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    • 6. 发明授权
    • Thermally integrated reformer for solid oxide fuel cells
    • 用于固体氧化物燃料电池的热集成重整器
    • US5366819A
    • 1994-11-22
    • US133444
    • 1993-10-06
    • Joseph J. HartvigsenAshok C. Khandkar
    • Joseph J. HartvigsenAshok C. Khandkar
    • C01B3/38H01M8/06H01M8/12H01M8/24
    • H01M8/247C01B3/384H01M8/0625H01M2008/1293H01M2300/0074Y02P20/129
    • A thermally integrated reformer (10) is located inside the stack furnace (12), housing stacks (14) of solid oxide fuel cells (16). The energy to support the endothermic reformation reaction converting hydrocarbon and water feedstock into hydrogen and carbon monoxide fuel is supplied by heat recuperated from the oxidation process in the stack (14) of fuel cells (16). The source of hydrocarbons is de-sulfurized natural gas. Heat transfers to the incrementally shielded packed beds (30, 60) of the reactors (18, 19) of the reformer (10) by radiation from the stacks (14) and furnace wall (38) and by forced convection from the exhausting airflow exiting the stack furnace (12). Temperature gradients in the reformer (10) are controlled by selective (or incremented) radiation shielding (20) and by counterflow heat exchange to prevent excessive premature cracking in the reformer where carbonization would clog interstices and render the catalyst granules (32) ineffective.
    • 热集成重整器(10)位于堆垛炉(12)的内部,固体氧化物燃料电池(16)的壳体堆叠(14)。 将碳氢化合物和水原料转化为氢气和一氧化碳燃料的支持吸热重整反应的能量是通过燃料电池(16)的堆叠(14)中的氧化过程回收的热来提供的。 烃的来源是脱硫天然气。 通过来自堆叠(14)和炉壁(38)的辐射以及通过从排出的气流排出的强制对流,热量传递到重整器(10)的反应器(18,19)的增量屏蔽的填充床(30,60) 堆垛炉(12)。 重整器(10)中的温度梯度通过选择性(或增量)辐射屏蔽(20)和逆流热交换来控制,以防止重整器中的过度开裂,其中碳化将堵塞间隙并使催化剂颗粒(32)无效。