

US20190127510A1 NOVEL INITIATORS FOR LIVING CARBOCATIONIC POLYMERIZATION 审中-公开
公开(公告)号：US20190127510A1
公开(公告)日：2019-05-02
申请号：US16069659
申请日：2017-01-20
申请人： Joseph KENNEDY , Turgut NUGAY
发明人： Joseph KENNEDY , Turgut NUGAY
IPC分类号： C08G18/62 , C08G81/02
CPC分类号： C08G18/6204 , C07C13/44 , C07C23/18 , C07C23/32 , C07C33/36 , C07C35/31 , C07C35/37 , C07C35/44 , C07C43/188 , C07C211/27 , C07C2602/06 , C07C2603/08 , C07C2603/40 , C08F2/48 , C08F8/06 , C08F8/30 , C08F210/10 , C08G81/024
摘要： In various embodiments, the present invention is directed to new low cost initiator compositions for use with the production of well-defined telechelic PIBs (by LC+P of isobutylene). In various other embodiments, the present invention is directed to methods for using these novel compositions as initiators for isobutylene (IB) and other cationically polymerizable monomers, such as styrene and its derivatives. In still other embodiments, the present invention is directed to structurally new, allyl (and chlorine) telechelic PIBs formed from these new initiator compositions and their derivatives (in particular, hydroxyl telechelic PIB and amine telechelic PIB). In yet other embodiments, the present invention is directed to structurally new polyurethanes, polyureas, and polyurethane ureas made using telechelic PIBs formed from these new initiator compositions.

7. 发明申请

US20180066079A1 POLYISOBUTYLENES AND PROCESS FOR MAKING SAME 审中-公开
公开(公告)号：US20180066079A1
公开(公告)日：2018-03-08
申请号：US15798542
申请日：2017-10-31
申请人： Joseph KENNEDY , Yongmoon KWON , Subramanyam UMMADISETTY
发明人： Joseph KENNEDY , Yongmoon KWON , Subramanyam UMMADISETTY
IPC分类号： C08F8/00 , C08F8/12 , C08G18/62 , C08G18/76 , C08F8/06
CPC分类号： C08F8/00 , C07C17/013 , C07C19/075 , C07C31/18 , C07C51/00 , C07C209/08 , C07C211/01 , C08F8/06 , C08F8/10 , C08F8/12 , C08F8/20 , C08F8/26 , C08F8/30 , C08F8/32 , C08F10/10 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08G18/3206 , C08G18/6204 , C08G18/7671 , C08F4/16 , C08F2/38 , C08F8/28
摘要： The present invention generally relates to alcohol-terminated polyisobutylene (FIB) compounds, and to a process for making such compounds. In one embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds, and to a process for making such compounds. In still another embodiment, the present invention relates to polyisobutylene compounds that can be used to synthesize polyurethanes, to polyurethane compounds made via the use of such polyisobutylene compounds, and to processes for making such compounds. In yet another embodiment, the present invention relates to primary alcohol-terminated polyisobutylene compounds having two or more primary alcohol termini and to a process for making such compounds. In yet another embodiment, the present invention relates to primary terminated polyisobutylene compounds having two or more primary termini selected from amine groups or methacrylate group.

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